Structure–Thermodynamic‐Property Relationships in Cyanovinyl‐Based Microporous Polymer Networks for the Future Design of Advanced Carbon Capture Materials

Nitrogen‐rich solid absorbents, which have been immensely tested for carbon dioxide capture, seem until this date to be without decisive molecular engineering or design rules. Here, a family of cyanovinylene‐based microporous polymers synthesized under metal‐catalyzed conditions is reported as a promising candidate for advanced carbon capture materials. These networks reveal that isosteric heats of CO₂ adsorption are directly proportional to the amount of their functional group. Motivated by this finding, polymers produced under base‐catalyzed conditions with tailored quantities of cyanovinyl content confirm the systematical tuning of their sorption enthalpies to reach 40 kJ mol^?1. This value is among the highest reported to date in carbonaceous networks undergoing physisorption. A six‐point‐plot reveals that the structure–thermodynamic‐property relationship is linearly proportional and can thus be perfectly fitted to tailor‐made values prior to experimental measurements. Dynamic simulations show a bowl‐shaped region within which CO₂ is able to sit and interact with its conjugated surrounding, while theoretical calculations confirm the increase of binding sites with the increase of Ph? C?C(CN)? Ph functionality in a network. This concept presents a distinct method for the future design of carbon dioxide capturing materials.     

252 km repeaterless 10 Gb/s transmission demonstration

Using a practical erbium-doped fiber postamplifier, a dual-stage optical preamplifier, a lithium niobate Mach-Zehnder external modulator and a dispersion-shifted line fiber, IM/DD repeaterless transmission over 252 km at 10 Gb/s with a wavelength-independent receiver sensitivity in the 1530-1565-nm range is achieved     

Determination of scattering parameters of junctions associated with electromagnetic topology

This paper is dedicated to the determination of topological S parameters in the transmission line networks. We are especially interested in ideal junctions which consist of short circuit connections. For this type of junctions, it is impossible to deduce the S parameters from the usual impedance or admittance matrices which are not defined in this case. We suggest a method allowing a direct calculation of S. This procedure is described and then carried out for a two wire fork. At last, an experimental application is given for this model.     

Compilation Methods for the Address Calculation Units of Embedded Processor Systems

An essential component of today's embedded system is an instruction-set processor running real-time software. All variations of these core components contain at least the minimum data-flow processing capabilities, while a certain class contain specialized units for highly data-intensive operations for Digital Signal Processing (DSP). For the required level of memory interaction, the parallel executing Address Calculation Unit (ACU) is often used to tune the architecture to the memory access characteristics of the application. The design of the ACU is performance critical. In today's typical design flow, this design task is somewhat driven by intuition as the transformation from application algorithm to architecture is complex and the exploration space is immense. Automatic utilities to aid the designer are essential; however, the key compilation techniques which map high-level language constructs onto addressing units have lagged far behind the emergence of these units. This paper presents a new retargetable approach and prototype tool for the analysis of array references and traversals for efficient use of ACUs. In addition to being an enhancement to existing compiler systems, the ArrSyn utility may be used as an aid to architecture exploration. A simple specification of the addressing resources and basic operations drives the available transformations and allows the designer to quickly evaluate the effects on speed and code size of his/her algorithm. Thus, the designer can tune the design of the ACU toward the application constraints. ArrSyn has been successfully used together with a C compiler developed for a VLIW architecture for an MPEG audio decoding application. The combination of these methods with the C compiler showed on average a 39% speedup and 29% code size reduction for a representative set of DSP benchmarks.     

