Highly Efficient,Bright, and Stable Colloidal Quantum Dot Short‐Wave Infrared Light‐Emitting Diodes

Unbalanced charge injection is deleterious for the performance of colloidal quantum dot (CQD) light‐emitting diodes (LEDs) as it deteriorates the quantum efficiency, brightness, and operational lifetime. CQD LEDs emitting in the infrared have previously achieved high quantum efficiencies but only when driven to emit in the low‐radiance regime. At higher radiance levels, required for practical applications, the efficiency decreased dramatically in view of the notorious efficiency droop. Here, a novel methodology is reported to regulate charge supply in multinary bandgap CQD composites that facilitates improved charge balance. The current approach is based on engineering the energetic potential landscape at the supra‐nanocrystalline level that has allowed to report short‐wave infrared PbS CQD LEDs with record‐high external quantum efficiency in excess of 8%, most importantly, at a radiance level of ≈5 W sr^?1 m², an order of magnitude higher than prior reports. Furthermore, the balanced charge injection and Auger recombination reduction has led to unprecedentedly high operational stability with radiance half‐life of 26 068 h at a radiance of 1 W sr^?1 m^?2.     

Effectiveness of phase I applications for identifying randomly scattered out‐of‐control observations and estimating control chart parameters

Estimation of unknown process parameters with fixed‐size samples are studied in the following. The standard textbook approach for phase I control chart implementation with a Shewhart control chart is evaluated for the case of normally distributed independent observations with random sampling. The charts are simultaneously implemented by generating observations that have a given percentage of randomly scattered out‐of‐control observations. Simulating the phase I steps, where out‐of‐control samples are detected iteratively by determining trial control limits, identifying samples exceeding these limits, and revising the control limits, the standard practice is evaluated in terms of both detection performance and quality of parameter estimates. It is shown that standard phase I control chart implementations with 3‐σ‐limits may perform very poorly in identifying true out‐of‐control observations and providing a reference set of in‐control observations for estimation in some practical settings. A chart design with 2‐σ‐limits is recommended for a successful phase I analysis.     

Proton Transport in Electrospun Hybrid Organic–Inorganic Membranes: An Illuminating Paradox

Chemistry and processing have to be judiciously combined to structure the membranes at various length scales to achieve efficient properties for polymer electrolyte membrane fuel cell to make it competitive for transport. Characterizing the proton transport at various length and space scales and understanding the interplays between the nanostructuration, the confinement effect, the interactions, and connectivity are consequently needed. The goal here is to study the proton transport in multiscale, electrospun hybrid membranes (EHMs) at length scales ranging from molecular to macroscopic by using complementary techniques, i.e., electrochemical impedance spectroscopy, pulsed field gradient‐NMR spectroscopy, and quasielastic neutron scattering. Highly conductive hybrid membranes (EHMs) are produced and their performances are rationalized taken into account the balances existing between local interaction driven mobility and large‐scale connectivity effects. It is found that the water diffusion coefficient can be locally decreased (2 × 10^?6 cm² s^?1) due to weak interactions with the silica network, but the macroscopic diffusion coefficient is still high (9.6 × 10^?6 cm² s^?1). These results highlight that EHMs have slow dynamics at the local scale without being detrimental for long‐range proton transport. This is possible through the nanostructuration of the membranes, controlled via processing and chemistry.     

Non-Newtonian laminar pulsating heat and fluid flow in plane duct

In the present study, laminar pulsating power-law momentum and heat transfer in a uniformly heated plane duct is studied analytically. Assuming that fully developed conditions exist both hydrodynamically and thermally, a perturbation series method is utilized to derive analytical solutions for the momentum and energy balance equations, and the amplitude is prescribed as the perturbation parameter. For varying values of the power-law index ( $n$), representing pseudoplastic, Newtonian, and dilatant fluids, effects of dimensionless amplitude ( $ϵ$) and frequency ( $F$) on periodic and period-averaged friction factor and Nusselt number are obtained. The results obtained for Newtonian fluid are shown to be in good harmony with the corresponding findings in the open literature.