Preparation and thermal properties of Alkoxy Silane functionalized polyether sulfone/well‐defined poly(trimethoxysilyl) propyl methacrylate‐based hybrid materials

In this study, novel polyethersulfone (PES) and poly(trimethoxysilyl) propyl methacrylate (PMPS) containing hybrid materials were prepared. PES was functionalized with trimethoxysilane groups by UV‐induced grafting reaction. PMPS was synthesized by atom transfer radical polymerization. In the followed process, the functionalized PES mixed with different amount of PMPS, thermally treated to promote sol–gel crosslinking process to prepare the PES‐based hybrid materials. The trimethoxysilane grafted PES chains are covalently bonded with the well‐defined trimethoxysilane groups of PMPS. The chemical structure of the prepared PES and PMPS is confirmed by Fourier transform infrared analysis. The morphology of the hybrids was investigated by scanning electron microscopy. The results of thermogravimetric analysis show that the thermal stability of the hybrid materials was significantly affected with the addition of PMPS. POLYM. ENG. SCI., 58:1346–1352, 2018. © 2017 Society of Plastics Engineers     

Processing‐structure‐property relationship in rigid polyurethane foams

Rigid polyurethane (PU) foam is used as a thermal insulating and supporting material in domestic refrigerator/freezers and it is produced by reaction injection molding (RIM) process. There is a need to improve the thermal property of rigid PU foam but this is still a challenging problem. Accordingly, this work investigates the RIM process parameters to evaluate their effects on rigid PU foam's structure and hence property. It has been found that mold temperature is a key parameter whereas curing time has negligible effect on structure of PU foam. Cell size, strut thickness, and foam density have been found very critical in controlling the thermal and mechanical properties. Upper and lower values of 30 to 32 kg/m³ density are critical to observe contribution of radiation and solid conductivity separately. Finally, PU foam with 160 µm average cell size, 16 µm strut thickness, below 10% open cell content, and 30 to 32 kg/m³ density allow obtaining better thermal insulation without significant reducing in the compressive strength. The presented work provides a better understanding of processing‐structure‐property relationship to gain knowledge on producing high‐quality rigid PU foams with improved properties. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44870.     

Evaluation of biocultural landscapes and associated ecosystem services in the region of Suğla Lake in Turkey

The purpose of this study was to evaluate biocultural landscapes and associated ecosystem services in the region of Su?la Lake located in Konya Province of Turkey. Method of the study includes four stages. In the first stage, the biodiversity function of landscapes was identified by overlapping the maps of flora and fauna and then it was evaluated by using a 1–5 score system. Second, the cultural diversity function of landscapes was evaluated by site survey and literature review. The obtained data were evaluated according to the 11 criteria by using a 1–4 score system. The analysed data were transferred on to the maps. Third, the biocultural landscapes were designated by overlapping the maps of the biodiversity and cultural diversity functions of landscapes. Finally, major ecosystem services provided by the biocultural landscapes were examined by assessing the collected data on the biodiversity and cultural diversity functions of landscapes and review of literature.     

In vitro characterisation of probiotic properties of Enterococcus faecium and Enterococcus durans strains isolated from raw milk and traditional dairy products

In this study, some probiotic characteristics such as antimicrobial activity, vancomycin resistance, growth ability at pH, resistance to bile salts, bile salt deconjugation and hydrophobicity of 30 Enterococcus faecium and Enterococcus durans strains isolated and identified from raw milk and various dairy products were investigated. According to the study results, antimicrobial activity profiling, pH and bile salt resistance and bile salt deconjugation ability of Enterococcus strains varied depending on the species and strains and all the strains showed resistance to the tested bile salt concentrations. It was concluded that the E. faecium and E. durans strains tested showed probiotic characteristics and have the potential to be used in food production.     

Towards full-structure determination of bimetallic nanoparticles with an aberration-corrected electron microscope

To fully understand the properties of functional nanostructures such as catalytic nanoclusters, it is necessary to know the positions of all the atoms in the nanostructure. The catalytic properties of metal nanoclusters can often be improved by the addition of a second metal, but little is known about the role of the different metals in these bimetallic catalysts, or about their interactions with each other and the support material. Here we show that aberration-corrected scanning transmission electron microscopy of supported rhodium-iridium clusters, combined with dynamic multislice image simulations, can identify individual atoms, map the full structure, and determine changes in the positions of metal atoms in sequential images. This approach could help in the development of new and improved catalysts and other functional nanostructures.     

