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101.
  总被引:3,自引:0,他引:3  
Pyrolysis experiments have been conducted on a sample of rapeseed to determine particularly the effects of pyrolysis temperature, heating rate, particle size and sweep gas flow rate on the pyrolysis product yields and their chemical compositions. The maximum oil yield of 73% was obtained at the final pyrolysis temperature of 550–600 °C, particle size range of +0.6–1.25 mm, and sweep gas flow rate of 100 cm3min−1 (N2) at flash pyrolysis conditions in tubular transport reactor. Chromatographic and spectroscopic studies on the pyrolytic oil showed that the oil obtained from rapeseed can be used as a renewable fuel and chemical feedstock.  相似文献   
102.
We report the observation of thermal annealing- and nitrogen-induced effects on electronic transport properties of as-grown and annealed n- and p-type modulation-doped Ga1 - xInxNyAs1 - y (x = 0.32, y = 0, 0.009, and 0.012) strained quantum well (QW) structures using magnetotransport measurements. Strong and well-resolved Shubnikov de Haas (SdH) oscillations are observed at magnetic fields as low as 3 T and persist to temperatures as high as 20 K, which are used to determine effective mass, 2D carrier density, and Fermi energy. The analysis of temperature dependence of SdH oscillations revealed that the electron mass enhances with increasing nitrogen content. Furthermore, even the current theory of dilute nitrides does not predict a change in hole effective mass; nitrogen dependency of hole effective mass is found and attributed to both strain- and confinement-induced effects on the valence band. Both electron and hole effective masses are changed after thermal annealing process. Although all samples were doped with the same density, the presence of nitrogen in n-type material gives rise to an enhancement in the 2D electron density compared to the 2D hole density as a result of enhanced effective mass due to the effect of nitrogen on conduction band. Our results reveal that effective mass and 2D carrier density can be tailored by nitrogen composition and thermal annealing-induced effects.

PACS

72.00.00; 72.15.Gd; 72.80.Ey  相似文献   
103.
Utilization of renewable resources and development of new processes aimed at converting these materials into value added bio-products are gaining more emphasis. The scope of this study was to optimize supercritical CO2 extraction (SFE) parameters such as pressure, temperature and flow rate for the yields of unsaturated fatty acids from Pistacia terebinthus berries by a Box-Behnken statistical design. All samples were analyzed for fatty acids by GC-FID. The most effective variables were pressure (P < 0.005) and flow rate (P ≤ 0.005). Maximizing the evaluative criteria for dependent variables (oleic acid, linoleic acid and linolenic acid), optimal conditions were determined to be 240 bar, 60 °C and a flow rate of 16 g/min yielding 51.2% oleic acid, 26.5% linoleic acid and 1.0% linolenic acid. The amounts of unsaturated fatty acids in SFE samples (81.3%) were higher than the hexane (74.3%) and were similar to that of cold press samples (80.1%). High concentrations of unsaturated fatty acids can indicate the utilization of the berries as a major dietary source and demonstrate challenges for industrial application of SFE as a green technology.  相似文献   
104.
In this study, cylindrical porous glass tablets were plated by palladium using electroless plating technique. Hypophosphite and Co(II) complexes were used as reducing agents in the prepared plating baths. Experiments were carried out in an especially designed glass vessel in which helium gas was continuously bubbled through the solution to create uniform concentration and to remove hydrogen gas from the surface for the case of hypophosphite-based procedure. XRF analysis of the upper layer of the composite membrane prepared by the hypophosphite-based bath showed a Pd/Si ratio of 4.6. SEM photographs indicated impregnation of Pd into the substrate upto 200 μm. However, the thickness of the dense Pd layer was only about 15 μm. SEM photographs and XRF results showed that hypophosphite-based bath was much more successful than the Co(II) complex-bath in Pd plating. Permeation experiments carried out at different temperatures showed that the contribution of surface diffusion to the permeation was significant at low temperatures and solution–diffusion mechanism was not important in the 40–200 °C temperature range for these membranes. The selectivity ratio for H2/N2 was found to be about 7 at 200 °C.  相似文献   
105.
Journal of Materials Science: Materials in Electronics - The effect of crystallographic texture on the properties of 0.94(Na0.5Bi0.5TiO3)–0.06BaTiO3 (0.94NBT–0.06BT) ceramics were...  相似文献   
106.
