Seismic design of special moment‐resisting steel frame with prevention of soft‐storey mechanism failure

Most structures with masonry infills that are continuous along their height, which are interrupted in the lowest storey, are damaged by earthquakes. These structures are anticipated to collapse due to the undesirable soft‐storey mechanism formed by lateral stiffness of masonry infills in other storeys. The seismic design criteria of UBC97 code for special moment‐resisting steel frame (SMRSF) are reviewed. In this paper, a new criterion for seismic design of such structures is presented. The proposed criteria are used to design three SMRSFs: 5, 8 and 15 storeys. Nonlinear time‐history dynamic analyses are applied for the designed SMRSFs based on the proposed criteria. Displacements and storey drifts, which are obtained by the proposed method, are compared with nonlinear time‐history dynamic analysis results, finally. Copyright © 2011 John Wiley & Sons, Ltd.     

Effect of soft‐storey mechanism caused by infill elimination on displacement demand in nonlinear static procedure using coefficient method

In recent earthquakes, many buildings have been damaged due to the soft‐storey mechanism failure. The seismic design codes for buildings do not contain enough criteria to predict the real displacement of such buildings. This paper focuses on evaluating the nonlinear displacement of buildings that fail in soft‐storey mechanism form. Results show that the nonlinear static procedure with coefficient method, which is described in Chapter 3 of ASCE/SEI 41‐06, does not have sufficient accuracy for estimation of structure displacement demand in such buildings. In this paper, the coefficient methodology is used for evaluating the target displacement for 5‐storey, 8‐storey and 15‐storey special moment resisting steel frames. For this purpose, dynamic nonlinear time‐history analysis has been applied for the mentioned structures having a soft‐storey mechanism failure form. The numerical results of storey displacement and interstorey drift were compared with those values obtained from the coefficient method described in Chapter 3 of ASCE/SEI 41‐06. Copyright © 2012 John Wiley & Sons, Ltd.     

Hydrodynamics of pulsed spouted beds: Effects of pulsation waveform,amplitude, and frequency

The effect of flow pulsations is studied via a discrete element model on hydrodynamics of spouted bed, which is being used in many important industries like drying processes. Decreased horizontal air percolation and preserving upward momentum, increased particle circulation, increased particle traverse distance, and better homogeneity are resulted from flow pulsations in spouted beds. Among the waveforms studied, square and triangular waveforms differ most and least from steady spouting, respectively. The predictions indicate that the pulsed spouted bed has the potential to enhance both gas and particle motion, hence being useful in drying and other operations.     

Synthesis and dissolution behavior of nanosized silicon and magnesium co-doped fluorapatite obtained by high energy ball milling

Nanosized hydroxyapatite (HA) powders exhibit a greater surface area than coarser crystals and are expected to show an improved bioactivity. In addition, properties of HA can be tailored over a wide range by incorporating different ions into HA lattice. The aim of this study was to prepare and characterize silicon and magnesium co-doped fluorapatite (Si–Mg–FA) with a chemical composition of Ca_9.5Mg_0.5 (PO₄)_5.5(SiO₄)_0.5F₂ by the high-energy ball milling method. Characterization techniques such as X-ray diffraction analysis (XRD), Fourier transformed infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDX) and transmission electron microscopy (TEM) were utilized to investigate the structural properties of the obtained powders. Dissolution behavior was evaluated in simulated body fluid (SBF) and physiological normal saline solution at 37 °C for up to 28 days. The results of XRD and FTIR showed that nanocrystalline single-phase Si–Mg–FA powders were synthesized after 12 h of milling. In addition, incorporation of magnesium and silicon into fluorapatite lattice decreased the crystallite size from 53 nm to 40 nm and increased the lattice strain from 0.220% to 0.296%. Dissolution studies revealed that Si–Mg–FA in comparison to fluorapatite (FA), releases more Ca, P and Mg ions into SBF during immersion. 175 ppm Ca, 33.5 ppm P and 48 ppm Mg were detected in the SBF containing Si–Mg–FA after 7days of immersion, while for FA, it was 75 ppm Ca, 21.5 ppm P and 29 ppm Mg. Release of these ions could improve the bioactivity of the obtained nanopowder. It could be concluded that the prepared nanopowders have structural properties such as crystallite size (~40 nm), crystallinity degree (~40%) and chemical composition similar to biological apatite. Therefore, prepared Si–Mg–FA nanopowders are expected to be appropriate candidates for bone substitution materials and also as a phase in polymer or ceramic-based composites for bone regeneration in tissue engineering applications.     

CFD modeling of immiscible liquids turbulent dispersion in Kenics static mixers: Focusing on droplet behavior

The present study is concerned with the computational fluid dynamics(CFD) simulation of turbulent dispersion of immiscible liquids, namely, water–silicone oil and water–benzene through Kenics static mixers using the Eulerian–Eulerian and Eulerian–Lagrangian approaches of the ANSYS Fluent 16.0 software. To study the droplet size distribution(DSD), the Eulerian formulation incorporating a population balance model(PBM) was employed. For the Eulerian–Lagrangian approach, a discrete phase model(DPM) in conjunction with the Eulerian approach for continuous phase simulation was used to predict the residence time distribution(RTD) of droplets.In both approaches, a shear stress transport(SST) k-ω turbulence model was used. For validation purposes, the simulated results were compared with the experimental data and theoretical values for the Fanning friction factor, Sauter mean diameter and the mean residence time. The reliability of the computational model was further assessed by comparing the results with the available empirical correlations for Fanning friction factor and Sauter mean diameter. In addition, the influence of important geometrical and operational parameters, including the number of mixing elements and Weber number, was studied. It was found that the proposed models are capable of predicting the performance of the Kenics static mixer reasonably well.     