A full-wave analysis of interconnection planar lines applications to structures with finite ground plane

The high integration level associated to the increase of the operating frequency of microelectronic integrated circuits create complex electromagnetic coupling in the interconnection lines which lead to mismatch and frequency dispersion. In the present paper, we propose a full-wave analysis to characterise the electromagnetic behaviour of interconnection planar lines using mixed-potential integral equations technique. The theoretical and numerical treatments of Green’s functions for the specific structures are firstly presented. The calculated results for parallel and coplanar strips are compared to the published ones. The effect of the finite ground plane on the propagation constant and the characteristic impedance is then analysed for different permittivities. The obtained theoretical and experimental results for the reflection coefficient of straight resonators confirm finally the observed effect of the finite ground plane on the frequency dispersion and the scattering characteristics.     

Passive alignment optical subassemblies for military/aerospacefiber-optic transmitter/receiver modules

Under the DARPA sponsored Avionics Optoelectronic Module Technology program, new passive alignment carrier (PAC) optical subassemblies (LED-PAC and PIN-PAC) ruggedized for military/aerospace avionics fiber-optic transmitter and receiver applications have been developed, LED-PAC and PIN-PAC silicon micro-optical bench substrates were fabricated together on a 5 in diameter silicon wafer via multistage photolithography, thin-film, and substrate processing. Alignment v-grooves designed for passive optical alignment of 100/140 μm multimode optical fiber to the optoelectronic devices were terminated by solder locking the fiber to the silicon PAC substrates. The LED-PAC comprising a surface emitting LED die-bonded onto a novel precision molded AM submount passively mounted onto the silicon microbench achieves the required high coupling efficiency to 100/140 μm multimode optical fiber to meet stringent avionics transmitter output power requirements. The 100/130 μm multimode optical fiber-pigtailed PIN-PAC with a refractive lens etched into the p-i-n photodiode backside surface exhibited responsivities greater than 0.8 A/W at 1.3 μm wavelength. The LED-PAC and PIN-PAC optical subassemblies integrated with Boeing ARINC 636 (FDDI) transmitter and receiver thick film multichip (MCM-C) circuitry are capable of meeting both ARINC 636 and FDDI physical layer requirements     

3.2 Tbit/s (80 × 40 Gbit/s) phase-shaped binary transmissionover 3 × 100 km with 0.8 bit/s/Hz efficiency

50 GHz-spaced 80 × 40 Gbit/s WDM transmission over 300 km of TeraLight^TM fibre is demonstrated without polarisation demultiplexing, using the PSBT format. A record capacity of 3.2 Tbit/s is thus achieved over the C-band only, with a spectral efficiency of 0.8 bit/s/Hz     

Development of the transmission line matrix method in acoustics applications to higher modes in the vocal tract and other complex ducts

Most traditional theories of speech production are currently based on plane waves. However, it is well known that, for acoustic waveguides, higher acoustical modes start to propagate and can become predominant above cut-on frequencies. This paper thus presents the transmission line matrix method, a numerical method initially designed for electromagnetic waves, and its adaptation to acoustic waveguides. The method, and in particular the representation of boundary conditions, is validated by comparison with known analytical theories. It is then used to show the dramatic effect of higher order modes upon the radiation characteristics of uniform ducts, as well as the importance of source location. Finally, first applications to bent and bifurcating rectangular ducts are presented, and the transfer function of a vowel [a] is shown to display frequency patterns typical of those measured on human subjects and that cannot be explained by one-dimensional propagation only. © 1998 John Wiley & Sons, Ltd.     

Multihour engineering and traffic routing optimization in hierarchical telephone networks

Classical hierarchical routing in telephone networks is extended to a wider class called out-of-chain routing in such a way that some useful properties of hierarchical routing are retained. This new routing pattern offers more potential paths than the fixed hierarchical one and can be introduced as a dynamic routing where the fixed alternate sequences change at some predetermined instants during the day. The effect of this new routing pattern on the network performances is examined. The main topic of this paper is to present heuristic methods used to optimise such routings in large networks. We show on artificial networks that the throughput of a given network can be significantly improved by suitable routing choices. We demonstrate that the integration of routing changes within a multihour dimensioning process is possible but the lack of realistic data does not permit at this time to quantify the value of routing optimization on real networks.