Although children and adolescents vary in their chronic tendencies to adaptively versus maladaptively reflect over negative feelings, the psychological mechanisms underlying these different types of self-reflection among youngsters are unknown. We addressed this issue in the present research by examining the role that self-distancing plays in distinguishing adaptive versus maladaptive self-reflection among an ethnically and socioeconomically diverse sample of fifth-grade public schoolchildren. Children were randomly assigned to analyze their feelings surrounding a recent anger-related interpersonal experience from either a self-immersed or self-distanced perspective. They then rated their negative affect and described in writing the stream of thoughts they experienced when they analyzed their feelings. Children's stream-of-thought essays were content analyzed for the presence of recounting statements, reconstruing statements, and blame attributions. Path analyses indicated that children who analyzed their feelings from a self-distanced perspective focused significantly less on recounting the “hot,” emotionally arousing features of their memory (i.e., what happened to me?) and relatively more on reconstruing their experience. This shift in thought content—less recounting and more reconstruing—led children in the self-distanced group to blame the other person involved in their recalled experience significantly less, which in turn led them to display significantly lower levels of emotional reactivity. These findings help delineate the psychological mechanisms that distinguish adaptive versus maladaptive forms of self-reflection over anger experiences in children. Their basic findings and clinical implications are discussed. (PsycINFO Database Record (c) 2011 APA, all rights reserved)  相似文献   
107.
It is a well-established fact that wireless sensor networks (WSNs) are very power constraint networks, but besides this, they are inherently more fault-prone than any other type of wireless network and their protocol design is very application specific. Major reasons for the faults are the unpredictable wireless communication channel, battery depletion, as well as fragility and mobility of the nodes. Furthermore, as traditional protocol design methods have proved inadequate, the cross-layer design (CLD) approach, which allows for interactions between different layers, providing more flexible and energy-efficient functionality, has emerged as a viable solution for WSNs. In this study we define a fault tolerance management module suitable to the requirements, limitations, and specifics of WSNs, encompassing methods for fault detection, fault prevention, fault management, and recovery. The suggested solution is in line with the CLD approach, which is an important factor in increasing the network performance. Through simulations the functionality of the network is evaluated, based on packet loss, delay, and energy consumption, and is compared with a similar solution not including fault management. The results achieved support the idea that the introduction of a unified approach to fault management improves the network performance as a whole.  相似文献   
108.
Bayesian networks (BN) have been used for decision making in software engineering for many years. In other fields such as bioinformatics, BNs are rigorously evaluated in terms of the techniques that are used to build the network structure and to learn the parameters. We extend our prior mapping study to investigate the extent to which contextual and methodological details regarding BN construction are reported in the studies. We conduct a systematic literature review on the applications of BNs to predict software quality. We focus on more detailed questions regarding (1) dataset characteristics, (2) techniques used for parameter learning, (3) techniques used for structure learning, (4) use of tools, and (5) model validation techniques. Results on ten primary studies show that BNs are mostly built based on expert knowledge, i.e. structure and prior distributions are defined by experts, whereas authors benefit from BN tools and quantitative data to validate their models. In most of the papers, authors do not clearly explain their justification for choosing a specific technique, and they do not compare their proposed BNs with other machine learning approaches. There is also a lack of consensus on the performance measures to validate the proposed BNs. Compared to other domains, the use of BNs is still very limited and current publications do not report enough details to replicate the studies. We propose a framework that provides a set of guidelines for reporting the essential contextual and methodological details of BNs. We believe such a framework would be useful to replicate and extend the work on BNs.  相似文献   
109.
The aim of this study is to investigate whether personalization of mathematical word problems affects student achievement; and if it does, to find out whether the outcomes vary depending on computer and class environment in the teaching of mathematics. The sample of the research, conducted in the 2006–2007 fall semester, consists of 90 seventh grade in four sub-groups. During the application in the classroom, paper-based personalized and paper-based non-personalized problems were given. As to the computer environment, web-based personalized and web-based non-personalized problems were presented. After the application, an achievement test was performed as an achievement post-test parallel to the pre-test. The results show no significant difference between the scores of the groups who used personalized materials and the groups who used non-personalized materials. The results also indicate that no significant difference exists between those who studied in the computer-based environment and those in the paper-based environment.  相似文献   
110.
A new formulation for multi-dimensional fractional optimal control problems is presented in this article. The fractional derivatives which are coming from the formulation of the problem are defined in the Riemann–Liouville sense. Some terminal conditions are imposed on the state and control variables whose dimensions need not be the same. A numerical scheme is described by using the Grünwald–Letnikov definition to approximate the Riemann–Liouville Fractional Derivatives. The set of fractional differential equations, which are obtained after the discretization of the time domain, are solved within the Grünwald–Letnikov approximation to obtain the state and the control variable numerically. A two-dimensional fractional optimal control problem is studied as an example to demonstrate the performance of the scheme.  相似文献   
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