Effect of nano‐silica filler on the rheological and morphological properties of polypropylene/liquid‐crystalline polymer blends

A fumed hydrophilic nano‐silica‐filled polypropylene (PP) composite was blended with a liquid‐crystalline polymer (LCP; Rodrun LC5000). The preblended polymer blend was extruded through a capillary die; this was followed by a series of rheological and morphological characterizations. The viscosity of the PP matrix increased with the addition of the hydrophilic nano‐silica. At shear rates between 50 and 200 s^?1, the composite displays marked shear‐thinning characteristics. However, the incorporation of LC5000 in the PP composite eliminated the shear‐thinning characteristic, which suggests that LC5000 destroyed the agglomerated nano‐silica network in the PP matrix. Although the viscosity ratio of LCP/PP was reduced after the addition of nano‐silica fillers, the LCP phases existed as droplets and ellipsoids. The nano‐silicas were concentrated in the LC5000 phase, which hindered the formation of LCP fibers when processed at high shear deformation. We carried out surface modification of the hydrophilic nano‐silica to investigate the effect of modified nano‐silica (M‐silica) on the morphology of the PP/LC5000 blend system. Ethanol was successfully grafted onto the nano‐silica surface with a controlled grafting ratio. The viscosity was reduced for PP filled with ethanol‐M‐silica when compared to the system filled with untreated hydrophilic nano‐silica. The LC5000 in the (PP/M‐silica)/LC5000 blend existed mainly in the form of fibrils. At high shear rates (e.g., 3000 s^?1), the LC5000 fibril network was formed at the skin region of the extrudates. The exclusion of nano‐silica in the LC5000 phase and the increased viscosity of the matrix were responsible for the morphological changes of the LCP phase. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 1484–1492, 2003     

Self-assembly of C60 containing poly(methyl methacrylate) in ethyl acetate/decalin mixtures solvent

[60]Fullerene (C₆₀) was mono-substituted with well-defined poly(methyl methacrylate) (PMMA-b-C₆₀) using the atom transfer radical polymerization (ATRP) technique. The self-assembly behaviors of PMMA-b-C₆₀ in ethyl acetate (EA) and decalin mixtures were studied using laser light scattering (LLS) and transmission electron microscopy (TEM). Homogeneous solutions of PMMA-b-C₆₀ can be obtained in the solvent mixtures containing more than 40 wt% EA, where the molar ratio of decalin to EA is close to 1. For each solvent mixture, unimers coexist with micelles and large aggregates. The sizes of PMMA-b-C₆₀ micelles and aggregates are independent of polymer concentration, confirming that they are produced via the closed association mechanism. For the various solvent mixtures, the weight-averaged molecular weights, M_w of the PMMA-b-C₆₀ aggregates range from 4.1×10⁷ to 12.5×10⁷ g/mol. The hydrodynamic radii of the large aggregate, R_h, vary from 90 to 136 nm, while the z-averaged radii of gyration, R_g, range from 210 to 311 nm. The R_g/R_h value for each solvent mixture is ∼2.3, which is independent of decalin contents in the mixed solvents. The morphological study using the transmission electron microscope suggests that the large aggregates are composed of porous large compound micelles (LCM) in solution.     

蜂窝式构件长细比的计算方法

为了进一步研究蜂窝构件稳定承载性能,以现有长细比计算理论为基础,结合蜂窝构件的受力机理和界面特性,提出了蜂窝构件长细比计算中相关参数的计算方法．同时,结合理论推导和数值分析结果,提出了蜂窝构件换算长细比建议计算公式．     

基于HSV空间的彩色图像直方图检索技术

传统彩色图像的直方图检索技术基于RGB空间,但研究发现,RGB空间不符合人眼的视觉感应。因此本文提出的算法是在HSV空间上计算彩色图像的三维直方图,通过非均匀的划分三个分量色相H（Hue）、饱和度S（Saturation）和亮度V（Value）的采样区间,得到不同的检索结果。实验结果分析表明,在HSV空间,不同的分量在不同类型的图像中的作用是不一致的。     

