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71.
The twinning of antimony single crystals in nanoindentation has been investigated. The role of twinning in the formation of the impression of the Berkovich pyramid on the surface (111) of antimony single crystals has been established. A new method of investigation of the mechanical twinning of single crystals has been developed. For the first time, the duration of the process of twinning has been determined experimentally by a direct technique.  相似文献   
72.
Ren Y  Xu S  Rider AE  Ostrikov KK 《Nanoscale》2011,3(2):731-740
Through a combinatorial approach involving experimental measurement and plasma modelling, it is shown that a high degree of control over diamond-like nanocarbon film sp3/sp2 ratio (and hence film properties) may be exercised, starting at the level of electrons (through modification of the plasma electron energy distribution function). Hydrogenated amorphous carbon nanoparticle films with high percentages of diamond-like bonds are grown using a middle-frequency (2 MHz) inductively coupled Ar+CH4 plasma. The sp3 fractions measured by X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy in the thin films are explained qualitatively using sp3/sp2 ratios 1) derived from calculated sp3 and sp2 hybridized precursor species densities in a global plasma discharge model and 2) measured experimentally. It is shown that at high discharge power and lower CH4 concentrations, the sp3/sp2 fraction is higher. Our results suggest that a combination of predictive modeling and experimental studies is instrumental to achieve deterministically grown made-to-order diamond-like nanocarbons suitable for a variety of applications spanning from nano-magnetic resonance imaging to spin-flip quantum information devices. This deterministic approach can be extended to graphene, carbon nanotips, nanodiamond and other nanocarbon materials for a variety of applications.  相似文献   
73.
The ionization energy theory is used to calculate the evolution of the resistivity and specific heat curves with respect to different doping elements in the recently discovered superconducting pnictide materials. Electron-conduction mechanism in the pnictides above the structural transition temperature is explained unambiguously, which is also consistent with other strongly correlated materials, such as cuprates, manganites, titanates and magnetic semiconductors.  相似文献   
74.
A method is proposed for scattered light correlation spectroscopy for objective evaluation of the effect of water, oxidation products, and particulate contaminants on the size of colloidal formations in petroleum oils with additives. It was shown that to increase the colloidal stability — resistance to separation of oils with additives — and correspondingly improve their performance properties, it is necessary to take into account the intermolecular interactions of the additives in composites and to ensure the minimum change in them under the effect of external factors. The mechanism of the reaction of the additives and their selection for ensuring the assigned performance properties of lube oils is theoretically substantiated. __________ Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 3, pp. 43–45, May–June, 2008.  相似文献   
75.
76.
Refractories and Industrial Ceramics - The following Acknowledgement is to be added to page 173 after the Conclusion: The work was financially supported by the Ministry of Education and Science of...  相似文献   
77.
    
The discovery of novel materials that possess extraordinary optical properties are of special interest, as they inspire systems for next‐generation solar energy harvesting and conversion devices. Learning from nature has inspired the development of many photonic nanomaterials with fascinating structural colors. 2D photonic nanostructures, inspired by the attractive optical properties found on the inner surfaces of seashells, are fabricated in a facile and scalable way. The shells generate shining clusters for preying on phototactic creatures through interaction with incident solar light in water. By alternately depositing graphene and 2D ultrathin TiO2 nanosheets to form 2D–2D heterostructures and homostructures, seashell‐inspired nanomaterials with well‐controlled parameters are successfully achieved. They exhibit exceptional interlayer charge transfer properties and ultrafast in‐plane electron mobility and present fascinating nacre‐mimicking optical properties and significantly enhanced light‐response behavior when acting as photoelectrodes. A window into the fabrication of novel 2D photonic structures and devices is opened, paving the way for the design of high‐performance solar‐energy harvesting and conversion devices.  相似文献   
78.
    
The release of nitrates into the environment leads to contaminated soil and water that poses a health risk to humans and animals. Due to the transition to renewable energy-based technologies, an electrochemical approach is an emerging option that can selectively produce valuable ammonia from nitrate sources. However, traditional metal-based electrocatalysts often suffer from low nitrate adsorption that reduces NH3 production rates. Here, a Ni-GaOOH-C/Ga electrocatalyst for electrochemical nitrate conversion into NH3 is synthesized via a low energy atmospheric-pressure plasma process that reduces CO2 into highly dispersed activated carbon on dispersed Ni─GaOOH particles produced from a liquid metal Ga─Ni alloy precursor. Nitrate conversion rates of up to 26.3 µg h−1 mg−1cat are achieved with good stability of up to 20 h. Critically, the presence of carbon centers is central to improved performance where both Ni─C and NiO─C interfaces act as NO3− adsorption and reduction centers during the reaction. Density functional theory (DFT) calculations indicate that the NiO─C and Ni─C reaction sites reduce the Gibbs free energy required for NO3− reduction to NH3 compared to NiO and Ni. Importantly, catalysts without carbon centers do not produce NH3, emphasizing the unique effects of incorporating carbon nanoparticles into the electrocatalyst.  相似文献   
79.
    
Microplasmas are low-temperature plasmas that feature microscale dimensions and a unique high-energy-density and a nonequilibrium reactive environment, which makes them promising for the fabrication of advanced nanomaterials and devices for diverse applications. Here, recent microplasma applications are examined, spanning from high-throughput, printing-technology-compatible synthesis of nanocrystalline particles of common materials types, to water purification and optoelectronic devices. Microplasmas combined with gaseous and/or liquid media at low temperatures and atmospheric pressure open new ways to form advanced functional materials and devices. Specific examples include gas-phase, substrate-free, plasma-liquid, and surface-supported synthesis of metallic, semiconducting, metal oxide, and carbon-based nanomaterials. Representative applications of microplasmas of particular importance to materials science and technology include light sources for multipurpose, efficient VUV/UV light sources for photochemical materials processing and spectroscopic materials analysis, surface disinfection, water purification, active electromagnetic devices based on artificial microplasma optical materials, and other devices and systems including the plasma transistor. The current limitations and future opportunities for microplasma applications in materials related fields are highlighted.  相似文献   
80.
The process of the coalescence of twin boundaries in bismuth single crystals has been studied. It has been established that the twin coalescence can occur without the formation of an interface between them or with the formation of a double twin boundary, depending on the direction of twin growth and orientation of twinning planes.  相似文献   
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