Effect of specimen size in determining ductile to brittle transition temperature

Ductile to brittle transition temperature (DBTT) for 9Cr–1Mo steel has been determined from Charpy impact testing for full size and subsized specimens. DBTT was obtained at various percentage of upper shelf energy (USE). Assuming that most of the energy is spent in crack initiation, notch root volumes of subsized specimens (V_NS) were normalised with full size specimen (V_NF), and a power law relationship between DBTT and notch root volume has been established. From finite element method, it is observed that the sum of von Mises stress (σ_eq) and hydrostatic stress (σ_h) reaches ～2400 MPa (fracture stress, σ_f*) as the specimen dimension decreases at a temperature corresponding to 33% USE. This corresponds to ～68 J of full size specimen used in the determination of nil ductility transition temperature.     

Performance of Choline-Based Deep Eutectic Solvents in the Extraction of Tocols from Crude Palm Oil

Deep eutectic solvents are emerging green solvents that have potential in many separation processes. This study investigates the performance of choline‐based deep eutectic solvents in the extraction of tocopherols and tocotrienols (collectively known as tocols) from palm oil, a major natural source of tocols. Deep eutectic solvents comprised of choline chloride salt and selected carboxylic acids as hydrogen bond donors were prepared and used in the extraction of tocols from crude palm oil by liquid–liquid extraction. Tocols concentration in the extracted product was at least double that in the control (8671 mg/kg compared to 3285 mg/kg, respectively). Increasing the amount of the deep eutectic solvents increased the tocols concentration in the extracted product up to 18,525 mg/kg, but the yields lowered from 4 % to less than 1 %. The tocols profile was significantly improved by the increase of the tocotrienols fraction in the products from 80.8 to 99.8 %. This study showed that unique interaction between the selected deep eutectic solvents with the tocols make it possible to selectively separate individual tocols in palm oil, where products with fractions rich in tocotrienols and low in tocopherols (particularly α‐tocopherol) are favorable.     

Adsorption of chromium (VI) on functionalized and non-functionalized carbon nanotubes

We did a comparative study on the adsorption capacity of Cr (VI) between functionalized carbon nanotubes (CNTs) and non-functionalized CNTs. The statistical analysis reveals that the optimum conditions for the highest removal of Cr (VI) are at pH 9, with dosage 0.1 gram, agitation speed and time of 120 rpm and 120 minutes, respectively. For the initial concentration of 1.0 mg/l, the removal efficiency of Cr (VI) using functionalized CNTs was 87.6% and 83% of non-functionalized CNTs. The maximum adsorption capacities of functionalized and non-functionalized CNTs were 2.517 and 2.49 mg/g, respectively. Langmuir and Freundlich models were adopted to study the adsorption isotherm, which provided a K _L and K _F value of 1.217 L/mg and 18.14 mg^1?n L ⁿ /g functionalized CNT, while 2.365 L/mg and 2.307 mg^1?n L ⁿ /g for non-functionalized CNTs. This result proves that functionalized CNTs are a better adsorbent with a higher adsorption capacity compared with the non-functionalized CNTs.     

Fabrication of three-dimensional nano, micro and micro/nano scaffolds of porous poly(lactic acid) by electrospinning and comparison of cell infiltration by Z-stacking/three-dimensional projection technique

The use of electrospun extracellular matrix (ECM)-mimicking nanofibrous scaffolds for tissue engineering is limited by poor cellular infiltration. The authors hypothesised that cell penetration could be enhanced in scaffolds by using a hierarchical structure where nano fibres are combined with micron-scale fibres while preserving the overall scaffold architecture. To assess this, we fabricated electrospun porous poly(lactic acid) (PLA) scaffolds having nanoscale, microscale and combined micro/nano architecture and evaluated the structural characteristics and biological response in detail. Although the bioactivity was intermediate to that for nanofibre and microfibre scaffold, a unique result of this study was that the micro/nano combined fibrous scaffold showed improved cell infiltration and distribution than the nanofibrous scaffold. Although the cells were found to be lining the scaffold periphery in the case of nanofibrous scaffold, micro/nano scaffolds had cells dispersed throughout the scaffold. Further, as expected, the addition of nanoparticles of hydroxyapatite (nHAp) improved the bioactivity, although it did not play a significant role in cell penetration. Thus, this strategy of creating a three-dimensional (3D) micro/nano architecture that would increase the porosity of the fibrous scaffold and thereby improving the cell penetration, can be utilised for the generation of functional tissue engineered constructs in vitro.     

Phenol Removal from Aqueous Solutions by Tamarind Nutshell Activated Carbon: Batch and Column Studies

Activated carbons prepared from tamarind nutshell, an agricultural waste by‐product, have been examined for the removal of phenol from aqueous solutions. The activated carbon was prepared by sulfuric acid activation. Both batch and column studies were performed for the sorption of phenol. The kinetic data were fitted to the models of Lagergren, pseudo‐second‐order and intraparticle diffusion, and closely followed the pseudo‐second‐order chemisorption model. The Freundlich and Langmuir isotherm models were well fitted. The solution pH greatly affects the sorption process. The column study results indicate that the sorption of phenol is dependent on the flow rate, the inlet phenol concentration as well as on the particle size of the adsorbent.     

