全文获取类型
收费全文 | 944篇 |
免费 | 63篇 |
国内免费 | 4篇 |
专业分类
电工技术 | 9篇 |
化学工业 | 263篇 |
金属工艺 | 31篇 |
机械仪表 | 25篇 |
建筑科学 | 19篇 |
矿业工程 | 1篇 |
能源动力 | 25篇 |
轻工业 | 16篇 |
石油天然气 | 7篇 |
无线电 | 94篇 |
一般工业技术 | 306篇 |
冶金工业 | 85篇 |
原子能技术 | 11篇 |
自动化技术 | 119篇 |
出版年
2024年 | 1篇 |
2023年 | 17篇 |
2022年 | 37篇 |
2021年 | 50篇 |
2020年 | 20篇 |
2019年 | 38篇 |
2018年 | 38篇 |
2017年 | 33篇 |
2016年 | 45篇 |
2015年 | 36篇 |
2014年 | 34篇 |
2013年 | 56篇 |
2012年 | 71篇 |
2011年 | 75篇 |
2010年 | 45篇 |
2009年 | 57篇 |
2008年 | 51篇 |
2007年 | 46篇 |
2006年 | 51篇 |
2005年 | 38篇 |
2004年 | 29篇 |
2003年 | 28篇 |
2002年 | 25篇 |
2001年 | 10篇 |
2000年 | 10篇 |
1999年 | 7篇 |
1998年 | 5篇 |
1997年 | 8篇 |
1996年 | 7篇 |
1995年 | 6篇 |
1994年 | 7篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1974年 | 1篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1956年 | 1篇 |
1954年 | 2篇 |
排序方式: 共有1011条查询结果,搜索用时 15 毫秒
31.
Akylbek Sydykov Himal Luitel Argen Mamazhakypov Malgorzata Wygrecka Kabita Pradhan Oleg Pak Aleksandar Petrovic Baktybek Kojonazarov Norbert Weissmann Werner Seeger Friedrich Grimminger Hossein Ardeschir Ghofrani Djuro Kosanovic Ralph Theo Schermuly 《International journal of molecular sciences》2020,21(23)
Although the response of the right ventricle (RV) to the increased afterload is an important determinant of the patient outcome, very little is known about the underlying mechanisms. Mast cells have been implicated in the pathogenesis of left ventricular maladaptive remodeling and failure. However, the role of mast cells in RV remodeling remains unexplored. We subjected mast cell-deficient WBB6F1-KitW/W-v (KitW/KitW-v) mice and their mast cell-sufficient littermate controls (MC+/+) to pulmonary artery banding (PAB). PAB led to RV dilatation, extensive myocardial fibrosis, and RV dysfunction in MC+/+ mice. In PAB KitW/KitW-v mice, RV remodeling was characterized by minimal RV chamber dilatation and preserved RV function. We further administered to C57Bl/6J mice either placebo or cromolyn treatment starting from day 1 or 7 days after PAB surgery to test whether mast cells stabilizing drugs can prevent or reverse maladaptive RV remodeling. Both preventive and therapeutic cromolyn applications significantly attenuated RV dilatation and improved RV function. Our study establishes a previously undescribed role of mast cells in pressure overload-induced adverse RV remodeling. Mast cells may thus represent an interesting target for the development of a new therapeutic approach directed specifically at the heart. 相似文献
32.
33.
Yang Jian Wang Qi Zhang Jianqiang Ostrovski Oleg Zhang Chen Cai Dexiang 《Metallurgical and Materials Transactions B》2019,50(6):2794-2803
Metallurgical and Materials Transactions B - CaO-Al2O3-based mold fluxes, which are under development for the continuous casting of high-Al steel, contain fluxing compounds, such as Na2O and B2O3.... 相似文献
34.
Oleg Vasylkiv Yoshio Sakka Valeriy V. Skorokhod 《Journal of the American Ceramic Society》2006,89(6):1822-1826
CeCl3 ·7H2 O and GdCl3 ·6H2 O that were dissolved in water were precipitated with urea (NH2 CONH2 ) to produce matrix agglomerates for three-component nano-reactors. Mixing hexamethylenetetramine with dilute nitric acid resulted in the formation of well-dispersed nano-particles of cyclotrimetilene trinitramine (C3 H6 N6 O6 ) (RDX) in the solvent. Nano-reactors were produced by impregnating the nano-C3 H6 N6 O6 into the matrix agglomerates of an intermediate complex of cerium and gadolinium compounds. Blast initiation of the C3 H6 N6 O6 resulted in extremely rapid detonation and gaseous products formation at temperatures of 2000°–5000°C, which were compressed into a volume nearly equal to the initial volume of each RDX nano-particle. Multiple "nano-blasts" occurred in the volume of each nano-reactor. The impact of the blast waves led to fragmentation of the surrounding matter. The evolution of a large volume of gaseous products dissipated the heat of the process and limited temperature increase, thus reducing the possibility of local sintering among the primary particles. The short-term high temperature generated during the blasts enhanced the solid solubility of the metal oxides. Uniform aggregates of 22∼74 nm consisting of 6∼14 nm crystallites of gadolinia in ceria solid solution were synthesized. 相似文献
35.