Energetic and exergetic performance evaluation of the quadruple-effect evaporator unit in tomato paste production

Quadruple-effect evaporator units are commonly used in food focus area in sector is evaporative unit. It consumes about 60% of total energy input. The present study evaluates the performance of quadruple-effect evaporator unit (QEEU) by using exergy analysis based on actual operational data. A tomato paste factory is chosen for the analysis. The highest exergy destruction/loss occurs in the first effect with 158.2 kW, 52.7% of exergy input in first effect. Steam temperature should be decreased in order to decrease exergy destruction in first effect. Also, third effect achieves the highest exergy efficiency with 93.3%. Exergetic improvement potential of each effect varies between 0.3 kW and 83.6 kW. The highest and lowest exergetic improvement potential occurs in first and third effect of QEEU system, respectively. Exergetic improvement potential is equals to 52.80%, 11.10%, 6.73% and 69.8% of exergy loss/destruction from the first effect to the last effect, respectively. Total exergetic improvement potential is achieved as 128 kW (55% of total exergy loss/destruction) in QEEU system. It is expected that analyses result provide important information for designer and/or resources of multiple effect evaporator unit.     

Using the when/where rules in dual resource constrained systems for a hybrid push-pull control

This paper proposes a production control system, DRC-HPP, which uses the when/where rules in dual resource constrained (DRC) systems for a hybrid push-pull (HPP) control, to overcome some difficulties in modelling/implementing DRC/Kanban systems. These rules and the novel ‘process-or-transport’ and ‘whereto’ rules are embedded in some policies workers use to decide when to process (transport) parts, and where (whereto). Unlike most control systems, in which a group of workers is always responsible for transporting and another group is always responsible for processing parts, workers in DRC-HPP are responsible for both transporting and processing parts, as in the Toyota Sewn Products Management System (TSS). Yet, unlike TSS, DRC-HPP can be applied in any layout type. Workers transport parts when they are idle in part processing to enhance their utilisations and synchronise transportation. Since the transportation does not require special worker skills, the cost of training workers is not incurred. DRC-HPP is compared with different benchmarks through simulation experiments to evaluate its performance. It performs well under relatively short transportation times with respect to processing times. If they are relatively longer, the issue becomes to determine the number of workers to achieve a performance level. DRC-HPP also facilitates bottleneck management.     

Preconcentration and matrix elimination for the determination of Pb(II), Cd(II), Ni(II), and Co(II)by 8‐hydroxyquinoline anchored poly(styrene‐divinylbenzene) microbeads

Poly(styrene-divinylbenzene), PS-DVB, microbeads were modified with 8-hydroxyquinoline (8-HQ) following nitration, reduction of  NO₂ to NH₂, and conversion of NH₂ to diazonium salt. Characterization of pristine,  NO₂,  NH₂,  NN⁺Cl⁻, and 8-QH functional groups modified microbeads was made by Fourier transform-infrared spectrometry (FTIR) and porosimetry. Total reflectron-X-ray florescence spectrometer (TXRF) was used to test the affinity of the 8-HQ modified microbeads to toxic metal ions. 8-HQ-modified microbeads were used to examine the adsorption capacity, recovery, preconcentration, and the matrix elimination efficiency for Pb(II), Cd(II), Ni(II), and Co(II) ions as a function of changing pH, initial metal-ion concentrations, and also equilibrium adsorption time of the studied metal ions. Preconcentration factors for the studied toxic metal ions were found to be more than 500-fold and recovery between 93.8% and 100.6%. Ultratrace toxic metal-ion concentrations in sea water were determined easily by using modified microbeads. Reference sea-water sample was used for the validation of the method, and it was found that recovery, preconcentration, and the matrix elimination were performed perfectly. For the desorption of the toxic metal ions, 3M of HNO₃ was used and desorption ratio shown to be more than 96%. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Variation in Fatty Acid Compositions, Oil Content and Oil Yield in a Germplasm Collection of Sesame (Sesamum indicum L.)

The variation in oil content, oil yield and fatty acid compositions of 103 sesame landraces was investigated. The landraces varied widely in their oil quantity and quality. The oil content varied between 41.3 and 62.7%, the average being 53.3%. The percentage content of linoleic, oleic, palmitic and stearic acids in the seed oil ranged between 40.7–49.3, 29.3–41.4, 8.0–10.3 and 2.1–4.8%, respectively. Linolenic and arachidic acids were the minor constituents of the sesame oil. Linoleic and oleic acids were the major fatty acids of sesame with average values of 45.7 and 37.2%, respectively. The total means of oleic and linoleic acids as unsaturated fatty acids of sesame were about 83% which increases the suitability of the sesame oil for human consumption. The superiority of the collection was observed in oil content. The oil content of a few accessions was above 60%, proving claims that some varieties of sesame can reach up to 63% in oil content. The accessions with the highest oil content were relatively richer in the linoleic acid content while there were some landraces in which linoleic and oleic acid contents were in a proportion of almost 1:1. The results obtained in this study provide useful background information for developing new cultivars with a high oil content and different fatty acid compositions. Several accessions could be used as parental lines in breeding programmes aiming to increase sesame oil quantity and quality.