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121.
I. A. Zvereva O. I. Silyukov A. V. Markelov A. B. Missyul’ M. V. Chislov I. A. Rodionov D. -Sh. Li 《Glass Physics and Chemistry》2008,34(6):749-755
The processes of phase formation in the Na2CO3-TiO2 and Na2CO3-TiO2-Nd2O3 systems are investigated in the temperature range 600–900°C. The high-temperature solid-phase reactions underlying the process of formation of complex oxide NaNdTiO4 are studied. It is established that the synthesis of the NaNdTiO4 compound occurs through the reaction of the intermediate product Na8Ti5O14 with neodymium oxide in the temperature range 720–780°C. The optimum method is proposed for synthesizing NaNdTiO4, which makes it possible to reduce the temperature of the synthesis, to avoid the formation of impurities, and to obtain the product in a finely dispersed state. 相似文献
122.
E. V. Golikova V. S. Grigor’ev V. I. Kuchuk T. S. Mashchenko L. P. Efimenko A. T. D’yachkova 《Glass Physics and Chemistry》2008,34(5):582-598
The aggregate stability of submicron and nanosized ZrO2 aqueous sols of different origins and different dispersities at pH 3–10 in the KCl concentration range 10?3–10?1 M is investigated by flow ultramicroscopy and photometry. The results obtained are analyzed in the framework of the extended Derjaguin-Landau-Verwey-Overbeek theory and the Muller-Martynov theory of reversible aggregation. The extension of boundary layers of water near the surface of the ZrO2 particles is estimated. 相似文献
123.
A. E. Lapshin Yu. F. Shepelev Yu. I. Smolin E. A. Vasil’eva 《Glass Physics and Chemistry》2008,34(2):182-186
The distribution and structure of tellurium nanoclusters synthesized in crystal channels of the porous silica ZSM-11 are investigated
using the maximum-entropy method and the Rietveld analysis. It is shown that the intercalated tellurium atoms are arranged
in channels of the ZSM-11 zeolite not randomly but in the form of scraps of infinite chains similar to those observed in massive
tellurium. The distances between the nearest neighbor tellurium atoms vary in the range 2.53(4)–2.70(3) ?. The clusters Te4 are formed at the intersections of channels in the structure. These clusters have the form of distorted tetrahedra in which
the tellurium atoms are separated by distances of 2.53(4) and 2.90(4) ?.
Original Russian Text ? A.E. Lapshin, Yu.F. Shepelev, Yu.I. Smolin, E.A. Vasil’eva, 2008, published in Fizika i Khimiya Stekla. 相似文献
124.
V. N. Jmerik A. M. Mizerov T. V. Shubina A. V. Sakharov A. A. Sitnikova P. S. Kop’ev S. V. Ivanov E. V. Lutsenko A. V. Danilchyk N. V. Rzheutskii G. P. Yablonskii 《Semiconductors》2008,42(12):1420-1426
Features of plasma-assisted molecular-beam epitaxy of AlGaN compounds at relatively low temperatures of the substrate (no higher than 740°C) and various stoichiometric conditions for growth of the nitrogen- and metal-enriched layers are studied. Discrete submonolayer epitaxy for formation of quantum wells and n-type blocking layers without varying the fluxes of components was used for the first time in the case of molecular- beam epitaxy with plasma activation of nitrogen for the nanostructures with the Al x Ga1 ? x N/Al y Ga1 ? y N quantum wells. Structural and optical properties of the Al x Ga1 ? x N layers in the entire range of compositions (x = 0–1) and nanostructures based on these layers are studied; these studies indicate that there is photoluminescence at room temperature with minimum wavelength of 230 nm. Based on the analysis of the photoluminescence spectra for bulk layers and nanoheterostructures and their temperature dependences, it is concluded that there are localized states in quantum wells. Using the metal-enriched layers grown on the c-Al2O3 substrates, heterostructures for light-emitting diodes with Al x Ga1 ? x N/Al y Ga1 ? y N quantum wells (x = 0.4–0.5, y = x + 0.15) were obtained and demonstrated electroluminescence in the ultraviolet region of the spectrum at the wavelength of 320 nm. 相似文献
125.
