A pilot-scale fireside deposit study of co-firing Cynara with two coals in a fluidised bed

Costs of biofuel production from energy crops can be reduced by applying the crop residues in heat and power production. Perennial herbaceous crops like Cynara cardunculus L. are challenging fuels because they tend to have high ash and chlorine contents. Coals, however, are often rich in aluminium silicates and sulphur, and co-firing of these biofuels with coal could be expected to reduce operational problems. In addition, CO₂ emissions are lower than during coal firing alone. Blends of Cynara and two coals, South African bituminous and Spanish sub-bituminous coal, were combusted in a 20 kW bubbling bed pilot reactor to ascertain the ability of the coals to reduce operational problems by alkali capture. The Cynara fuel sample contained almost 2 wt% chlorine. The South African coal was rich in kaolinite capable of capturing alkalies from chlorides to produce alkali aluminium silicate and HCl. The Spanish coal was rich in sulphur (mostly present as FeS₂), and produced high concentrations of SO₂ that partially oxidised to SO₃. The SO₃ can capture alkalies from chlorides by sulphation. Up to 30% Cynara, on energy basis, could be co-fired with Spanish coal without operational problems, whereas the same percentage of Cynara with South African coal led to strong Cl deposition. Co-firing of Cynara with both coals resulted in high HCl emissions (up to 1500 mg/Nm³ in 6% O₂). In addition, co-firing of the Spanish coal led to very high SO₂ emissions (up to about 16,000 mg/N m³ in 6% O₂). Thus, a power plant capable of firing such blends must be equipped with flue gas cleaning equipment for effective SO₂ and HCl capture in the flue gas channel after the superheaters, or else the quality of the Cynara must be markedly improved by changing the harvesting technology and fertilisers, which could be major sources of high ash and chlorine content in the fuel.     

避风堂孤儿院的图书屋

在《苹果酒屋里的规则》这部以孤儿院孩子为主角的小说里,勤于思考的拉齐医生把孤儿们称为缅因州的王子,新英格兰的国王,并坚持在每个晚上的同一时间为他们朗读。     

Isomerisation of α-Pinene Oxide to Campholenic Aldehyde Over Supported Ionic Liquid Catalysts (SILCAs)

The isomerisation of α-pinene oxide to campholenic aldehyde, an expensive ingredient utilized by e.g. flavor industry, was studied over Supported Ionic Liquid Catalysts (SILCAs) consisting of catalytically active species residing in ionic liquid. The ionic liquid, in turn, was immobilized on a solid support material. SILCAs were demonstrated as efficient catalysts for the transformation of α-pinene oxide into campholenic aldehyde, with the product distribution and activity being dependent on the nature of the ionic liquid.

     

Bromine as an ash forming element in a fluidised bed boiler combusting solid recovered fuel

Plastic materials are the main sources of chlorine in solid recovered fuels (SRF). Chlorine is attributed to be the main initiator of slagging, fouling and corrosion in biomass and waste combustion as it lowers the melting point of ash forming matter and reacts chemically with the heat transfer surface steels. SRF may also contain sources of bromine in the form of brominated flame retardants (BFRs) applied in many plastics and textiles. Results presented in this paper from an experimental campaign at an 80 MW_th bubbling fluidised bed (BFB) boiler show that bromine is behaving in a similar manner as chlorine: bromine was found at the corrosion front in boiler membrane wall tubes, and as water soluble salts in aerosol samples collected from the furnace and electrostatic precipitator (ESP) ash. It is evident from these results and the data in the literature that most of the salts of bromine are, by both their fate and physical and chemical properties, similar to those of chlorine. It can be concluded that it if there is a source of bromine in the fuel corrosive high vapour pressure bromides can be formed analogously to chlorides.     

Product category description for web-shopping in e-commerce

In this paper, we focus on the web-shopping activity and on ways to improve the quality of the information available to consumers. We describe a tool, called a product space map, for the presentation of information about a product category which can help consumers in making purchasing decisions. Using this tool we first provide a clustering or segmentation of a product line, that is, 27-inch televisions, into price categories such as low end, moderate and high end. Once having this partitioning we then use the idea of linguistic summaries to describe the properties of each category with respect to relevant features. An example of such a summary is “Most TV's in the high price category provide extremely high resolution.” With the aid of such information it becomes much easier for consumers to understand the product line, see what they are getting for their money, and more easily and confidently locate products that are of particular value for the money. Considerable use is made of fuzzy set technology to provide the ability to describe the information in a way, using linguistic expressions, that is particularly consumer friendly. © 2001 John Wiley & Sons, Inc.     

