Determination of sulphur and copper depth distribution in patina layers using nuclear reaction techniques

A method for Cu and S profiling in patina layers was developed by applying a combination of nuclear reaction analysis (NRA) and Rutherford backscattering spectroscopy (RBS). The copper profiling was performed by using the 1327 keV γ-ray deexciting the third excited state to the ground state of ⁶³Cu produced by the reaction ⁶³Cu(p,p^′γ)⁶³Cu. For the determination of sulphur the 2230 keV γ-ray was used deexciting the first excited state to the ground state of ³²S formed through the reaction ³²S(p,p^′γ)³²S, which exhibits three sharp resonances at projectile energies 3.094, 3.195 and 3.379 MeV. The relevant cross-sections were measured in the energy range between 3.0 and 3.7 MeV in steps of 20 keV at 125° to the incident proton beam direction. The technique was tested using artificially produced and natural copper patina layers. Supporting information on the depth distribution of the constituent elements of the patina samples was obtained by p-RBS (E_p: 1.5 MeV, θ: 160°).     

Biomimetic Omnidirectional Antireflective Glass via Direct Ultrafast Laser Nanostructuring

Here, a single‐step, biomimetic approach for the realization of omnidirectional transparent antireflective glass is reported. In particular, it is shown that circularly polarized ultrashort laser pulses produce self‐organized nanopillar structures on fused silica (SiO₂). The laser‐induced nanostructures are selectively textured on the glass surface in order to mimic the spatial randomness, pillar‐like morphology, as well as the remarkable antireflection properties found on the wings of the glasswing butterfly, Greta oto, and various Cicada species. The artificial structures exhibit impressive antireflective properties, both in the visible and infrared frequency ranges, which are remarkably stable over time. Accordingly, the laser‐processed glass surfaces show reflectivity smaller than 1% for various angles of incidence in the visible spectrum for s–p linearly polarized configurations. However, in the near‐infrared spectrum, the laser‐textured glass shows higher transmittance compared to the pristine. It is envisaged that the current results will revolutionize the technology of antireflective transparent surfaces and impact numerous applications from glass displays to optoelectronic devices.     

Spatio-temporal evolution of the deformation around the Rio-Patras fault (Greece) observed by synthetic aperture radar interferometry from 1993 to 2017

We analysed the ground deformation across two blocks defined by the Rio-Patras fault from 1993 to 2017 using multi-temporal Synthetic Aperture Radar Interferometry (InSAR) techniques. Our main objective was to contribute to the assessment of seismic hazard near the large city of Patras. Multiple data-sets were used, each one covering different temporal periods. Descending and ascending acquisitions, providing different viewing geometries contribute to fully determine the ground displacement in 3D. The data-sets used are from the European Space Agency’s (ESA) European Remote Sensing (ERS), Environmental Satellite (ENVISAT) and SENTINEL-1 as well as German Aerospace Center (DLR) ’s TERRASAR-X missions. Considering ESA’s missions covering both acquisition geometries and long periods, the southern block, showing lack of a sufficient number of scatterers does not allow the displacement characterization. In contrary, the northern block is characterized by a high number of scatterers having values of maximum likehood ranging from ?3.5 to ?4.3 mm year^?1 for ascending geometry and from ?1.6 to ?2.7 mm year^?1 for the descending one. The fact that both geometries show negative values of displacements are consistent with downlift movement and at the same time the quantitative differentiation probably indicates an horizontal component as well.     

Stochastic model for BOD and DO in streams when the velocity is random and distance‐dependent

The stochastic model studied in this paper is a random differential equation of the form X(t) = A(t) X(t) = Y(t), t ≥ 0, with initial conditions X₀ = X(0). X(t) is a vector with biochemical oxygen demand (BOD) and dissolved oxygen (DO) at a distance t downstream from the pollution source for components. The velocity of the stream is incorporated into the vector A(t) and is random and distance dependent. The inhomogeneous term Y(t) and the initial conditions are random vectors. Therefore, this model contains random initial conditions, random coefficients and random inhomogeneous terms. Simulated trajectories of the BOD and DO are computed.     

Durability of particleboards made from wood particles chemically modified with propionic anhydride: results after six years in ground stake-test

Propionylated particleboard stakes with 12.2% propionyl content were tested in ground contact in Western Greece. The stakes showed severe attack after five years of testing and total decay after six years, whereas the unmodified boards showed total decay during the fourth year of testing.     

