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81.
Aly Valderrama Jaime Tapia Patricio Peñailillo Danny E. Carvajal 《Water and Environment Journal》2013,27(3):293-300
The aim of this work was to evaluate the utility of Azolla filiculoides growing in a hydroponic system for the phytoremediation of continental water polluted with cadmium and copper during 7 days of exposure. Cadmium and copper chloride were added to the medium at concentrations of 0.5–10 mg/L and 0.1–25 mg/L, respectively. Cadmium and copper levels were measured in each plant using flame atomic absorption spectrophotometry. The analytical methodology used to measure cadmium and copper levels was validated with standard reference material (SRM) – 1570 (spinach) National Institute of Standards and Technology. The results indicated that cadmium and copper phytoremediation was statistically significant with a maximum increase in plant tissue of 1623.20 and 6013.1 μg/g, respectively. This photosynthetic efficiency was chronically damaged when Azolla filiculoides were exposed to 10 mg/L of Cd and 25 mg/L of Cu. The Azolla plants were not affected in the other phytoremediation treatments with copper. 相似文献
82.
Mubarak Ali Ishtiaq Ahmed Patricio Ramirez Saima Nasir Christof M. Niemeyer Salvador Mafe Wolfgang Ensinger 《Small (Weinheim an der Bergstrasse, Germany)》2016,12(15):2014-2021
The label‐free detection of pyrophosphate (PPi) anions with a nanofluidic sensing device based on asymmetric nanopores is demonstrated. The pore surface is functionalized with zinc complexes based on two di(2‐picolyl)amine [bis(DPA)] moieties using carbodiimide coupling chemistry. The complexation of zinc (Zn2+) ion is achieved by exposing the modified pore to a solution of zinc chloride to form bis(Zn2+–DPA) complexes. The chemical functionalization is demonstrated by recording the changes in the observed current–voltage (I–V) curves before and after pore modification. The bis(Zn2+–DPA) complexes on the pore walls serve as recognition sites for pyrophosphate anion. The experimental results show that the proposed nanofluidic sensor has the ability to sense picomolar concentrations of PPi anion in the surrounding environment. On the contrary, it does not respond to other phosphate anions, including monohydrogen phosphate, dihydrogen phosphate, adenosine monophosphate, adenosine diphosphate, and adenosine triphosphate. The experimental results are described theoretically by using a model based on the Poisson–Nernst–Planck equations. 相似文献
83.
Water management studies often overlook community diversity, different stakeholders’ values, and frames to claim water rights. Using a political-ecology approach, this article examines an irrigation system in Ecuador’s highlands via Fraser’s principles of justice (recognition, representation, redistribution). Large flower companies and indigenous smallholders frame their arguments differently to legitimize water allocation claims. Framing is effective when it resonates with other stakeholders’ values. Some unexpected findings are explained: most of the water is still used by large companies since communities took control; rules regarding water use differ greatly among sectors in the system; and small flower producers have been appearing recently. 相似文献
84.
Jesús Casas Julia Toja Santiago Bonachela Francisca Fuentes Irene Gallego Melchor Juan David León Patricio Peñalver Carmen Pérez Pedro Sánchez 《Water and Environment Journal》2011,25(3):308-317
A total of 16 543 artificial ponds were inventoried. Ninety‐one per cent of the ponds were classified as for farming use. Generally, the fraction of farm land converted to pond structures was close to that predicted from the average annual precipitation in the region. However, in several areas, this fraction was remarkably higher than the value predicted, probably due to excessive groundwater extraction. Overall, the naturalisation stage of ponds was poor. However, ponds sited on natural substrate basins had more structured‐marginal vegetation, compared with ponds of artificial substrate basins. Furthermore, other factors related to pond management might seriously limit their naturalisation stage. Despite the high abundance of ponds in Andalusia, our results suggest that, in order to improve the potential for biodiversity conservation in these environments, substantial structural and management changes are required. 相似文献
85.
The objective of this work was to evaluate the filter addition in centrifugal cryoconcentration. The cryoconcentration process was optimized by Response Surface Method using initial concentration (C0) and centrifugation speed (CS) (independent variables) and efficiency (η), percentage of concentrate (PC) and solute yield (Y) (dependent variables), under radial and axial freezing conditions. The optimal interactions were 5 (wt.%), 3850 rpm and axial condition, with high final solute concentration, and extraordinary separation, with 86%, 63% and 0.87 (kg/kg) for η, PC and Y, respectively. Therefore, the centrifugal filter cryoconcentration allowed the migration of solutes between the crystals, and the filter improved the separation and elution process of the concentrated solution from the ice. 相似文献
86.