Pd(II)/Pd(0) Anchored on Magnetic Organic–Inorganic Hybrid Mesoporous Silica Nanoparticles: A Nanocatalyst for Suzuki–Miyaura and Heck–Mizoroki Coupling Reactions

Journal of Inorganic and Organometallic Polymers and Materials - 3-Chloropropyltrimethoxysilane (CPTMS) was grafted on the surface of silica coated Fe3O4 core (Fe3O4@MCM-41) and then condensed with...     

Thermal,mechanical, and corrosion resistance properties of vinyl ester/clay nanocomposites for the matrix of carbon fiber‐reinforced composites exposed to electron beam

Vinyl ester/clay nanocomposites with 1, 3, and 5% nanoclay contents were prepared. X‐ray diffractography patterns and Scanning Electron micrographs showed that nanocomposites with the exfoliated structure were formed. Thermogravimetric analysis, water absorption test, and Tafel polarization method, respectively, revealed the improvements in thermal resistance, water barrier properties, and corrosion resistance properties of the samples with an increase in the amount of the incorporated nanoclay. Tensile tests showed that nanoclay also enhanced the mechanical properties of the polymer, so that the tensile strength of the samples with 5% nanoclay was more than 3 times higher than tensile strength of pure vinyl ester samples. Overall, the best properties were observed for the samples containing 5% nanoclay. Pure vinyl ester and nanocomposite with 5% nanoclay content were exposed to the electron beam radiation and their mechanical properties improved up to 500 kGy irradiation dose. Finally, pure vinyl ester and vinyl ester/nanoclay (5%) matrixes were reinforced with carbon fiber and the effect of electron beam irradiation on their mechanical properties was examined. The tensile strength and the modulus of the samples initially increased after exposure to the radiation doses up to 500 kGy and then a decrease was observed as the irradiation dose rose to 1000 kGy. Moreover, nanoclay moderated the effect of the irradiation. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42393.     

Flexural and Charpy impact behaviour of epoxy/glass fabric treated by nano-SiO2 and silane blend

A sizing formulation, containing compatible and incompatible silane coupling agents with epoxy resin in conjunction with nanoscale colloidal silica, was used to modify the surface of glass fabric. The modified glass fabric/epoxy resin composite panels were fabricated and characterised by flexural test, Charpy impact test and scanning electron microscope (SEM). By combining nano silica with silane blend in the fabric sizing, more energy was consumed under bending and impacting, which resulted in an improvement of the toughness in composites. The flexural strength, bending stain and Charpy impact strength of the epoxy composite/glass fabric treated with 1?wt-% nano silica and silane blend were ～42, ～22 and 35%, respectively, higher than those of silane blend coated glass fabric-reinforced composites (without nano silica). Furthermore, the change of the brittle fracture of the composite into ductile fracture was investigated by SEM micrographs. A possible toughening mechanism was also proposed.     

Inter-particle heat transfer in a riser of gas-solid turbulent flows

Effects of the particle-particle heat transfer in a gas-solid turbulent flow in a riser were evaluated. An Eulerian/Lagrangian four-way interaction formulation including the particle collisions in conjunction with the k − τ and the k_θ − τ_θ model equations were used in the numerical simulation. Inter-particles and particle-wall interactions were accounted for with an inelastic collision model, where the restitution coefficient was evaluated for each collision. The special case when the flow initially contains two groups of hot and cold particles was treated in details. Particular attention was given to the nature of heat transfer to particles due to inter-particle interactions. The results showed that the effect of particle-particle heat transfer was more significant for smaller sizes, lower flow Reynolds numbers, and for higher loading ratios. Solid thermal properties, however, did not have a noticeable effect on the inter-particle heat transfer. The simulation results indicates that although the heat transferred to each group of hot and cold particles was significant, the mean values of gas and particle temperatures and suspension heat transfer was insensitive to the inter-particle heat transfer.     

Experimental study of onset of subcooled annular flow boiling

An experimental study on the onset of nucleate boiling (ONB) is performed for water annular flow to provide a systematic database for low pressure and velocity conditions. A parametric study has been conducted to investigate the effect of pressure, inlet subcooling, heat and mass flux on flow boiling. The test section includes a Pyrex tube with 21 mm inner diameter and a stainless steel (SS-304) rod with outer diameter of 6 mm. Pressure, heat and mass flux are in the range of 1.73 < P < 3.82 bar, 40 < q < 450 kW/m² and 70 < G < 620 kg/m² s, respectively. The results illustrate that inception heat flux is extremely dependent on pressure, inlet subcooling temperature and mass flux; for example in pressure, velocity and inlet subcooling as 3.27 bar, 230 kg/m² s and 41.3 °C; consequently q_w,ONB is 177.3 kW/m². In other case with higher inlet temperature of 71.5 °C and with P, 3.13 bar and G, 232 kg/m² s the inception heat flux reached to 101.6 kW/m². The data of ONB heat flux are over estimated from the existing correlation, and maximum deviation of wall superheat (ΔT_w,ONB) from correlations is 30%. Experimental data of inception heat flux are within 22% of that predicted from the correlation.