Bringing Knowing-When and Knowing-What Together: Periodically Tuned Categorization and Category-Based Timing Modeled with the Recurrent Oscillatory Self-Organizing Map (ROSOM)

The study addresses the cyclically temporal aspect of sequence recognition, storage and recall using the Recurrent Oscillatory Self-Organizing Map (ROSOM), first introduced by Kaipainen, Papadopoulos and Karhu (1997). The unique solution of the network is that oscillatory States are assigned to network units, corresponding to their `readiness-to-fire'. The ROSOM is a categorizer, a temporal sequence storage system and a periodicity detector designed for use in an ambiguous cyclically repetitive environment. As its external input, the model accepts a multidimensional stream of environment-describing feature configurations with implicit periodicities. The output of the model is one or a few closed cycles abstracted from such a stream, mapped as trajectories on a two-dimensional sheet with an organization reminiscent of multi-dimensional scaling. The model's capabilities are explored with a variety of workbench data.     

Railroad capacity tools and methodologies in the U.S. and Europe

A growing demand for passenger and freight transportation, combined with limited capital to expand the United States (U.S.) rail infrastructure, is creating pressure for a more efficient use of the current line capacity. This is further exacerbated by the fact that most passenger rail services operate on corridors that are shared with freight traffic. A capacity analysis is one alternative to address the situation and there are various approaches, tools, and methodologies available for application. As the U.S. continues to develop higher speed passenger services with similar characteristics to those in European shared-use lines, understanding the common methods and tools used on both continents grows in relevance. There has not as yet been a detailed investigation as to how each continent approaches capacity analysis, and whether any benefits could be gained from cross-pollination. This paper utilizes more than 50 past capacity studies from the U.S. and Europe to describe the different railroad capacity definitions and approaches, and then categorizes them, based on each approach. The capacity methods are commonly divided into analytical and simulation methods, but this paper also introduces a third, “combined simulation–analytical” category. The paper concludes that European rail studies are more unified in terms of capacity, concepts, and techniques, while the U.S. studies represent a greater variation in methods, tools, and objectives. The majority of studies on both continents use either simulation or a combined simulation–analytical approach. However, due to the significant differences between operating philosophy and network characteristics of these two rail systems, European studies tend to use timetable-based simulation tools as opposed to the non-timetable-based tools commonly used in the U.S. rail networks. It was also found that validation of studies against actual operations was not typically completed or was limited to comparisons with a base model.

     

The effect of the impingement air drying on print mottle and other coated paper properties

The objective of this work is to study the influence of effective initial impingement drying (one-sided high intensity air impingement drying) on the quality of blade-coated paper and to compare it with IR (infrared) drying. A specially designed 1.31 m-long impingement air dryer unit was installed 2 m downstream of the coating station of the pilot coater for more efficient paper drying. Different drying strategies using different combinations of three impingement temperatures (300, 450 and 550 °C) and three impingement velocities (25, 40 and 60 m/s) were tested in the impingement dryer unit to determine the influence of drying on paper quality. Drying effects are compared with those obtained with two rows of an electrical IR at same position. The results of the investigation indicate that backtrap (BT) mottle was reduced with increasing drying power of the impingement dryer. The paper quality parameters, gloss and smoothness of the coated samples were better with air-drying than IR drying. The interesting finding of this study is the improvement of mottle with a high drying rate in the consolidation phase for coated WF (wood-free) paper. Drying section configuration with effective impingement drying unit directly after the coating station showed good performance and is proposed as a possible solution for the future dryer designs.     

Contribution à une meilleure approche dans la détection et l’estimation de la fréquence laryngienne

Combined use of different laryngeal frequency information furnished simultaneously by short-time Fourier transform and by instantaneous frequency distribution function leads to a higher precision of the frequency estimation. Two parameters are defined : the spectral dissymmetry coefficient and the “inter-correlation function. These parameters give a clear insight into the nature of the analysed speech windows, leading to an exact detection of the voicing feature. The exploitation of the sensibility with respect to the nature of the speech windows enables the extraction of voiced/mixed/unvoiced decision and also the specification of the mixed source.