R. R. Dias A. Lavoratti D. Piazza C. R. da Silva A. J. Zattera R. M. Lago P. S. de Oliveira Patricio I. M. Pereira 《应用聚合物科学杂志》2019,136(8):47094
Three different ultrahigh-molecular-weight polyethylene (UHMWPE)–clay nanocomposites (Muscovite, Cloisite 30B and amphiphilic clay/carbon nanofibers) were investigated with the nanocomposite nanomorphology studied before and after dynamic mechanical compressive tests at high strain rates. Their material structure and thermal properties were investigated using techniques such as step-scan differential scanning calorimetry, split Hopkinson pressure bar, synchrotron small angle X-ray scattering (SAXS), and dynamic mechanical analysis. Results were associated with morphological changes observed after deformation. chemical vapor deposition (CVD)-modified nanocomposite, due to the molecular bonding and the extra functional groups, is designed with crystalline structures with fewer defects and higher stability. The increase in particulate/polymer interactions observed for the CVD-modified material decreased the elongation in the quasi-static test. However, the dynamic mechanical behavior contradicted the quasi-static behavior because at very high strain rates there was not sufficient time for the interlamellar and intralamellar defect facilitated plastic flow and the material transitioned through the glassy state. The SAXS results show that deformation strongly induced changes in the UHMWPE and UHMWPE–clay nanocomposite morphology. SAXS indicates that CVD-modified samples became more compact and dense, thus corroborating the formation of additional secondary bonds between structures and/or the carbon nanofibers alignment. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47094. 相似文献
87.
The aim of this paper is to design a robust control for stabilization of a class of nonlinear perturbed system subject to matched and unmatched disturbances. Here, the concept of dynamic sliding mode control and the attractive ellipsoid method advantages are used to design a robust nonlinear control algorithm, which reduces considerably the perturbation effects. Hence, in finite time, the dynamic sliding mode control brings the system trajectory to a specific configuration. After this time, the controller reduces the perturbation effects by using the high‐gain control obtained in the attractive ellipsoid method. Thus, based on the solution of a specific matrix inequality, the feedback control of the system guarantees that the trajectory will be stabilized in the ultimate uniform bounded sense. To illustrate the theoretical results, a numerical example with a comparative study is introduced. Finally, the performance of the controller designed in this paper is tested on an electromechanical real‐time system. 相似文献
88.
The original instantaneous reactive power theory or p–q theory has been systematically used in the control of active power filters (APFs). When the APF is connected in parallel to a non-linear and unbalanced load, the p–q theory application has allowed a compensation strategy named constant power to be obtained. This means that, after the APF connection, the instantaneous power supplied by the source is constant and it has the same value as the average power consumed by the load. Nevertheless, the use of other compensation strategies is possible: unity power factor or sinusoidal and balanced supply currents, among others. This paper shows that any compensation strategy may be developed into the p–q theory frame. Besides, the paper presents a p–q theory reformulation without using mapping matrices, which makes easier the obtention of the compensation currents. Finally, an exhaustive analysis of practical cases has been carried out at simulation and experimental level through a laboratory prototype which has allowed the proposed approach to be verified. 相似文献
89.
Different series of manganese-supported catalysts containing 10 wt.% of manganese, as oxide, on TiO2 have been prepared by the sol–gel method and by the traditional method based on the impregnation of the support with the metal precursor on commercial and sol–gel supports. The samples were characterized by measuring the specific area (SBET), temperature-programmed desorption (TPD), Fourier transform infrared (FTIR) spectroscopy, temperature-programmed reduction (TPR), electrophoretic migration (IP) and X-ray diffraction (XRD). The catalytic and photocatalytic activity was measured in a batch reactor using ozone as the oxidizing agent. The catalytic behavior, expressed as constant rate, in absence of irradiation did not show significant changes for the manganese-supported catalysts. The only exception was the cogelated Mn/TiO2 catalyst, which showed higher degradation activity, the main product being benzoquinone. On the other hand, all the irradiated systems showed an increase in the phenol degradation, being CO2 and small organic acids the final product. 相似文献
90.
In the field of computer vision, the introduction of a low‐level preprocessing step to oversegment images into superpixels – relatively small regions whose boundaries agree with those of the semantic entities in the scene – has enabled advances in segmentation by reducing the number of elements to be labeled from hundreds of thousands, or millions, to a just few hundred. While some recent works in mesh processing have used an analogous oversegmentation, they were not intended to be general and have relied on graph cut techniques that do not scale to current mesh sizes. Here, we present an iterative superfacet algorithm and introduce adaptations of undersegmentation error and compactness, which are well‐motivated and principled metrics from the vision community. We demonstrate that our approach produces results comparable to those of the normalized cuts algorithm when evaluated on the Princeton Segmentation Benchmark, while requiring orders of magnitude less time and memory and easily scaling to, and enabling the processing of, much larger meshes. 相似文献