The effect of sputtering gas pressure on structure and photocatalytic properties of nanostructured titanium oxide self-cleaning thin film

Titanium oxide thin films were deposited by DC reactive magnetron sputtering on ZnO (80 nm thickness)/soda-lime glass and SiO₂ substrates at different gas pressures. The post annealing on the deposited films was performed at 400 °C in air atmosphere. The results of X-ray diffraction (XRD) showed that the films had anatase phase after annealing at 400 °C. The structure and morphology of deposited layers were evaluated by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The surface grain size and roughness of TiO₂ thin films after annealing were around 10-15 nm and 2-8 nm, respectively. The optical transmittance of the films was measured using ultraviolet-visible light (UV-vis) spectrophotometer and photocatalytic activities of the samples were evaluated by the degradation of Methylene Blue (MB) dye. Using ZnO thin film as buffer layer, the photocatalytic properties of TiO₂ films were improved.     

A journey across the solid state polymerization to assess the role of critical factors influencing the molecular weight of polylactic acid

Solid state polymerization (SSP) offers an effective route for synthesizing green polymers with variable molecular weights depending on polymerization condition. In this work, critical factors governing the molecular weight of polylactic acid (PLA) in the course of SSP are manipulated systematically and their contributions to the efficiency of SSP process are discussed. The initial molecular weight of the prepolymer formed, the degree of crystallinity of prepolymer, and the SSP time are changed and analyzed for their effects through different analyses including differential scanning calorimetry, gel permeation chromatography, and Fourier‐transform infrared spectroscopy techniques. It was observed that PLA having highest molecular weight would be the result of formation of a prepolymer having low‐molecular weight, as detected by the analysis of functional group concentration. For the optimized sample, the rate of mass loss in SSP was 12,263 g/mol.day and a crystallinity drop over the hydrolysis process was 3.14 per day. The crystallinity of prepolymers was optimized at ca. 26% in regard with the PLA showing the highest molecular weight. J. VINYL ADDIT. TECHNOL., 25:165–171, 2019. © 2018 Society of Plastics Engineers     

Corrosion behavior of Zr41.2Ti13.8Ni10Cu12.5Be22.5 bulk metallic glass in various aqueous solutions

In this study electrochemical corrosion behavior of Zr_41.2Ti_13.8Ni₁₀Cu_12.5Be_22.5 bulk metallic glass (BMG) in various aqueous solutions (3.5% NaCl, 1 N HNO₃, H₂SO₄ and HCl) in order to compare with 316L stainless steel were thoroughly investigated. Scanning electron microscopy (SEM) was used to evaluate the influence of corrosion on the surface topography in immersion specimens to examine where the corrosion pits initiated. Corrosion rate of Zr_41.2Ti_13.8Ni₁₀Cu_12.5Be_22.5 BMG in 3.5% NaCl solution was ∼0.6 mpy and its excellent corrosion resistance can be concluded. Polarization and SEM results also vouched a remarkable corrosion resistance of Zr_41.2Ti_13.8Ni₁₀Cu_12.5Be_22.5 BMG in 3.5% NaCl aqueous solution in comparison with 316L stainless steel.     

Adsorptive desulfurization and denitrogenation of model fuel by mesoporous adsorbents (MSU-S and CoO-MSU-S)

Adsorption of heterocyclic sulfur- and nitrogen-containing compounds by mesostructure adsorbent (MSU-S) and its modified form with cobalt oxide is studied using model fuel. The results of characteristic tests (XRD, N₂ adsorption–desorption, FTIR, and SEM) indicate that CoO impregnation causes a negative impact on mesoporous structure, crystalline phase, and particle shape along with a positive effect on surface ion exchange. CoO modification increased the adsorption loadings of DBT and BT to about 33.6% and 45.7%, respectively. For nitrogen compounds adsorption with the model fuel, adsorption loadings of quinoline and carbazole increase by 6.7% and 8.6%, respectively. Data fitting for carbazole, DBT, and BT is achieved better by the Langmuir model than the Freundlich model, and the data of quinoline fitted very well to the Freundlich model for CoO-MSU-S.     

