Unsaturated diffusivity functions for concrete derived from NMR images

Deterioration of concrete or reinforcing steel through excessive contaminant concentration is often the result of repeated wetting and drying cycles. At each cycle, the absorption of water carries new contaminants into the unsaturated concrete. Nuclear Magnetic Resonance (NMR) is used with large concrete samples to observe the shape of the wetting profile during a simple one-dimensional wetting process. The absorption of water by dry concrete is modelled by a nonlinear diffusion equation with the unsaturated hydraulic diffusivity being a strongly nonlinear function of the moisture content. Exponential and power functions are used for the hydraulic diffusivity and corresponding solutions of the diffusion equation adequately predict the shape of the experimental wetting profile. The shape parameters, describing the wetting profile, vary little between different blends and are relatively insensitive to subsequent re-wetting experiments allowing universal parameters to be suggested for these concretes.

---

Résumé La détérioration du béton ou du béton armé à travers la concentration excessive de contaminant est souvent le résultat de cycles humides et secs répétés. A chaque cycle, l'absorption de l'eau amène de nouveaux contaminants à l'intérieur du béton non saturé en eau. Pour observer le profil du processus d'humidification, on peut utiliser la Résonance Magnétique Nucléaire (RMN) sur de grands échantillons de béton dans le cadre d'une simple étude unidimensionnelle de ce profil. Il est démontré que l'absorption d'eau par du béton sec peut être précisément modélisée par une équation de diffusion non linéaire où la diffusivité hydraulique non saturée est fonction hautement non linéaire de l'humidité du contenant. Des fonctions exponentielles et puissances peuvent définir la diffusivité hydraulique. Les solutions résultant de l'équation modélisant cette diffusion permettent de prédire avec précision la forme du profil de l'humidification expérimentale. Les paramètres de forme qui décrivent le profil de l'humidification varient peu entre les différents mélanges de béton et sont relativement insensibles à des expériences de réhumidification ultérieures. Cela permet de suggérer que ces bétons suivent des paramètres d'humidification universels.

     

SURFACE ALLOYING OF MILD STEEL BY LASER MELTING OF AN ELECTROLESS NICKEL DEPOSIT CONTAINING CHROMIUM CARBIDES

It is possible to realize surface alloys by laser melting an electroless nickel layer containing chromium carbide particles predeposited on a mild steel substrate. By this way the surface alloy is expected to have not only a high nickel content but also an important chromium content in order to improve the corrosion resistance. The presence of chromium in solid solution results from the dissolution or melting of the carbide particles. Typical laser solidification microstructures are obtained. Dendrites consist of an austenitic Fe-Ni-Cr solid solution and interdendritic regions are constituted by an eutectic mixture containing the same austenitic solid solution and complex Fe, Ni, Cr carbides and phosphides. In comparison with a surface alloy obtained by laser melting of an electroless nickel layer without carbide particles, the corrosion resistance was slightly improved in saline aqueous solutions. The limited effect was due to the fact that the final chromium content in the present experimental conditions was not as high as that initially expected.     

Optical and structural properties of MOVPE grown GaxIn1−xAs/InP strained multiple quantum well atructures

This paper presents a study of the structural and optical properties of strained GaInAs/ InP multiple quantum well (MQW) structures fabricated by LP-MOVPE. The composition of the Ga _x In_1−x As films ranged fromx = 0.17 tox = 1.0 and was determined by sputtered neutral mass spectrometry (SNMS) on thick layers. The structures of the MQW samples with well widths from 1.5 to 5 nm were investigated by high resolution x-ray diffraction (HR-XRD). Simulations of the diffraction patterns showed that transition layers of approximately 2 monolayer (ML) thickness with high lattice mismatch exist at the interfaces. Photoluminescence (PL) measurements indicate well widths of a multiple of a monolayer with local variations of one monolayer. The PL peak energies vary smoothly with the Ga concentration. These results were confirmed by optical absorption measurements.     

