A Modified Method for the Determination of N‐Nitrosodiethanolamine in Coconut Diethanolamide Using HPLC with Dual‐Wavelength UV–Vis Detector

A simple and novel method based on high‐performance liquid chromatography with dual‐wavelength ultraviolet detection at 234 and 254 nm has been developed for the determination of underivatized N‐nitrosodiethanolamine in coconut diethanolamide. The correlation coefficient obtained shows that the method is correct.     

Investigations of the Failure in Boilers Economizer Tubes Used in Power Plants

In this study, failure of a high pressure economizer tube of a boiler used in gas-Mazut combined cycle power plants was studied. Failure analysis of the tube was accomplished by taking into account visual inspection, thickness measurement, and hardness testing as well as microstructural observations using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and x-ray diffraction (XRD). Optical microscopy images indicate that there is no phase transformation during service, and ferrite-pearlite remained. The results of XRD also revealed Iron sulfate (FeSO₄) and Iron hydroxide sulfate (FeOH(SO₄)) phases formed on the steel surface. A considerable amount of Sulfur was also detected on the outer surface of the tube by EDS analysis. Dew-point corrosion was found to be the principal reason for the failure of the examined tube while it has been left out-of-service.     

Non-invasive monitoring of water content and textural changes in clay-rocks using spectral induced polarization: A laboratory investigation

Seven well-characterized clay-rocks have been taken from three test sites to perform spectral induced polarization (SIP) measurements during desiccation of these samples. These test sites include (1) the Tournemire site (IRSN) located in south of France, (2) The Bure test site (ANDRA) located in west of France, and (3) the Super-Sauze earthflow located in south western of France. We dried the samples at ambient temperature followed by heating between 65 °C and 105 °C. The quadrature conductivity, at very low-frequency, was able to discriminate between the loss of free water from the macropores and the loss of water in the micropores associated with textural changes. The calcite and quartz grain size distributions had a significant effect on the low-frequency spectrum. The inversion of our SIP data demonstrated that the generalized Cole–Cole model is an appropriate empirical and practical model for monitoring changes in water content of clay-rocks.     

Putting labs online with Web services

This paper describes an online experiment system that is based on Web services designed to support interoperable, machine-to-machine interaction over a network, and can also integrate heterogeneous resources. A service-oriented architecture was devised for online experiment systems, enabled by Web service protocols, and a methodology for wrapping the operations of the instruments into Web services. Although these methods aren't suitable for time-critical missions or applications that need real-time control, they do work for controlling standard commercial instruments over low-speed or unreliable communication networks. Using this framework, an online experiment system for students can be created that incorporates a great variety of instruments and that users can access without installing special software.     

Study on novel poly (vinyl pyrrolidone) doped MWCNTs/polyrhodanine nanocomposites: Synthesis,characterization, and thermal performance

In this paper, poly (vinyl pyrrolidone) (PVP) doped multiwall carbon nanotubes (MWCNTs/polyrhodanine), were synthesized through one-step chemical oxidative polymerization of rhodanine monomers on the surface-modified carbon nanotubes. Characterization of MWCNTs/polyrhodanine was conducted by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transforms infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and EDX spectrum analyses in which the results confirmed the successful formation of MWCNTs/polyrhodanine. In addition, to investigate the thermal properties of samples, thermogravimetric analysis (TGA) was employed, and results exhibited significant improvement in the nanocomposite thermal stability due to the addition of MWCNTs with reinforcement effect in polymer matrix.     

Modelling Energy Dissipation Over Stepped-gabion Weirs by Artificial Intelligence

The hydraulics of energy dissipation over stepped-gabion weirs is investigated by carrying out a series of laboratory experiments, building models to explain the experimental data, and testing their robustness by using the data reported by other researchers. The experiments comprise: six different stepped-gabion weirs tested in a horizontal laboratory flume, a wide range of discharge values, two weir slopes (V:H): 1:1 and 1:2, and gabion filling material gravel size (porosity equal to 38 %, 40 % and 42 %). These experimental setups were selected to ensure the development of both the nappe and skimming flow regimes within the measured dataset. The models developed for computing energy dissipation over stepped-gabion weirs comprise: multiple regression equations based on dimensional analysis theory, Artificial Neural Network (ANN) and Gene Expression Programming (GEP). The analysis shows that the measured data capture both flow regimes and the transition in between them and above all, and by using all of the data, it may be possible to identify the range of each regime. Energy dissipation modelled by the ANN formulation is successful and may be recommended for reliable estimates but those by GEP and regression analysis can still serve for rough-and-ready estimates in engineering applications.     

Fault detection in non-linear systems based on type-2 fuzzy logic

This paper presents a new method for fault detection (FD) based on interval type-2 fuzzy sets. The main idea is based on a confident span using interval type-2 fuzzy systems. An estimate for upper and lower bounds of output has been taken using the designing of an optimal fuzzy system through clustering. Finally the method has been tested in two non-linear systems, a two-tank with a fluid flow and pH neutralisation process, and it is compared with a well-known method named ANFIS. Furthermore, the mathematical model and the results of simulations prove the effectiveness, usefulness and applications of our new method.     

Theoretical Investigation of Ethanol Conversion to Ethylene over H–ZSM–5 and Transition Metals–Exchanged ZSM–5

Abstract  

Reaction mechanisms of ethanol conversion to ethylene over H–ZSM–5, Cu–ZSM–5, Ag–ZSM–5, and Au–ZSM–5 catalysts were investigated using density functional theory calculations. Energetics, thermodynamic quantities, rate and equilibrium constants of ethanol conversion to ethylene were obtained using the B3LYP/LanL2DZ method. The catalytic abilities of these catalysts on the reaction rates of ethanol conversion to ethylene are in order: Au–ZSM–5 > > Ag–ZSM–5 > H–ZSM–5 > > Cu–ZSM–5.     

Estimating botnet virulence within mathematical models of botnet propagation dynamics

Mathematical models of botnet propagation dynamics are increasingly deemed to have potential for significant contribution to botnet mitigation. Botnet virulence, which comprises network vulnerability rate and network infection rate, is a key factor in those models. In this paper we discuss a practical approach that draws on epidemiological models in biology to estimate the botnet virulence in a network. Our research provides mathematical models of botnet propagation dynamics with concrete measures of botnet virulence, which make those models practical and hence employable in mitigation of real world botnets in a timely fashion. The approach is based on random sampling and follows a novel application of statistical learning and inference in a botnet-versus-network setting. We have implemented this research in the Matlab programming language. In this paper, we discuss an experimental evaluation of the effectiveness of this research with respect to botnet propagation dynamics realistically simulated in a GTNetS network simulation platform.