26.
The solid solutions based on the pyrochlore-type system Bi
2MgNb
2-xTa
xO
9 were formed in the compositional range х = 0–2.0 (Bi
1·6Mg
0·8Nb
1.6-tTa
tO
7.2, t = 0–1.6). The Rietveld method was used to refine the structure for Bi
2MgNb
2-xTa
xO
9 (x = 0, 1.0, 2.0). The increasing tantalum content led to the slight decrease in the cubic unit cell parameters from 10.56934 (4) Å for x = 0 and 10.54607 (3) Å for x = 2 (sp.gr.
Fd-3
m:2). At the same time, tantalum additions suppressed grain growth in the pyrochlore ceramics during sintering and made it possible to obtain materials with an average grain size of 1–2 μm (Bi
1·6Mg
0·8Ta
1·6O
7.2). The increase in the Ta
5+ concentration led to the decrease in the dielectric permeability from 104 (Bi
1·6Mg
0·8Nb
1·6O
7.2) to 20 (Bi
1·6Mg
0·8Ta
1·6O
7.2) at room temperature, while the dielectric loss tangent remained lower than 0.002, which is due to the small grain size and the high porosity of the samples. An increase in temperature has practically no effect on the values of the dielectric permittivity in the entire frequency range. The samples have weak through conductivity. The activation energies of electrical conductivity varied in the range of 0.84–1.00 eV, and the less tantalum, the lower the activation energy. The electrical properties of the samples at 200 Hz to 1 MHz are described by the simplest parallel scheme.
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