基于广东区域性高职院校创业教育的思考——记广州城建职业学院学生创业教育的探索

职业素质是劳动者对社会职业了解与适应能力的一种综合体现,主要包括职业修养和职业技能。在高职院校中开展创业教育是我国经济形势发展的需要,对于培养学生的实践能力、创新精神和解决学生的就业压力有着十分重要的意义。广州城建职业学院的创业教育可以从以下三方面着手：一是转变观念,营造氛围;二是传授本领,打好基础;三是开展活动,提高能力,逐步探索出一条适合广州城建职业学院特色高职学生创业教育的新路子。     

快速路网单点入口匝道动态控制策略仿真评价研究

有别于以往工作,运用宏观交通网络动态建模理论与计算机仿真技术,以快速路网为考察对象,提出单点入口匝道动态控制策略的宏观交通仿真评价方法,设计了一种基于ALINEA原理的单点入口匝道动态控制算法,针对一多起点-多终点拥挤路网,开发仿真系统,给出控制前后路段交通状态时变图、全局路网交通状态图等可视化仿真结果,描述路网交通流演化,定量评价匝道控制效果。算例表明,控制后路网拥堵显著缓解,网络总耗时减少约5%。研究显示了单点匝道控制策略宏观交通仿真评价方法有助于深刻、全面、直观地理解路网交通流演化,剖析拥堵成因,设计符合全局、系统眼光的高效控制策略,给出定量评价,具有有效性与优越性。     

The crack of harden cement paste observed with multi-technique

The shrinkage of the cement paste with low water-cement ratio at different relative humidity was observed and analyzed with ESEM and deformation map technique. The crack morphology was observed with different magnification with SEM and FESEM, and the formation of the crack was observed with AFM between two C-S-H nano particles. The observation by multi technique at multi scale indicated that the shrinkage was increase with the decrease of the humidity due to the increase of the pressure of the capillary pressure, the morphology of the crack in smaller scale was similar to that in the bigger scale, the smaller crack distributed in the latticework of the bigger ones, and the crack propagated along the gap between two nano particles of C-S-H with weaker bonding.     

Oily wastewater treatment by porous ceramics mediums with surface lipophilic modification

Aiming at the treatment of difficult-to-handle oily wastewater, the ceramics filter mediums made from the iron and steel plant sludge were adopted to surface lipophilic modification so as to remove oil efficiently. The hydrolysis technique by FTIR and conductivity test indicated that under acid conditions hydrogen silicon oil did not hydrolyze but release hydrogen by chemical reaction under alkaline conditions. The results of the experiments including contact angle measurement, FTIR analysis, and SEM analysis illustrate that a layer of lipophile coating indeed exists evenly on the surface of filter mediums after modification. Furthermore, the hydrogen-containing silicone oil was combined through dehydration of Si-H bond with the -OH on the surface of ceramic filter medium.     

Equilibrium equations for nonlinear buckling analysis of drill-strings in 3D curved well-bores

With the development of drilling technology, the oil/gas well has evolved from its early vertical straight form to the inclined, horizontal, plane curved, or even 3D curved well-bore. Understanding of the buck-ling behavior of a drill-string in a well-bore is crucial for the success of a drilling operation. Therefore, equilibrium equations for analyzing the buckling behavior of a drill-string in a 3D curved well-bore are required. Based on Love’s equilibrium equations for a curved and twisted rod in space, ...     

P_2O_5和V_2O_5对CaO－Al_2O_3－SiO_2系统玻璃分相与析

Ｐ＿２Ｏ＿５和Ｖ＿２Ｏ＿５对ＣａＯ－Ａｌ＿２Ｏ＿３－ＳｉＯ＿２系统玻璃分相与析晶行为的影响膝立东，陆德明，甘朝亢（山东轻工业学院２５０１００）ＴｈｅＥｆｆｅｃｔｓｏｆＰ＿２Ｏ＿５ａｎｄＶ＿２Ｏ＿５ｏｎｔｈｅＰｈａｓｅｓｅｐａｒａｔｉｏｎａｎｄＣｒｙｓ...