The role of ammonium citrate washing on the characteristics of mechanochemical–hydrothermal derived magnesium-containing apatites

The role of citrate washing on the physical and chemical characteristics of magnesium-substituted apatites (HAMgs) was performed. HAMgs were synthesized by a mechanochemical–hydrothermal route at room temperature in as little as 1 h, which is five times faster than our previous work. Magnesium-substituted apatites had concentrations as high as 17.6 wt% Mg with a corresponding specific surface area (SSA) of 216 m²/g. A systematic study was performed to examine the influence of increasing magnesium content on the physical and chemical characteristics of the reaction products. As the magnesium content increased from 0 to 17.6 wt%, magnesium-doped apatite crystallite size decreased from 12 to 8.8 nm. The Mg/(Mg + Ca) ratio in the product was enriched relative to that used for the reacting precursor solution. During mechanochemical–hydrothermal reaction, magnesium doped apatites co-crystallize with magnesium hydroxide. Citrate washing serves to remove the magnesium hydroxide phase. The concomitant increase in surface area results because of the removal of this phase. Possible mechanisms for magnesium hydroxide leaching are discussed to explain the measured trends.     

Comparing Five and Lower-Dimensional Grain Boundary Character and Energy Distributions in Copper: Experiment and Molecular Statics Simulation

Metallurgical and Materials Transactions A - The misorientation of 515 grain boundaries has been determined using electron backscatter diffraction data from an 18 μm thick copper foil with...     

Controllable Generation of a Submillimeter Single Bubble in Molten Metal Using a Low-Pressure Macrosized Cavity

Metallurgical and Materials Transactions B - We develop a method for generation of a single gas bubble in a pool of molten metal. The method can be useful for applications and research studies...     

冰硬度试验台设计与试验

极地冰层硬度特性对铠装电缆电动机械取心钻具反扭装置设计和使用具有重要意义。针对冰层特殊的物理性质,结合材料硬度测试原理,设计了一套可在模拟极地冰层低温条件下测量冰硬度特性的硬度试验台。该试验台由低温冷柜、硬度测试台和数据采集及控制系统3部分组成,其中,数据采集及控制系统隔离在常温环境中,降低了元器件对环境温度的要求。利用该试验台对硬度压头压入冰层的压力和深度进行数据检测,换算得到相应的硬度值。对设计的试验台进行初步实验表明,该试验台工作状态良好,数据准确,可满足对低温材料硬度特性的检测。     

The hot rectus abdominis muscle sign

We report a 2.5-year-old child who presented with an acute abdomen caused by the perforation of a sewing pin through her appendix that had started to penetrate the wall of the bladder.     

Filter‐ versus wrapper‐based feature selection for credit scoring

We address the problem of credit scoring as a classification and feature subset selection problem. Based on the current framework of sophisticated feature selection methods, we identify features that contain the most relevant information to distinguish good loan payers from bad loan payers. The feature selection methods are validated on several real‐world datasets with different types of classifiers. We show the advantages following from using the subspace approach to classification. We discuss many practical issues related to the applicability of feature selection methods. We show and discuss some difficulties that used to be insufficiently emphasized in standard feature selection literature. © 2005 Wiley Periodicals, Inc. Int J Int Syst 20: 985–999, 2005.     

Reactive phenylbenzimidazole UV absorbers and their application to cellulose textiles

New types of reactive UV absorbers for applications to cellulose textiles have been prepared. These substances are condensation products of sulfobenzimidazolaniline, cyanuric chloride, and aminophenyl‐(2‐sulfethoxy)‐sulfone. They were applied to bleached, unbleached, as well as dyed cellulose textiles with the aim to increase the protection effect of these textiles against UV radiation. All the tested textiles showed a marked increase in the UV protection factor (UPF). The effects of the UV absorbers tested neither interfere with the function of fluorescent brighteners (FBs) nor affect the hue of the used dyestuffs. They exhibit synergistic effect in the protection effectiveness against UV radiation: the UV absorbers used together with dyestuffs and FBs have a higher UPF factor than is the sum of UPF contributions of the individual components. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

The wave scattering on the step of the circular oversized waveguide filled in with insulator

The method of calculation of the circular oversized waveguide filled in with insulator using the method of plane cross-section (PCS) is developed. The wave scattering on the output insulator window for powerful occilator is investigated.     

Brillouin scattering from epoxy resins and gels

Summary The isothermal curing process of the system diglycidyl ether of Bisphenol A/poly (oxypropylene) diamine (Jeffamine D-400) without and in the presence of solvent (Diglyme) was investigated by Brillouin spectroscopy for the stoichiometric amounts of epoxide and amine groups. The spectroscopic data have been explained in terms of the relaxing viscosity model in the former case and by the scattering of phonons by stationary heterogeneities in the latter one. It is suggested that these heterogeneities may be small air bubles released during curing and frozen in due to the high viscosity at and above the gel point.