扎赉诺尔褐煤制取高炉喷吹料和中热值煤气研究 (Ⅰ)煤气、焦油产率及性质

本文是在10kg／h固体热载体干馏实验装置上用扎赉诺尔褐煤制取高炉喷吹料和中热值煤气的研究结果。在干馏温度450℃～650℃范围制得煤气110Nm3/t～400Nm3/t，煤气热值为14．7MJ／Nm3～17．5MJ／Nm3，属中热值煤气。可供民用，也可用于补充钢铁企业燃气不足，平衡能源。得低温焦油2％～9％，可加工成化工产品和燃料油。半焦可用于高炉喷吹。     

Nanocrystalline CeO2 in SBA-15: Performance of Pt/CeO2/SBA-15 Catalyst for Water-gas-shift Reaction

CeO₂ particles confined within the pores of an SBA-15 mesoporous silica host were prepared by incipient wetness impregnation (IMP) and deposition precipitation (DP) methods. The materials were characterized by XRD, N₂-adsorption and temperature programmed reduction (TPR) to evaluate the structure, texture, and redox properties. The preparation procedure had significant impact on the assembling mode of CeO₂ inside the SBA-15 mesopores. A high dispersion of CeO₂ particles was achieved via DP, whereas the dispersion of CeO₂ prepared by IMP was found to be inhomogeneous and CeO₂ partially blocked the pores. The CO conversion in the water-gas-shift reaction was enhanced over 1 wt% Pt supported on CeO₂-modified SBA-15 obtained by DP.     

PVC╱NBR╱BR三元共混弹性体的制备

采用结合丙烯腈含量为26％的NBR、分子量适中的悬浮法Ⅲ型PVC和BR共混,制得了综合性能较PVC/NBR并用胶优异的弹性体。优选的工艺条件为:PVC/NBR/BR=30/60/10(质量比);补强剂选用炭黑40份,超细碳酸钙50份,轻质碳酸钙20份;硫化体系选用过氧化物加少量硫磺;混炼温度为140—170℃,混炼时间为10—15min。通过电子显微镜和动态力学分析,弹性体存在两个T,PVC为分散相,橡胶为连续相。     

浅谈俄罗斯银行信息安全体系的建立

本文主要从俄罗斯银行信息安全管理体系（ISMS）建立准则,ISMS成熟度等级,与信息安全体系相关的法律法规三个方面来介绍俄罗斯银行信息安全体系的建立。     

水基Fe3O4磁流体的制备工艺研究

用共沉淀法制备Fe3O4磁流体,总结出用十二烷基磺酸钠与聚乙二醇作为表面活性剂制备水基磁流体的合适条件:(1)反应温度为室温或不高于35℃;(2)表面活性剂十二烷基磺酸钠的最佳用量为0.0030～0.0040 g/80 mL;(3)第一次包裹的最佳pH为9～10;(4)聚乙二醇作为第二次包裹的表面活剂时,体系最佳温度为40℃左右;(5)表面活性剂聚乙二醇的最佳用量为0.0050～0.0060 g/80 mL。通过实验制得了能稳定存在180 d的水基磁流体。并用透射电镜、红外光谱、分光光度计、古埃磁天平等进行了初步表征。     

Polypropylene photostabilization by hindered amines in the presence of acidic species

Some volatile acids were found to dramatically reduce the effectiveness of additives based on 2,2,6,6-tetramethylpiperidine as photostabilizers for polypropylene films. Strong acids such as HCl, HBr, and HNO₃ had the largest effect with sulfurous acid somewhat less detrimental. Weak organic acids did not impair the effectiveness of the hindered amine light stabilizers. The role of acid concentration and contact time were explored for the HCl–piperidyl additive system. Secondary and tertiary amines were included in the study as well as oligomeric additives and an N-oxyl derivative. The latter is less basic than the free amines, and it was correspondingly less effected by acid exposures. The possibilities for acid exposure during the compounding, fabrication, and use of stabilized polyolefin articles is discussed as well as the effects of acids in terms of proposed stabilization mechanisms for the hindered amines.     

Important issues in a molecular dynamics simulation for characterising the mechanical properties of carbon nanotubes

This paper discusses several important issues in a molecular dynamics simulation for analysing carbon nanotubes and their mechanical properties. In particular, the paper addresses the problems in selecting appropriate inter-atomic potentials, number of thermostat atoms, thermostat techniques, time and displacement steps and number of relaxation steps to reach the dynamic equilibrium. Based on these, the structural changes of armchair and zigzag nanotubes and their mechanical properties are investigated. The Young's modulus and Poisson's ratio of the armchair tube are 3.96 and 0.15 TPa, respectively, and those of the zigzag tube are 4.88 and 0.19 TPa, respectively. The best simulation technique identified in this study predicts that the ultimate tensile strain of a carbon nanotube is around 40% before atomic bond breakage.     

Synthesis, isolation, spectroscopic and electrochemical characterization of some calcium-containing metallofullerenes

A few Ca-containing mono-metallofullerenes, i.e. Ca@C₇₆, Ca@C₈₈, Ca@C₉₀ (I, II), were synthesized by an improved DC arc discharge method and isolated by a multi-stage HPLC method for the first time. These isomer-separated metallofullerenes were characterized by LD-TOF MS and UV-vis-NIR spectrometry. Their HOMO-LUMO band gaps and possible molecular geometries are discussed according to the absorption spectra in this report. In addition, the cyclic and differential pulse voltammetry of Ca@C₇₆ was conducted in MeCN/C₆H₅CH₃ (1:4 v/v). The voltammograms of Ca@C₈₂ (II, III) and Ca@C₈₄ (II) were also recorded. Their electrochemical behaviors are discussed compared with those of corresponding ytterbium metallofullerenes. The features of the Ca metallofullerenes’ electronic structures are also discussed.     

Studies of structure and cycleability of LiMn2O4 and LiNd0.01Mn1.99O4 as cathode for Li-ion batteries

Lithium manganese oxides LiMn₂O₄ and rare earth elements doped LiNd_0.01Mn_1.99O₄ were synthesized by microwave method. The structure and the electrochemical performances of the samples were characterized. XRD data shows both samples exhibit the same pure spinel phase. But due to the introduction of Nd³⁺ ion into the unit cell, the lattice parameter of the Nd-doped spinel was larger than that of the undoped one. The two samples had a similar morphology including small particle size and homogeneous particle distribution as tested by SEM. The cyclic voltammmetry and constant-current charge-discharge tested that Nd-doped spinel displayed a better reversibility and cycleability.     

浅谈构建安全的长江海事电子政务网络体系

电子政务已成为长江海事局工作信息化的重点工程。对长江海事电子政务网络建设的基础安全服务设施、安全管理保障体系、安全技术支撑平台和响应与恢复机制等问题进行了分析,并结合实践经验,提出了建立安全可靠的长江海事电子政务网络体系的对策。