Electrochemical behavior of fission palladium in 1-butyl-3-methylimidazolium chloride

Electrochemical behavior of palladium (II) chloride in 1-butyl-3-methylimidazolium chloride has been investigated by various electrochemical transient techniques using glassy carbon working electrode at different temperatures (343-373 K). Cyclic voltammogram consisted of a prominent reduction wave at −0.61 V (vs. Pd) due to the reduction of Pd(II) to Pd, and two oxidation waves at −0.26 and 0.31 V. A nucleation loop is observed at −0.53 V. The diffusion coefficient of palladium (II) in bmimCl (∼10⁻⁷ cm²/s) was determined and the energy of activation (63 kJ/mol) was deduced from the cyclic voltammograms at various temperatures. Nucleation and growth of palladium on glassy carbon working electrode has been investigated by chronoamperometry and chronopotentiometry. The growth and decay of chronocurrents measured for palladium deposition has been found to follow the instantaneous nucleation model with three-dimensional growth of nuclei. The surface morphology of the deposit obtained at various applied potentials revealed the formation of dendrites immediately after nucleation and spread in all the directions with time.     

Influence of the macrotidal environment on the source to sink pathways of suspended flux in the Gulf of Kachchh,India: evidence from the Ocean Colour Monitor (IRS‐P4)

A series of tide‐synchronous satellite images, obtained from the Ocean Colour Monitor (OCM) onboard the Indian Remote Sensing Satellite (IRS‐P4), in situ measurements and hydrodynamic model simulations were used to describe dispersal pathways and sources of total suspended matter (TSM) in the Gulf of Kachchh, a macrotidal system with insignificant freshwater inputs. Strong alongshore currents are prevalent at the mouth that move in (out) clockwise during flood (ebb) and undergo cyclic, dynamic changes with the tidal phases. The Gulf, unlike other regions of the Indian coastline, has dynamic turbidity that is zonal (very high in the outer Gulf and in the creeks of the Gulf), particularly during flooding, and reduced in the central region throughout the entire tidal cycle. From this dynamic turbidity with regard to the prevalent currents, it is deduced that inland amplifying flood currents draw in TSM‐rich offshore waters into the Gulf, and are the major source of turbidity in the outer regions of the Gulf. In the inner Gulf, because of these high‐magnitude currents, scouring of the creek bed leads to resuspension to create higher turbidity. Most of the scoured flux sinks off the mouths of these creeks because of the fanning out of ebbing flows from the narrow creeks into the wider Gulf. The areas under specific influence of different sources of turbidity are delineated schematically.     

A Predictably Low-Leakage ASIC Design Style

In this paper, we describe a new low-leakage standard cell based application-specific integrated circuit (ASIC) design methodology. This design is based on the use of modified standard cells, designed to reduce leakage currents (by almost two orders of magnitude) in standby mode and also allow precise estimation of leakage current. For each cell in a standard cell library, two low-leakage variants of the cell are designed. If the inputs of a cell during the standby mode of operation are such that the output has a high value, we minimize the leakage in the pull-down network, and similarly we minimize leakage in the pull-up network if the output has a low value. In this manner, two low-leakage variants of each standard cell are obtained. While technology mapping a circuit, we determine the particular variant to utilize in each instance, so as to minimize leakage of the final mapped design. We have performed experiments to compare placed-and-routed area, leakage and delays of this new methodology against Multithreshold CMOS (MTCMOS) and a regular standard cell based design style. The results show that our new methodology (which we call the "HL" methodology) has better speed and area characteristics than MTCMOS implementations. The leakage current for HL designs can be dramatically lower than the worst-case leakage of MTCMOS based designs, and two orders of magnitude lower than the leakage of traditional standard cells. An ASIC design implemented in MTCMOS would require the use of separate power and ground supplies for latches and combinational logic, while our methodology does away with such a requirement. Another advantage of our methodology is that the leakage is precisely estimable, in contrast with MTCMOS. Our primary contribution in this paper is a new low leakage design style for static CMOS designs. In addition, we also discuss techniques to reduce leakage in dynamic (domino logic) designs     

Failure analysis of an ammonia refrigerant condenser tube

A detailed failure analysis was conducted on an ammonia refrigerant condenser tube component that failed catastrophically during its initial hours of operation. Evidence collected clearly demonstrated that the weld between a pipe and a dished end contained a sharp unfused region at its root (lack of penetration). Component failure had started from this weld defect. The hydrogen absorbed during welding facilitated crack initiation from this weld defect during storage of the component after welding. Poor weld toughness at the low operating temperature facilitated crack growth during startup, culminating in catastrophic failure as soon as the crack exceeded critical length.