Laser sintering of coated polyamide 12: a new way to improve flammability

Journal of Materials Science - In this study coatings of kaolin and talc particles were successfully applied on the surface of polyamide 12 powder intended for laser sintering (LS). Microscopic...     

On accounting for screen resolution in adaptive video streaming: QoE-driven bandwidth sharing framework

Screen resolution along with network conditions are main objective factors impacting the user experience, in particular for video streaming applications. User terminals on their side feature more and more advanced characteristics resulting in different network requirements for good visual experience. Previous studies tried to link mean opinion score (MOS) to video bitrate for different screen types (e.g., Common Intermediate Format [CIF], Quarter Common Intermediate Format [QCIF], and High Definition [HD]). We leverage such studies and formulate a Quality of Experience (QoE)-driven resource allocation problem to pinpoint the optimal bandwidth allocation that maximizes the QoE over all users of a network service provider located behind the same bottleneck link, while accounting for the characteristics of the screens they use for video playout. For our optimization problem, QoE functions are built using curve fitting on datasets capturing the relationship between MOS, screen characteristics, and bandwidth requirements. We propose a simple heuristic based on Lagrangian relaxation and Karush Kuhn Tucker (KKT) conditions to efficiently solve the optimization problem. Our numerical simulations show that the proposed heuristic is able to increase overall QoE up to 20% compared to an allocation with a TCP look-alike strategy implementing max-min fairness.     

A new denoising method for removing salt & pepper noise from image

Multimedia Tools and Applications - Digital image has a significant importance in many fields in human life such as, in medicine, photography, biology, astronomy, industry and defense. Thus, it...     

Co-condensates of resorcinols and methylol compounds for adhesive resins

A proton magnetic nuclear resonance study was performed on co-condensation reactions of resorcinol, 5-methylresorcinol and 2,5-dimethylresorcinol with methylol compounds, including ortho- and para-methylolphenol, N-methylol-caprolactam, methylol-N,N-diethylurea, methylolurea and N,N′-dimethylolurea. Spectral assignments, reaction kinetics and composition of products are discussed. The reaction in melt (120°C) with methylolphenols occurs as co-condensation in the presence of all catalysts studied. In resorcinols C4C6 substitution is favored. The rate constants of methylol disappearance clearly indicate the preferable influence of acid and alkaline catalyst (not zinc acetate) on para-methylol. The reaction with N-containing methylol compound does not give any co-condensate in the presence of alkaline catalyst. The optimum conditions for co-condensation mainly depend on reactivity of co-reagents with formaldehyde and stability of methylol compound. The quantitative amount of co-condensate with methylolcaprolactam can be obtained in melt-condensation (70°C) in the presence of acid catalyst. Because of the higher reactivity of urea, the reaction in melt (100°C) in the presence of acid catalyst does not lead to quantitative co-condensation. The condensation of methylol compound or resorcinols with formaldehyde can be avoided substantially by performing the reaction in aqueous solution at lower temperature.     

The Photosensitising Clinical Agent Verteporfin Is an Inhibitor of SPAK and OSR1 Kinases

STE20/SPS1‐related proline/alanine‐rich kinase (SPAK) and oxidative‐stress‐responsive kinase 1 (OSR1) are two serine/threonine protein kinases that play key roles in regulating ion homeostasis. Various SPAK and OSR1 mouse models exhibited reduced blood pressure. Herein, the discovery of verteporfin, a photosensitising agent used in photodynamic therapy, as a potent inhibitor of SPAK and OSR1 kinases is reported. It is shown that verteporfin binds the kinase domains of SPAK and OSR1 and inhibits their catalytic activity in an adenosine triphosphate (ATP)‐independent manner. In cells, verteporfin was able to suppress the phosphorylation of the ion co‐transporter NKCC1; a downstream physiological substrate of SPAK and OSR1 kinases. Kinase panel screening indicated that verteporfin inhibited a further eight protein kinases more potently than that of SPAK and OSR1. Although verteporfin has largely been studied as a modifier of the Hippo signalling pathway, this work indicates that the WNK‐SPAK/OSR1 signalling cascade is also a target of this clinical agent. This finding could explain the fluctuation in blood pressure noted in patients and animals treated with this drug.     