Chelated alkoxyalumoxanes and a silica-free binder based on them

Chelated alkoxyalumoxane oligomers have been synthesized through consecutive hydrolysis and alcoholysis of organoaluminum compounds stabilized by compounds capable of keto-enol tautomerism. The chelated alkoxyalumoxanes were used to prepare a silica-free binder for the fabrication of heat-resistant (up to 2050°C), chemically inert corundum ceramic composites. The likely structures of the synthesized preceramic alumoxane oligomers were inferred from physicochemical characterization results (¹H, ¹³C, and ²⁷Al NMR, IR spectroscopy, mass spectrometry, gel-permeation chromatography, thermal analysis, and elemental analysis).     

Web-based systems design: a study of contemporary practices and an explanatory framework based on “method-in-action”

This paper reports the findings of a detailed study of Web-based systems design (WBSD) practices in Ireland based on data collected over a 3-year period (2002–2005), the objectives of which were to (1) contribute towards a richer understanding of the current “real-world” context of WBSD by characterising the profile of a typical project (team size, timeframe, nature of requirements, etc.) and identifying the key challenges, constraints, and imperatives (i.e. “mediating factors”) faced by Web-based system designers, and (2) understand how those contextual parameters and mediating factors influence the activity of WBSD as regards the selection and enactment of whatever design practices are therefore engaged (i.e. the use of methods, procedures, etc.). Data was gathered through a survey which yielded 165 usable responses, and later through a series of semi-structured qualitative interviews. Using grounded theory, an explanatory conceptual framework is derived, based on an extension of the “method-in-action” model, the application of which to WBSD has not been previously investigated in depth. It is proposed that this framework of WBSD issues is valuable in a number of ways to educators, researchers, practitioners, and method engineers.     

Mechanisms in damping of mechanical vibration by piezoelectric ceramic-polymer composite materials

The piezoelectric ceramic (piezoceramic) component of a polymer-piezoelectric ceramic composite converts mechanical energy into electrical energy and this electrical energy is dissipated as heat in a load resistance, R _x, simulated by a shunted resistance, but provided in practice by a conductive polymer composite matrix. The composite therefore dissipates the input mechanical energy via the damping mechanism provided by piezoelectric ceramic-conductive matrix material, as well as the conventional viscoelastic damping provided by the polymer. Mathematical models have been developed to characterize the damping behaviour of the composites, and the maximum damping ratio of composites can be as high as 23%. A two degrees-of-freedom (2DOF) experimental setup was developed to test the validity of the models. The experimental results are in good agreement with the theoretical predictions.     

Repair of Cracked Aluminum Overhead Sign Structures with Glass Fiber Reinforced Polymer Composites

Transportation departments have been using aluminum overhead sign structures since the 1950s. It is well documented that cracks develop in the welds between diagonal and chord members due to fatigue stresses from wind-induced vibration of the slender members. The cracks propagate to complete failure of the members, which can cause collapse of the truss and inflict injuries. The original design of overhead sign structures did not consider fatigue as a limit state. In addition, field welding of aluminum structures for any possible repairs is prohibited. A repair method for the cracked aluminum welded connections between diagonals and chord members using glass fiber reinforced polymer composites (GFRPs) is proposed. The static load carrying capacity of the welded connection, and the cracked connection repaired with GFRP composites are established. The paper describes the surface preparation of the aluminum tubular members, and the architecture and application sequence of the GFRP composite to retrofit the connection. Experimental results are presented from static tests of welded aluminum connections, welded aluminum connections retrofitted with GFRP composites, and new aluminum connections that depend only on GFRP composite elements for their strength. The results from monotonic static tests carried out on cracked welded specimens from actual sign structures show that the retrofitted connection with GFRP reinforcement achieved 1.17 to 1.25 times the capacity of the welded aluminum connection without any visible cracks. This result, and the minimal traffic disruption anticipated in the actual field application, makes this retrofit method a good candidate for implementation.