Condensation of 4-phenyl-3,5-dicarboethoxycyclopentane-1,2-dione with primary amines

Condensation of the title compound ( 1 ) with primary aromatic amines gave the dianilides ( 2 ), which cyclized to cyclopenta[1,2-c:4,3-c′]diquinolines ( 3 ). Treatment of 1 with o-phenylenediamine or 2,3-diaminopyridine afforded cyclopenta[2,1-b:3,4- b ′]bis[1,5]benzodiazepine ( 4 ) and bis[1,5]pyrido[b]diazepine derivative ( 5 ), respectively. Whereas, with o-aminophenol a mixture of 2c and cyclopenta[2,1- b :3,4- b ′]bis[1,5]benzoxazepine ( 7 ) was obtained. Pechmann reaction of 1 with m-cresol gave the bis[1]benzopyrane ( 9 ). Mannich reaction of 1 with benzylamine afforded the 3-azabicyclo[3.2.1]octane system ( 10 ).     

Removal of heavy‐metal ions by magnetic beads containing triazole chelating groups

The aim of this study was to prepare magnetic beads that could be used for the removal of heavy‐metal ions from synthetic solutions. Magnetic poly(ethylene glycol dimethacrylate–1‐vinyl‐1,2,4‐triazole) [m‐poly(EGDMA–VTAZ)] beads were produced by suspension polymerization in the presence of a magnetite Fe₃O₄ nanopowder. The specific surface area of the m‐poly(EGDMA–VTAZ) beads was 74.8 m²/g with a diameter range of 150–200 μm, and the swelling ratio was 84%. The average Fe₃O₄ content of the resulting m‐poly(EGDMA–VTAZ) beads was 14.8%. The maximum binding capacities of the m‐poly(EGDMA–VTAZ) beads from aquous solution were 284.3 mg/g for Hg²⁺, 193.8 mg/g for Pb²⁺, 151.5 mg/g for Cu²⁺, 128.1 mg/g for Cd²⁺, and 99.4 mg/g for Zn²⁺. The affinity order on a mass basis was Hg²⁺ > Pb²⁺ > Cu²⁺ > Cd²⁺> Zn²⁺. The binding capacities from synthetic waste water were 178.1 mg/g for Hg²⁺, 132.4 mg/g for Pb²⁺, 83.5 mg/g for Cu²⁺, 54.1 mg/g for Cd²⁺, and 32.4 mg/g for Zn²⁺. The magnetic beads could be regenerated (up to ca. 97%) by a treatment with 0.1M HNO₃. These features make m‐poly(EGDMA–VTAZ) beads potential supports for heavy‐metal removal under a magnetic field. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Material Parameters for Creep Rupture of Austenitic Stainless Steel Foils

Creep rupture properties of austenitic stainless steel foil, 347SS, used in compact recuperators have been evaluated at 700 °C in the stress range of 54-221 MPa to establish the baseline behavior for its extended use. Creep curves of the foil show that the primary creep stage is brief and creep life is dominated by tertiary creep deformation with rupture lives in the range of 10-2000 h. Results are compared with properties of bulk specimens tested at 98 and 162 MPa. Thin foil 347SS specimens were found to have higher creep rates and higher rupture ductility than their bulk specimen counterparts. Power law relationship was obtained between the minimum creep rate and the applied stress with stress exponent value, n = 5.7. The value of the stress exponent is indicative of the rate-controlling deformation mechanism associated with dislocation creep. Nucleation of voids mainly occurred at second-phase particles (chromium-rich M₂₃C₆ carbides) that are present in the metal matrix by decohesion of the particle-matrix interface. The improvement in strength is attributed to the precipitation of fine niobium carbides in the matrix that act as obstacles to the movement of dislocations.     

大塑性变形技术制备块状超细晶TiNi基形状记忆合金研究进展

详细介绍了块状超细晶TiNi基形状记忆合金的研究进展,包括其制备工艺与显微组织、马氏体相变行为、力学性能和形状记忆特性以及超弹性性能,并介绍了其在医学和工程领域的实际应用,最后探讨了块状超细晶TiNi基形状记忆合金今后的研究发展方向。     

Effect of Boronizing on Operating Stability of Steel AISI 304L under Erosion Impact of Hard Particles

Metal Science and Heat Treatment - The effect of solid boronizing at 950°C for 2 and 4 h on the phase composition, microstructure, hardness and abrasive wear of steel AISI 304L is studied...     

