Plasmon-induced trap filling at grain boundaries in perovskite solar cells

The deep-level traps induced by charged defects at the grain boundaries (GBs) of polycrystalline organic–inorganic halide perovskite (OIHP) films serve as major...     

Analysis of time-domain and spectral-domain two-beam interference including the effect of a variable spectral bandpass of a detecting system

Abstract

The effect of a variable Gaussian response function of a monochromator in a detecting system with a broadband detector is included in the theoretical and experimental analysis of time-domain and spectral-domain interference of two light beams from a source of a multimode Gaussian spectrum. The time-domain theoretical analysis gives the analytic expressions for the measured complex degree of temporal coherence of the light with and without the effect of variable spectral bandpass of the detecting system. The spectral-domain theoretical analysis of the two-beam interference gives the spectral interference law from which the visibility of the spectral interference fringes resolved for a given delay in the interferometer by a spectrometer is expressed as a function of the bandpass of the spectrometer. The theoretical conclusions are confirmed experimentally in the Michelson interferometer configuration using a laser diode operated below the threshold, a prism monochromator and a p-i-n photodetector. From the width of the central peak in the measured visibility dependence that narrows with increasing slit width of the monochromator, the spectral bandpass of the monochromator is evaluated. It is also shown how the visibility of the spectral interference fringes decreases as the slit width of the prism spectrometer increases.     

Two-dimensional linear model of elastic shell accounting for general anisotropy of material

A two-dimensional linearly elastic model of shells made of an anisotropic material described by 21 elastic moduli is developed. For this aim, the generalized Timoshenko–Reissner hypotheses are used. In contrast to the ordinary shell models, the tangential stress-resultants here depend not only on the tangential strains but also on the transverse shear. An asymptotic analysis of the obtained equations is fulfilled. The typical stress-strain states, namely the membrane state, the edge effect state, and the boundary layer, are constructed. The system of the Donnell type is delivered. As an example of general anisotropy, a composite material consisting of a matrix reinforced by the system of fibers inclined to the mid-surface is studied. Certain simple static problems and free vibration problems are solved for a cylindrical shell made of this material.     

Automated resolution of connector architectures using constraint solving (ARCAS method)

In current software systems, connectors play an important role by encapsulating the communication and coordination logic. Since they share common patterns (elements) depending on characteristics of the connections, the elements can be predefined and reused. A method of connector implementation based on a composition of predefined elements naturally comprises two steps: resolution of the connector architecture, and creation of the actual connector code based on the architecture. However, manual resolution of a connector architecture is very difficult due to the number of factors to be considered. Thus, the challenge is to come up with an automated method, able to address all the important factors. In this paper, we present a method for automated resolution of connector architectures based on constraint solving techniques. We exploit a propositional logic with relational calculus for defining a connector theory, a constraint specification reflecting both the predefined parts and the important resolution factors, and employ a constraint solver to find a suitable connector architecture as a model of the theory. As a proof of the concept, we show how the theory can be captured in the Alloy language and resolved via the Alloy Analyzer.     

Comparative nanoindentation of single crystals of hard and superhard oxidess

The results have been considered of the studies of the plastic flow initiation in nanoindentation of single crystals of hard and superhard oxides. It has been found that the transition from elastic to elastoplastic deformation in superhard brittle oxides is accompanied by the formation of essentially lower number of dislocations (by an order of magnitude) than in metals. The hardest oxides are sapphire, stishovite, and boron suboxide (B₆O). Up to now the reliable results of nanoindentation have been reported only for sapphire and stishovite. It has been defined that the stishovite hardness is considerably higher than that of sapphire (38 GPa and 28 GPa, respectively). At the same time if the hardness of nanocrystalline sapphire may be expected to be increased up to a limiting value of 48 GPa, the essential increase of the stishovite hardness should not be expected due to a shear softening of the lattice at pressures 40–45 GPa.     

Corrosion of NiTi Wires with Cracked Oxide Layer

Corrosion behavior of superelastic NiTi shape memory alloy wires with cracked TiO₂ surface oxide layers was investigated by electrochemical corrosion tests (Electrochemical Impedance Spectroscopy, Open Circuit Potential, and Potentiodynamic Polarization) on wires bent into U-shapes of various bending radii. Cracks within the oxide on the surface of the bent wires were observed by FIB–SEM and TEM methods. The density and width of the surface oxide cracks dramatically increase with decreasing bending radius. The results of electrochemical experiments consistently show that corrosion properties of NiTi wires with cracked oxide layers (static load keeps the cracks opened) are inferior compared to the corrosion properties of the straight NiTi wires covered by virgin uncracked oxides. Out of the three methods employed, the Electrochemical Impedance Spectroscopy seems to be the most appropriate test for the electrochemical characterization of the cracked oxide layers, since the impedance curves (Nyquist plot) of differently bent NiTi wires can be associated with increasing state of the surface cracking and since the NiTi wires are exposed to similar conditions as the surfaces of NiTi implants in human body. On the other hand, the potentiodynamic polarization test accelerates the corrosion processes and provides clear evidence that the corrosion resistance of bent superelastic NiTi wires degrades with oxide cracking.     

Behavior of Boron in Molten Aluminum and its Grain Refinement Mechanism

The mechanism of heterogeneous grain refining of aluminum by ultrafine elemental boron particles was investigated. In order to facilitate the observation of the boron-aluminum interface, a boron filament was introduced in a melt at 1013 K (740 °C) containing different levels of Ti. The Al/B interface was studied using transmission electron microscopy and different phases were identified using the electron diffraction method. The experimental results showed that boron is dissolved in pure aluminum while its dissolution is inhibited in presence of titanium solute. A thin layer of TiB₂ formed at the surface of boron thickens with residence time in the melt. The mechanisms by which aluminum is crystallized on boron are discussed.