Suitability of simplified methods for monthly and twice-monthly milk recording, and new prediction factors for the alternate a.m./p.m. method in dairy ewes under a low-input production system

Sicilo-Sarde dairy flock test-day data were analysed (1) to check predicting ability of ten milk recording procedures, based on information from a single monthly or bimonthly milking and (2) to look for the best pair of factors for predicting daily milk yield from either morning or afternoon milkings for the alternate testing method (AT). Prior to analyses, data were adjusted for variation factors with known significant effect. Number of test-day observations was 4755 from 458 lactations of 288 ewes. Losses of precision associated with simplified methods were evaluated by comparing estimated lactation yields with those observed both in a reference plan, where the two daily milkings were recorded at 2-weekly intervals and in the official A4 milk recording (monthly recording of the two daily milkings). Ranking of simplified plans based on their accuracy was still the same under either monthly or twice-monthly frequency. Estimates of lactation yields showed more lack of precision when the usual monthly designs were compared with twice-monthly sampling of both a.m. and p.m. milkings. Losses of precision ranged from 5.1%, for the A4 plan, to 14.6%. Thus, milk production should be estimated from both mikings when their measurement is economically feasible. When only one milking is weighed, designs based on-or beginning with-the a.m. milking were more accurate. There was no evidence of improvement in sampling accuracy by adjustment for milking interval or production level. For practical and economic reasons, the design alternating a.m. and p.m. milkings, without adjustment, is suggested for ovine milk recording. In such a case, new factors for estimating daily production from the measured milking (1.7, 2.3) should be used rather than the factors currently in use (2, 2) because they improved the loss of precision by more than 13% in a monthly recording system.     

One-line measurement of the residence time distribution in screw extruders

A fluorescence monitoring device was constructed to measure in real time the residence time distribution (RTD) function in screw extruders. Its centerpiece was an optical fiber probe capable of transmitting optical excitation energy to the processed flow stream and detecting the subsequent fluorescence emission. The source of fluorescence emission was an anthracene-bearing substance that was injected to the flow stream as a pulse (tracer) in very small amounts. This device was validated against an off-line ultraviolet spectrophotometer and self-checked as well. In addition to its great sensitivity to fluorescence emission and ease of implementation on an extrusion line, this device could be used to monitor in real time subtle variations of an extrusion operation. The influence of the nature of anthracene-bearing compounds on the measured distribution and the effects of processing parameters on the RTD function were also investigated.     

Effects of granulated blast furnace slag and superplasticizer type on the fresh properties and compressive strength of self-compacting concrete

This paper presents the results of an experimental investigation carried out to study the effect of granulated blast furnace slag and two types of superplasticizers on the properties of self-compacting concrete (SCC). In control SCC, cement was replaced with 10%, 15%, 20%, and 25% of blast furnace slag. Two types of superplasticizers: polycarboxylate based superplasticizer and naphthalene sulphonate based superplasticizers were used. Tests were conducted for slump flow, the modified slump test, V-Funnel, J-Ring, U-Box, and compressive strength. The results showed that polycarboxylate based superplasticizer concrete mixes give more workability and higher compressive strength, at all ages, than those with naphthalene sulphonate based superplasticizer. Inclusion of blast furnace slag by substitution to cement was found to be very beneficial to fresh self-compacting concrete. An improvement of workability was observed up to 20% of slag content with an optimum content of 15%. Workability retention of about 45 min with 15% and 20% of slag content was obtained using a polycarboxylate based superplasticizer; compressive strength decreased with the increase in slag content, as occurs for vibrated concrete, although at later ages the differences were small.     

Impedance investigation of thermally formed oxide films on AISI 304L stainless steel

Thin oxide layers on 304L stainless steel were grown by thermal oxidation at 300 °C at different durations ranging from 2 to 4 h. The structural characterization of the oxide films was carried out by atomic force microscopy (AFM) and scanning electron microscopy (SEM). Electrochemical impedance spectroscopy was used to investigate the effects of exposure time and applied potential on the electronic properties of these films. Oxide films are described by a multilayer structure, with n-type iron oxide and oxyhydroxide in the outer layers and p-type chromium oxide in the inner layer. Doping densities evaluated from Mott-Schottky plots increased with the oxidation duration, with characteristics of highly disordered semiconductor.     

Optimization of Microchannel Heat Sinks Using Genetic Algorithm

In this study, a genetic algorithm is employed to minimize the entropy generation rate in microchannel heat sinks. The entropy generation rate allows the combined effects of thermal performance and pressure drop to be assessed simultaneously as the heat sink interacts with the surrounding flow field. Previously developed models for the heat transfer, pressure drop and entropy generation rate are used in the optimization procedure. The results of optimization are compared with existing results obtained by the Newton–Raphson method. It is observed that the GA gives better overall performance of the microchannel heat sinks.