Selective separation of cobalt and nickel by supported liquid membranes

The selective separation of cobalt from acidic media, containing both equimolar and nonequimolar mixtures of cobalt and nickel, was examined by supported liquid membranes using Alamine 336 as mobile carrier dissolved in various diluents. The membrane support was microporous hydrophobic polypropylene Celgard 2500 (25 μm thick, 0.209 × 0.054 μm pore size and 55% porosity). Acetic acid-Na acetate buffer was used for the adjustment of the feed pH which was critical. Various parameters were experimentally studied and the optimum conditions were determined.     

Use of basalt in asphalt concrete mixes

One of the main reasons behind the appearance of early distresses in Jordan roads and the low surface skid resistance is the use of marginal quality limestone aggregate. Large quantities of good quality basalt are available in the Northeastern parts of Jordan. In this research, the possibility of improving the properties of local asphalt concrete mixes by replacing different portions of the normally used limestone aggregate by basalt was investigated. The replacement included total replacement of the limestone by basalt, replacing the coarse aggregate, and replacing the fine aggregate. Results showed that the optimal mix was the mix that had basalt coarse aggregate and limestone fine aggregate. In order to overcome the stripping potential of the optimal mix, 20% of the filler portion of the aggregate, material smaller than 0.075 mm, was replaced by lime. The optimal mix showed superiority, over the tested mixes, in all the evaluated properties, which were Marshall Stability, indirect tensile strength, stripping resistance, resilient modulus, dynamic creep, fatigue, and rutting.     

Use of low CaO unprocessed steel slag in concrete as fine aggregate

Steel slag, which is produced locally in great amounts, has a negative impact on the environment when disposed. Local steel slag has a low CaO content and has no pozzolanic activity.In this research, local unprocessed steel slag is introduced in concrete mixes. Various mixes with compressive strength ranging from 25 to 45 MPa are studied. The slag is used as fine aggregate replacing the sand in the mixes, partly or totally. Ratios of 0%, 15%, 30%, 50% and 100% are used.Depending on the grade of concrete, the compressive strength is improved when steel slag is used for low sand replacement ratios (up to 30%).When optimum values are used, the 28-day tensile strength of concrete is improved by 1.4–2.4 times and the compressive strength is improved by 1.1–1.3 times depending on the replacement ratio and the grade of concrete. The best results are obtained for replacement ratios of 30–50% for tensile strength and 15–30% for compressive strength.Therefore, the use of steel slag in concrete would enhance the strength of concrete, especially tensile strength, provided the correct ratio is used.     

Electrochemical and spectroscopic characterization of a Benzo[c]cinnoline electrografted platinum surface

In this work, a platinum surface was modified with benzo[c]cinnoline (BCC) to get new insight into the metal modification area. By potential scanning from + 0.4 V to - 0.8 V, the diazotized BCC was reduced electrochemically and grafted onto the platinum electrode surface to form benzo[c]cinnoline modified platinum electrode (Pt-BCC). Electrochemical reduction of benzo[c]cinnoline diazonium salt on the electrode surface yielded a relatively stable organic film. The introduction of BCC molecules onto the platinum surface was verified by cyclic voltammetry, electrochemical impedance spectroscopy, Raman spectroscopy and ellipsometry. The stability and the potential range of the Pt-BCC electrode were also studied.     

Real-time Design Constraints in Implementing Active Vibration Control Algorithms

Although computer architectures incorporate fast processing hardware resources, high performance real-time implementation of a complex control algorithm requires an efficient design and software coding of the algorithm so as to exploit special features of the hardware and avoid associated architecture shortcomings. This paper presents an investigation into the analysis and design mechanisms that will lead to reduction in the execution time in implementing real-time control algorithms. The proposed mechanisms are exemplified by means of one algorithm, which demonstrates their applicability to real-time applications. An active vibration control (AVC) algorithm for a flexible beam system simulated using the finite difference (FD) method is considered to demonstrate the effectiveness of the proposed methods. A comparative performance evaluation of the proposed design mechanisms is presented and discussed through a set of experiments.