The aim of this article is the study of the potential relationships between PAHs contamination, physicochemical parameters, and microbial activity in industrial soils. The research was based on two series of measurements. The first was conducted in June 2013 and the second in November 2013. Samples used in study were collected from the area of fuel handling and a loading station, located in the Silesia region of Poland. All collected samples were characterized by the following analytical procedures: PAHs content analysis, the basic physical and chemical parameters determinations (pH, CEC, humic acids content, TC, TN, TP) and microbial activity analysis. The obtained results were also subjected to statistical analysis, based on the Pearson's correlation coefficient calculations.
Results collected during described above procedure show that: the PAHs content was highly positively correlated with C and N contents (p < 0.001) and moderately correlated with humic acids and P contents (p < 0.01). This phenomenon confirms the thesis that the increase of soil organic matter content promotes accumulation of hydrophobic organic compounds such as PAHs. Microbiological analysis shows that bacteria from the mesophilic group are most resistant to PAHs contamination. This information indicates that the organisms belonging to this group should be considered as potentially useful in the soil bioremediation processes. 相似文献
A series of Schiff bases with hydroxyl anchoring group/s in various positions were synthesised. Their visible light absorption and electrochemical and physicochemical adsorption properties were investigated. Results show that the studied compounds have adequate highest‐occupied‐molecular‐orbital and lowest‐unoccupied‐molecular‐orbital levels that match with the conduction band of titanium dioxide and the redox potential of the electrolyte. Adsorption of azomethine compounds with hydroxyl group/s on titanium dioxide was studied. Experimental data show that the introduction of two β‐hydroxyethyl groups can greatly enhance the adsorption efficiency of the studied Schiff base on titanium dioxide. Sorption kinetics was measured for di‐(β‐hydroxyethyl)aminobenzyliden‐2‐aminobenzothiazol. Results show rapid initial sorption (<30 min), followed by a slower rate of increasing uptake between 0.5 and 6 h. Kinetic data were modelled using pseudo‐first‐order, pseudo‐second‐order, and intraparticle diffusion kinetics equations. These results indicate that the pseudo‐second‐order equation and intraparticle diffusion model can better describe the adsorption kinetics of di‐(β‐hydroxyethyl)aminobenzyliden‐2‐aminobenzothiazol onto titanium dioxide. 相似文献
The adsorption of non‐ionic polysaccharide guar gum (GG) in the presence of surfactants (anionic SDS, non‐ionic TX‐100, cationic CTAB and their equimolar mixtures) from their NaCl solutions onto an alumina surface (Al2O3) was studied spectrophotometrically. This study is important in light of the many disagreements concerning the structure and behaviour of mixtures containing polymers and surfactants at the surface of an adsorbent. The presence of surfactant caused an increase in the GG adsorption in all studied systems as a consequence of the formation of complexes. Among the single surfactants the highest increase in the GG adsorption was observed in the presence of CTAB. However, the usage of mixtures of the surfactants caused a much more effective increase in the GG adsorption on the alumina surface because of the synergistic effect of the surfactants. In order to get some information on the structure of the electrical double layer (edl), the surface charge density of alumina was determined and zeta potential measurements were conducted. The obtained data showed that the adsorption of GG or GG/surfactant complexes on the metal oxide surface strongly influences a diffused part of the edl, whereas a compact part of the edl is not affected. The colloidal stability of the alumina suspensions was measured in the presence and absence of GG and surfactants. It was found that GG and the mixtures of GG and surfactants can improve the stability of the suspensions. 相似文献
In the present study calcium hydroxyapatites enriched at 0.08 wt% in Mn2+ ions (Mn–HA) and their unsubstituted forms (HA) were synthesized using the same standard wet chemical route. Mn‐HA and HA were both calcined at 800°C to give Mn‐HAc and HAc, respectively or sintered at 1250°C, to give Mn‐HAs and HAs, respectively. The influence of the heat treatment on physicochemical properties of Mn‐HA was investigated using powder X‐ray diffraction (PXRD), scanning, and transmission electron microscopy (SEM and TEM), and solid‐state nuclear magnetic resonance (ssNMR). Mn‐HAc and Mn‐HAs were compared to each other and to HAc and HAs, respectively. Assignment of the proton ssNMR peaks from high‐temperature‐treated apatites has been revised. It was found that Mn–HAc and HAc were nanocrystalline, while Mn‐HAs and HAs comprised micrometer sized, partially fused particles (SEM and TEM). PXRD and ssNMR demonstrated that the incorporation of Mn2+ into the crystal lattice of hydroxyapatite significantly facilitates its dehydroxylation and decomposition to oxyhydroxyapatite during calcination at 800°C, and induces its transformation to tetracalcium phosphate (TTCP) and alpha‐tricalcium phosphate (α‐TCP) at 1250°C. Contamination by CaO has also been detected. The 1H→31P NMR cross‐polarization experiments have indicated that the Mn2+ ions preferentially occupied the Ca(I) position in the crystallographic unit cell of Mn‐HAc. In Mn‐HAs, the Mn2+ ions were evenly distributed between the Ca(I) and Ca(II) positions. 相似文献
Streptomyces hygroscopicus is a natural producer of geldanamycin. Mutasynthetic supplementation of an AHBA‐blocked mutant with all possible monofluoro 3‐aminobenzoic acids provided new fluorogeldanamycins. These showed strong antiproliferative activity and inhibitory effects on human heat shock protein Hsp90. Binding to Hsp90 in the low nanomolar range was determined from molecular modelling, AFM analysis and by calorimetric studies. 相似文献
The aim of the present study was to compare different rape varieties. For this purpose oil from six different varieties of rapeseeds was cold pressed under laboratory conditions. In the obtained rapeseed oils the fatty acids composition and minor components, characteristic values (acid value; AV and TOTOX), oxidative stability (DSC test), and volatiles were determined and a sensory evaluation was carried out. The highest oxidative stability was found for oil from sample 5 (IP = 158 min), which also has the lowest amount of C18:3 (7.8%), chlorophylls (0.083 mg/kg), and metals (Cu2+ 0.02 mg/kg and Fe2+ 0.08 mg/kg). This oil has also the lowest AV (0.17 mg KOH/g), which may be related to the lowest moisture content of the seeds prior to extraction. It was characterized by the highest rapeseed flavor intensity. The lowest induction period was observed for samples 3 and 6 (100 min). Although sample 3 had the same low level of metals as sample 5 and the highest concentration of tocopherols (635 mg/kg), PUFA (33.9%), and AV (1.37 mg KOH/g) it also had the lowest intensity of rapeseed flavor among the analyzed oils. Sample 6, despite its low percentage of PUFA (24.7%), conjugated diens and triens, and the lowest content of total volatiles (0.4Vs), had the highest concentration of metals (Cu2+ 0.04 mg/kg and Fe2+ 0.34 mg/kg). 相似文献