Yu. V. Larichev D. A. Shlyapin P. G. Tsyrul’nikov V. I. Bukhtiyarov 《Catalysis Letters》2008,120(3-4):204-209
Sibunit-supported Ru-catalysts promoted with cesium or rubidium compounds have been comparatively studied with XPS. The cesium promoter interacts both with support and with active component. The absence of the promoter–support interaction in the case of rubidium provides a stronger interaction between promoter and active component compared to the cesium-based catalysts. These differences in the promoter–support and promoter–metal interactions are exhibited when a sequence of ruthenium and alkali introduction are changed. 相似文献
126.
The sorghum distillery residue (SDR) has been an underutilized by‐product with estimated production of 150 ton/day in Kinmen, Taiwan. The objective of this study was to test for any physiological effects of SDR, thus to utilize it as a nutraceutical feed ingredient in diets for cultured fish. Hot air‐dried, wet, and dehulled‐wet sorghum distillery residue showed 63%, 90% and 97% inhibition of the hemoglobin‐catalyzed oxidation of linoleic acid compared to soybean (13%) and rice bran (78%). The feed formulated with 20% wet or dehulled‐wet sorghum distillery residue both showed an antioxidant activity of 68% being higher than the control diet (53%). Feeding these diets to cultured grey mullet for 60 days in summer (temperature ranged 24–30C), resulted in a lower hydroperoxide content in gill tissue, as shown by a chemiluminesence intensity of 1806 or 1409 mV as opposed to 2666 mV for fish fed a control diet. In winter, when the water temperature decreased to 14C, grey mullet fed a diet consisting of 10% dehulled wet sorghum distillery residue had a blood viscosity of 1.9 mPas and a hematocrit value of 33%, in contrast to 3.6 mPas and 41% for control. The blood of the control group started to aggregate in 6 h and showed hemolysis, while the mullet fed dehulled, wet sorghum distillery residue did not show blood aggregation, maintained normal fluidity and erythrocyte membrane integrity. It seems that cultured fish may have the potential as an animal model for prescreening antioxidant and blood thinning effects of food ingredients. 相似文献
127.
Some sulfides of gold and silver: Composition,mineral mineral assemblage,and conditions of formation
Characteristic mineral assemblage and special features of the composition of Au and Ag sulfides of gold-silver deposits have been established. The forms of the occurrence of Au and Ag in the minerals of the early and last stages have been analyzed. The conditions for the formation of uytenbogaardtite and petrovskaite in supergene and low-temperature hydrothermal processes have been considered. A thermodynamic model explaining their genesis in the oxidation zones is presented. 相似文献
128.
129.
The photoluminescence spectra of CdS quantum dots grown in a borosilicate glass by sol-gel technology are recorded and analyzed. It is shown that the photoluminescence spectra of the samples are related to annihilation of free (interior) excitons in the ground state and excited state. Emission associated with the surface states of the quantum dots is detected in the region around 2.7 eV for the first time. The emission is due to recombination of electrons localized at the surface with heavy holes in the free states of the quantum dots. Resonance excitation of the structures makes it possible to reveal the specific features of the localized surface states responsible for the photoluminescence band. The properties of the band are, to a large extent, similar to the properties of the emission bands of both three-dimensional media (amorphous semiconductors and substitution alloys) and two-dimensional systems (quantum wells and superlattices). 相似文献
130.
M. M. Zverev N. A. Gamov D. V. Peregoudov V. B. Studionov E. V. Zdanova I. V. Sedova S. V. Gronin S. V. Sorokin S. V. Ivanov P. S. Kop’ev 《Semiconductors》2008,42(12):1440-1444
Emission characteristics of an electron-beam-pumped Cd(Zn)Se/ZnMgSSe semiconductor laser are studied. The laser’s active region consists of a set of ten equidistant ZnSe quantum wells containing fractional-monolayer CdSe quantum-dot inserts and a waveguide formed by a short-period superlattice with the net thickness of ~0.65 μm. Lasing occurs at room temperature at a wavelength of 542 nm. Pulsed power as high as 12 W per cavity face and an unprecedentedly high efficiency of ~8.5% are attained for the electron-beam energy of 23 keV. 相似文献