Encapsulation of urease in double‐layered hydrogels of macroporous poly(2‐hydroxyethyl methacrylate) core and poly(ethylene oxide) outer layer: fabrication and biosensing properties

Double‐layered hydrogels of super‐macroporous poly(2‐hydroxyethyl methacrylate) (PHEMA) cryogel core and poly(ethylene oxide) (PEO) hydrogel outer layer for encapsulation of the enzyme urease were constructed. The enzyme was entrapped into the pores of PHEMA cryogel by soaking and then the core was covered with a PEO layer. The leaking of urease from the core was prevented when the density of the PEO network was increased by incorporation of the crosslinking agent, poly(ethylene glycol) diacrylate. The hybrid system exhibited a nearly constant enzyme activity with time and maintained its structural integrity after several reactions of hydrolysis of urea. The potential of double‐layered hydrogels containing urease for establishment of water pollution with copper was investigated as well. Copyright © 2011 Society of Chemical Industry     

Water leakage problems at the Tangab Dam Reservoir (SW Iran), case study of the complexities of dams on karst

Bulletin of Engineering Geology and the Environment - The Tangab Dam was constructed at a unique geological structure, within a karst valley at the deepest point of a saddle-shaped feature which...     

Study of Silicon Cantilevers by the Photoacoustic Elastic Bending Method

Rectangular silicon cantilevers are studied by the photoacoustic (PA) elastic bending method. Experimental signals versus modulation frequency of the excitation optical beam are measured and analyzed in a frequency range from 20 Hz to 50 000 Hz. The procedure for experimental signal correction to eliminate the frequency characteristics of the measuring system is given. The corrected experimental signal shows a good correlation with theoretically calculated PA signal at frequencies below 32 000 Hz. The corrected experimental PA elastic bending signals for cantilevers with different thicknesses are analyzed. The experimental results allow identifying the resonant frequency (the first resonant mode) of the cantilever vibrations. These values are in good agreement with the theoretically computed values. A theoretical model of the optically excited Si cantilever is derived, taking into account plasmaelastic, thermoelastic, and thermodiffusion mechanisms. Dynamic relations for the amplitude and phase of electronic and thermal elastic vibrations in optically excited cantilevers are derived. The theoretical model is compared to the experimental results.     

Electrospun Poly(styrene) Fibers as a Protection for the First- and the Second-Generation Grubbs’ Catalyst

The study presents a novel method for protection of the first- and the second-generation Grubbs’ catalyst, by incorporation in poly(styrene) fibers through electrospinning technique. Both catalysts are sensitive to the presence of the amine hardeners in the epoxy-based self-healing composites and require protection from deactivation to retain their ability to promote polymerization reaction of the healing agent. Comparison of healing efficiencies of both catalysts suggested that poly(styrene) fibers offer better protection and dispersion for the first-generation Grubbs’ catalyst, although all the samples exhibited high-healing efficiency. Difference in stereoselectivity between two catalysts was also indicated.     

The kinetic and thermodynamic analysis of ultrasound-extraction of minerals from aerial parts of white lady's bedstraw (Galium mollugo L.)

The present paper deals with the extraction of some minerals (potassium, calcium and magnesium) from ground, dried aerial parts of white lady's bedstraw (Galium mollugo L.) using an aqueous ethanol solution (50% by volume) at different temperatures (from 23 to 40 °C) in the presence and absence of ultrasound. The main goal was to establish the kinetics and the thermodynamics of the two extraction processes. A phenomenological model involving simultaneous washing and diffusion was proved for both ultrasound-assisted and silent extraction of the minerals. The minerals extraction both in the presence and the absence of ultrasound is endothermic and irreversible since the enthalpy change and the entropy change are positive in the ranges of extraction temperature applied. The Gibbs free energy change for the extraction of minerals is negative, indicating that the process is feasible and spontaneous. The minerals yield increased by a factor of 1.02–1.06 and 1.14–1.27 in the absence and the presence of ultrasound, respectively for every 10 °C rise in temperature.     

The dependence of the photocatalytic activity of TiO2/carbon nanotubes nanocomposites on the modification of the carbon nanotubes

Nanostructural TiO₂/modified multi-wall carbon nanotubes photocatalysts were prepared by hydrolysis of Ti(iso-OC₃H₇)₄ providing chemical bonding of anatase TiO₂ nanoparticles onto oxidized- or amino-functionalized multi-wall carbon nanotubes (MWCNT). The processes of functionalization of the MWCNT and the deposition of TiO₂ influence the photocatalytic activity of the synthesized nanocomposites. The phase composition, crystallite size, and the structural and surface properties of the obtained TiO₂/modified-MWCNT nanocomposite were analyzed from XRD, FEG-SEM, TEM/HRTEM and FTIR data, as well low temperature N₂ adsorption. In the photocatalytic study, the TiO₂/oxidized-MWCNT catalyst showed the highest and the TiO₂/amino functionalized-MWCNT catalysts somewhat lower degradation rates, indicating that the enhancement of photocatalysis was supported by the more effective electron transfer properties of the oxygen- than amino-containing functional groups, which support the efficient charge transportation and separation of the photogenerated electron-hole pairs.     

Criteria for use of groundwater as renewable energy source in geothermal heat pump systems for building heating/cooling purposes

Environmental protection measures are conducted directly by the use of renewable energy sources. The energy development of cities in Europe is aimed at the sustainable use of renewable energy sources in order to achieve the substitution of fossil fuels and the reduction of the hazardous gas emission into the atmosphere. Geothermal resources of medium and low enthalpy in Europe being used for obtaining heat energy are providing about 6600 MW_t, currently having the growth trend of 50 MW_t annually. The use of geothermal low enthalpy, namely of subgeothermal groundwater resources, has even higher annual growth rate, and if such a trend is kept till the year 2010, the produced energy will amount about 8000 MW_t. Criteria of the groundwater use as a hydrogeothermal energy resource in heat pumps are complex, and they deal with aspects of incoming temperatures and groundwater quantities. The precise limit temperature of groundwater that would separate the direct use of geothermal energy (only by the use of heat exchangers), and indirectly by the use of a heat pump has not been determined in the professional and scientific practice of Serbia so far. Taking into account that relatively small number of new flat is being built in Serbia nowadays, if we want to save energy it is necessary to carry out the energy reconstruction of the existing flats whose number is estimated to be more than 2.8 million. By the application of subgeothermal energy and the use of heat pumps, energy consumption would be significantly reduced.