Interlaminar stress analysis in general thick composite cylinder subjected to nonuniform distributed radial pressure

Interlaminar stresses in thick a composite cylinder with general layer stacking subjected to uniform and nonuniform distributed radial pressure are studied. The layerwise theory of Reddy is employed for formulation of the problem. An analytical method is presented for solving the governing equations. To increase accuracy, interlaminar stresses are obtained by integrating the equilibrium equation of elasticity. After a convergence study, the accuracy of the layerwise laminate theory is investigated using the predictions of finite element method. Predictions of Hooke's law and integration method for interlaminar stresses are compared. Uniform and nonuniform internal and external loads are considered and a parametric study is done for various cylinders.     

Notch stress concepts for the fatigue assessment of welded joints - Background and applications

Among modern fatigue design concepts for welded structures, the linear-elastic notch stress concept gains increasing industrial acceptance. There are two variants of this concept, one for thick walled (t ? 5 mm) welded joints with the reference radius r_ref = 1.00 mm, which is already included in the fatigue design recommendations of the IIW and applied for the assessment of big welded structures, and one for thin walled (t < 5 mm) welded joints with the reference radius r_ref = 0.05 mm, which is more and more used in the automotive industry.The concept with r_ref = 1.00 mm is based on the micro-support theory of Neuber with the fictitious radius r_ref = 1.00 mm, derived by Radaj. The background of the concept with r_ref = 0.05 mm is the relationship between the stress-intensity factor and the notch stress according to Creager and Paris as well as Irvin’s theory of crack blunting. Besides these two theories, the definition of both of these radii has also an experimental background; they are observed in many welded joints.In the present paper, first the background and then different applications of both concept variants are described: the application of the reference radius of r_ref = 1.00 mm for MAG-welded offshore K-nodes (t = 30 mm) and sandwich panels for ship decks (t = 5 mm), and the application of r_ref = 0.05 mm for spot-welded automotive doors (t = 1 mm) and MAG-welded automotive trailing links (t = 3-4 mm). The sandwich panels were evaluated additionally with r_ref = 0.05 mm. Calculations and experimental results are compared and the reliability of the notch stress concept variants underlined. Additionally, recommendations for the slope of design lines distinguishing between thin and thick dimensions are given, i.e. k = 3.0 and 5.0 (normal stress, shear stress) for thick and stiff structures, k = 5.0 and 7.0 for thin and flexible structures.     

On development of a finite dynamic element and solution of associated eigenproblem by a block Lanczos procedure

The paper first presents the details of the development of a new six-noded plane triangular finite dynamic element. A block Lanczos algorithm is developed next for the accurate and efficient solution of the quadratic matrix eigenvalue problem associated with the finite dynamic element formulation. The resulting computer program fully exploits matrix sparsity inherent in such a discretization and proves to be most efficient for the extraction of the usually required first few roots and vectors, including repeated ones. Most importantly, the present eigenproblem solution effort is shown to be comparable to that of the corresponding finite element analysis, thereby rendering the associated dynamic element method rather attractive owing to superior convergence characteristics of such elements, presented herein.     

Synthesis and characterization of yttrium aluminum garnet nanostructures by cathodic electrodeposition method

Pure nanostructures of yttrium aluminum garnet (YAG) was prepared based on the cathodic electrodeposition method from the mixture of YCl₃ and AlCl₃ dissolved in water/ethanol solution. At first, hydroxide precursors cathodically were grown on the steel substrates then, the hydroxide powders heat treated at 850 °C for 4 h in dry air atmosphere. The formation of crystalline YAG nanopowder was confirmed by X-ray diffraction (XRD), thermogravimetric analysis (DSC-TGA), scanning electron microscopy (SEM) and Fourier transformed infrared spectroscopy (FT-IR). The results of the SEM showed that applied current density and bath temperature have the prominent effect on the morphology and particle size of the products. The results revealed that cathodic electrodeposition followed by heat-treatment can be used as a facile method for preparation of YAG nanostructures with different morphology.     

A miniaturised monopole antenna for ultra-wide band applications with band-notch filter

This study presents a new miniaturised printed monopole antenna. The size of the antenna is 18 x 18 mm². First simple design rules are given to arrive at an initial design for the antenna, then the antenna parameters are optimised for utilisation in ultra wide band (UWB) applications. The performance parameters like voltage standing wave ratio (VSWR) of the single antenna as well as transmission function, group delay and the fidelity factor of a two-antenna system are calculated and measured. It is shown that the band-notched performance can be obtained from the designed antenna by introducing simple p-shape or V-shape slots in its radiating element. Good agreements between simulated and measured results are observed.