Implementation of a high speed frequency synthesizer employing a dual input phase accumulator

We present a new PLL based frequency synthesizer, in which we have replaced the conventional phase frequency detector and the dividers (programmable counters) with a sequential dual input phase accumulator (DIPA), consisting of a digital circuit employing adders, registers and a ladder. The main feature of the DIPA is that the two input frequencies are not required to be normalized (divided down) to the step frequency of the synthesizer. Instead, the two different high frequencies, that is the reference and the output frequency of the synthesizer, are applied directly. The DIPA samples and normalizes their phases at very high rates, calculates their phase difference, producing an output that consists of a dc component proportional to the phase difference and harmonics of the two input high frequencies. These harmonics are high frequencies and can easily be rejected by a wide bandwidth filter of the loop, without affecting the high convergence speed of the loop. Moreover, these harmonics do not generate spurs near the output frequency. The resolution of the DIPA based synthesizer depends only on the length of the digital word of the DIPA, and its convergence speed depends on the lower of the two input frequencies. The output of the DIPA is a linear function of the phase difference of the two input frequencies and its dynamic range exceeds the limit of ±2π that governs the conventional phase detectors. Thus, the proposed frequency synthesizer based on the DIPA has low phase noise, no spurs nearby the output frequency, high resolution and fast convergence rate. Additionally, the output frequency can be digitally modulated under the control of the closed loop, either by phase or frequency modulation.     

Optimization methodology of dynamic data structures based on genetic algorithms for multimedia embedded systems

Modern multimedia application exhibit high resource utilization. In order to efficiently run this kind of applications in embedded systems, the dynamic memory subsystem needs to be optimized. A key role in this optimization is played by the dynamic data structures that reside in every real-life application. This paper presents a novel and automated way to optimize dynamic data structures. The search space is pruned using genetic algorithms that converge to the best multilayered data structure implementation for the targeted applications.     

Low-frequency scattering from perfectly conducting spheroidal bodies in a conductive medium with magnetic dipole excitation

Inductive electromagnetic means that are currently employed in the exploration of the Earth’s subsurface and embedded voluminous bodies often call for an intensive use, primary at the modeling stage and later on at the inversion stage, of analytically demanding tools of field calculation. Under the aim of modeling implementation, this contribution is concerned with some interesting aspects of the low-frequency interaction of arbitrarily orientated (i.e. three-dimensional) time-harmonic magnetic dipoles, with 3-D perfectly conducting spheroidal bodies embedded in an otherwise homogeneous conductive medium. For many practical applications involving buried obstacles such as Earth’s subsurface electromagnetic probing at low-frequency or any other physical cases (e.g. geoelectromagnetics), non-axisymmetric spheroidal geometry approximates sufficiently such kind of metallic shapes. On the other hand, our analytical approach deals with prolate spheroids, since the corresponding results for the oblate spheroidal geometry can be readily obtained through a simple transformation. The particular physical model concerns a solid impenetrable (metallic) body under a magnetic dipole excitation, where the scattering boundary value problem is attacked via rigorous low-frequency expansions for the incident, scattered and total electric and magnetic fields in terms of positive integral powers of (ik), that is (ik)ⁿ for n ? 0, where k stands for the complex wavenumber of the exterior medium. The purpose of the modeling is to contribute to a simple yet versatile tool to infer information on an unknown body from measurements of the three-component electric and magnetic fields nearby. Our goal is to obtain the most important terms of the low-frequency expansions of the electromagnetic fields, that is the static (for n = 0) and the dynamic (n = 1, 2, 3) terms. In particular, for n = 1 there are no incident fields and thus no scattered ones, while for n = 0 the Rayleigh electromagnetic expression is easily obtained in terms of infinite series. Emphasis is given on the calculation of the next two non-trivial terms (at n = 2 and at n = 3) of the aforementioned fields. Consequently, those are found in closed form from exact solutions of coupled (at n = 2, to the one at n = 0) or uncoupled (at n = 3) Laplace equations and they are given in compact fashion, as infinite series expansions for n = 2 or finite forms for n = 3. Nevertheless, the difficulty of the Poisson’s equation that has to be solved for n = 2 is presented, whereas our analytical approach demands the use of the well-known cut-off method in order to obtain an analytical closed solution. Finally, this research adds useful reference results to the already ample library of scattering by simple shapes using analytical methods.     

Microstructure effect on the properties of a commercial low-fusing dental porcelain

The aim of this study was to investigate the effect of firing cycle on a dental porcelain microstructure in order to correlate microstructure changes with mechanical and thermal properties. A commercial low-fusing dental porcelain powder (Omega 900, Vita) was investigated for this purpose. The powder was treated at different temperatures in the range 750–1000 °C. The fired samples were characterized in terms of their morphology and microstructure, and their mechanical and thermal properties were evaluated. The results showed that firing temperature affects porcelain microstructure influencing significantly in this way both the mechanical properties and the thermal expansion coefficient of the fired objects. Firing at 800 °C led to a homogeneous structure. After treatment at this temperature, the leucite crystals exhibit their maximum concentration and they are well dispersed into the glassy phase. As a consequence the optimum mechanical strength and the maximum thermal expansion coefficient are observed in these samples.