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排序方式: 共有10000条查询结果,搜索用时 31 毫秒
991.
F Javier Álvarez‐Hornos Carmen Gabaldón Vicente Martínez‐Soria Paula Marzal Josep‐Manuel Penya‐roja 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(5):643-653
BACKGROUND: Two peat biofilters were used for the removal of toluene from air for one year. One biofilter was fed with pure toluene and the other received 1:1 (by weight) ethyl acetate:toluene mixture. RESULTS: The biofilters were operated under continuous loading: the toluene inlet load (IL) at which 80% removal occurred was 116 g m?3 h?1 at 57 s gas residence time. Maximum elimination capacity of 360 g m?3 h?1 was obtained at an IL of 745 g m?3 h?1. The elimination of toluene was inhibited by the presence of ethyl acetate. Intermittent loading, with pollutants supplied for 16 h/day, 5 days/week, did not significantly affect the removal efficiency (RE). Biomass was fully activated in 2 h after night closures, but 6 h were required to recover RE after weekend closures. Live cell density remained relatively constant over the operational period, while the dead cell fraction increased. Finally, a 15 day starvation period was applied and operation then re‐started. Performance was restored with similar re‐acclimatization period to that after weekend closures, and a reduction in dead cell fraction was observed. CONCLUSION: This study demonstrates the capacity of the system to handle intermittent loading conditions that are common in industrial practices, including long‐term starvation. Copyright © 2008 Society of Chemical Industry 相似文献
992.
疏水缔合型聚丙烯酰胺的合成与性能评价 总被引:1,自引:0,他引:1
为了提高高相对分子质量的聚丙烯酰胺的抗温抗盐性能,利用自制的两亲表面活性单体与丙烯酰胺共聚合成了疏水缔合型聚丙烯酰胺并进行室内评价。结果表明,在高温、高盐、高钙条件下,合成的疏水缔合型聚丙烯酰胺具有良好的增粘性和较强的热稳定性;克服了疏水缔合型聚合物在盐水中溶解性差的问题,可用各种矿化度的盐水和油田产出污水配制;具有良好的无机盐增粘性能和抗温性能。 相似文献
993.
Material removal and surface damage of Ti3SiC2 ceramic during electrical discharge machining (EDM) were investigated. Melting and decomposition were found to be the main material removal mechanisms during the machining process. Material removal rate was enhanced acceleratively with increasing discharge current, ie, working voltage, ui, but increased deceleratively with pulse duration, te. Microcracks in the surface and loose grains in the subsurface resulted from thermal shock were confirmed, and the surface damage in Ti3SiC2 ceramic led to a degradation of both strength and reliability. 相似文献
994.
Edna R Meza‐Escalante Anne‐Claire Texier Flor Cuervo‐López Jorge Gómez Francisco J Cervantes 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(3):372-377
BACKGROUND: Many industrial discharges, such as those generated from petrochemical refineries, contain large amounts of sulfurous, nitrogenous and organic contaminants. Denitrification has emerged as a suitable technology for the simultaneous removal of these pollutants in a single reactor unit; however, more evidence is demanded to clarify the limitations of denitrification on the simultaneous removal of sulfide and phenolic contaminants and to optimize the biological process. The aim of this study was to evaluate the capacity of a denitrifying sludge to simultaneously convert sulfide and p‐cresol via denitrification. RESULTS: Sulfide was the preferred electron donor over p‐cresol, imposing a 5 h lag phase (required for complete sulfide removal) on organotrophic denitrification. Addition of sulfide (20 mg S2? L?1) to p‐cresol‐amended denitrifying cultures also decreased the reduction rate of nitrate and nitrite, as well as the production rate of nitrogen gas. Nitrite reduction rate was the most affected step by sulfide, decreasing from 35 to 21 mg N (g VSS d)?1. A synergistic inhibitory effect of nitrate and sulfide was also observed on nitrite reduction. Despite the effects of sulfide on the respiratory rates monitored, complete removal of nitrate, sulfide and p‐cresol could be achieved after 48 h of incubation. CONCLUSION: Our results suggest that simultaneous removal of sulfide and p‐cresol could be achieved in denitrifying reactors, but a large hydraulic residence time may be required to sustain an efficient process due to inhibitory effects of sulfide. Copyright © 2008 Society of Chemical Industry 相似文献
995.
Xinsheng Zhu Hansong Xu Jianmei Lu Juying Wang Shunhua Zhou 《Journal of Polymer Research》2008,15(4):295-300
Poly(ethylene terephthalate) (PET) is of excellent mechanical properties and melt processability and is widely used as raw
material for textile fibers. However, the flame retardant properties of PET were rather poor, and both reactive and additive
phosphorus- and halogen-containing compounds have been employed to enhance the reaction-to-fire properties while the meltdripping
behaviour during burning hasn’t been handled properly with the flame retardants. In this work, fluoropolymer was blended with
both pure PET (pPET) and reactive phosphorus-containing flame retarded copolyester (fPET), and the flame retardance and char
formation and mechanical properties of the resulted pPET and fPET blends were investigated. The tensile strengths of modified
pPET samples were worsen whereas those of modified fPET samples were improved at low concentrations. The initial thermal degradation
in nitrogen was accelerated remarkably for the two polyesters with fluoropolymer. The oxygen indices of the all modified samples
were reduced while char formation and meltdripping suppression were encouraged. The apparent melt viscosity and elasticity
for the two polyesters were gained much with antidripping agent. Therefore, fluoropolymer improved char formation of the two
polyesters based on the gaseous phase mechanism while the partial suppression of meltdripping behavior and the decrease of
mechanical properties mainly originated from the increase of melt viscosity via fibrillation for pPET. 相似文献
996.
997.
Ying‐Hung So 《Polymer International》2006,55(2):127-138
Poly(2,4‐dimethyl‐1,4‐phenylene oxide) (PPO), poly(benzo[1,2‐d:5,4‐d′]bisoxazole‐2,6‐diyl‐1,4‐phenylene) (PBO) and poly(benzo[1,2‐d:4,5‐d′]bisthiazole‐2,6‐diyl‐1,4‐phenylene) (PBZT), which are polymers with extended conjugated structures, undergo a self‐sensitized photo‐induced electron‐transfer reaction. A second component is not required. This article presents many similar observations on these polymers when they are exposed to light and evidence to support the proposed photo‐induced electron‐transfer mechanism. Methods to stabilize these polymers against photo‐oxidation are also described. Workers investigating other conjugated polymeric systems may find the experimental methods, observations and polymer stabilization approaches discussed in this review useful. Copyright © 2005 Society of Chemical Industry 相似文献
998.
999.
应用于油气藏流体近临界区状态方程的发展及改进现状 总被引:1,自引:0,他引:1
对近临界流体的特殊性质进行了描述,并对近年来经典和非经典状态方程在近临界流体PVT相态特征模拟计算方面的发展及应用现状进行了总结,指出要找到适用于近临界流体的状态方程还有很多工作要做,需要大量的实验数据支持以及理论上的突破。同时它的发展在近临界油、气藏开发工程、注气驱油藏开发工程中具有广泛的应用前景。 相似文献
1000.