Oleg Vasylkiv Yoshio Sakka Valeriy V. Skorokhod 《Journal of the American Ceramic Society》2003,86(2):299-304
The 1.5- to 3-mol%-Y2 O3 -stabilized tetragonal ZrO2 (Y-TZP) and Al2 O3 /Y-TZP nanocomposite ceramics with 1 to 5 wt% of alumina were produced by a colloidal technique and low-temperature sintering. The influence of the ceramic processing conditions, resulting density, microstructure, and the alumina content on the hardness and toughness were determined. The densification of the zirconia (Y-TZP) ceramic at low temperatures was possible only when a highly uniform packing of the nanoaggregates was achieved in the green compacts. The bulk nanostructured 3-mol%-yttria-stabilized zirconia ceramic with an average grain size of 112 nm was shown to reach a hardness of 12.2 GPa and a fracture toughness of 9.3 MPa·m1/2 . The addition of alumina allowed the sintering process to be intensified. A nanograined bulk alumina/zirconia composite ceramic with an average grain size of 94 nm was obtained, and the hardness increased to 16.2 GPa. Nanograined tetragonal zirconia ceramics with a reduced yttria-stabilizer content were shown to reach fracture toughnesses between 12.6–14.8 MPa·m1/2 (2Y-TZP) and 11.9–13.9 MPa·m1/2 (1.5Y-TZP). 相似文献
36.
Wei Li Zhen Yue Artur Lozovoi Oleg Petrov Carlos Mattea Siegfried Stapf 《Journal of Polymer Research》2018,25(11):239
The structure of chain entanglements in the solid state is important for revealing the relationship of structure and properties of polyolefin. In this work, low-field solid-state 1H NMR is used to study the chain dynamics of ultra-high molecular weight polyethylene (UHMWPE) in the solid state. It has been found that the relaxation distribution, analyzed by a multi-exponential inversion program, is an effective method to characterize the heterogeneous chain mobility. It is evidenced from the results that the UHMWPE in a less entangled state presents an obviously heterogeneous distribution of chain mobility in the non-crystalline phase, corresponding to its heterogeneous distribution of entangled points. In comparison, the commercial UHMWPE with a large number of entanglements shows a much more uniform mobility of the non-crystalline components. This heterogeneous distribution of chain mobility becomes even more critical after annealing the samples below the melting point, especially for the less entangled UHMWPE. 相似文献
37.
Vladimir S. Derevschikov Janna V. Veselovskaya Anton S. Shalygin Dmitry A. Yatsenko Andrey Z. Sheshkovas Oleg N. Martyanov 《中国化学工程学报》2022,46(6):11-20
Potassium carbonate-based sorbents are prospective materials for direct air capture (DAC). In the present study, we examined and revealed the influence of the temperature swing adsorption (TSA) cycle conditions on the CO2 sorption properties of a novel aerogel-based K2CO3/ZrO2 sorbent in a DAC process. It was shown that the humidity and temperature drastically affect the sorption dynamic and sorption capacity of the sorbent. When a temperature at the sorption stage was 29 ℃ and a water vapor pressure in the feed air was 5.2 mbar (1 bar = 105 Pa), the composite material demonstrated a stable CO2 sorption capacity of 3.4% (mass). An increase in sorption temperature leads to a continuous decrease in the CO2 absorption capacity reaching a value of 0.7% (mass) at T = 80 ℃. The material showed the retention of a stable CO2 sorption capacity for many cycles at each temperature in the range. Increasing PH2O in the inlet air from 5.2 to 6.8 mbar leads to instability of CO2 sorption capacity which decreases in the course of 3 consecutive TSA cycles from 1.7% to 0.8% (mass) at T = 29 ℃. A further increase in air humidity only facilitates the deterioration of the CO2 sorption capacity of the material. A possible explanation for this phenomenon could be the filling of the porous system of the sorbent with solid reaction products and an aqueous solution of potassium salts, which leads to a significant slowdown in the CO2 diffusion in the composite sorbent grain. To investigate the regeneration step of the TSA cycle in situ, the macro ATR-FTIR (attenuated total reflection Fourier-transform infrared) spectroscopic imaging was applied for the first time. It was shown that the migration of carbonate-containing species over the surface of sorbent occurs during the thermal regeneration stage of the TSA cycle. The movement of the active component in the porous matrix of the sorbent can affect the sorption characteristics of the composite material. The revealed features make it possible to formulate the requirements and limitations that need to be taken into account for the practical implementation of the DAC process using the K2CO3/ZrO2 composite sorbent. 相似文献
38.
Oleg A. Kazantsev Dmitry V. Orekhov Denis M. Kamorin Maria V. Savinova 《Designed Monomers and Polymers》2017,20(1):136-143
Concentration effects in the base-catalyzed hydrolysis of water-soluble methacrylates (3-(N,N-dimethylaminoethyl) methacrylate (DMAEMA), 2-hydroxyethyl methacrylate (HEMA) and oligo(ethylene glycol) methacrylates (OEGMAs)) have been studied. These monomers are rapidly hydrolyzed in the presence of bases at the room temperature in dilute aqueous solutions, but the reaction rate decreases sharply in highly concentrated solutions. A clear correlation was found between a form of the viscosity isotherm for DMAEMA solutions and the concentration dependence of the autocatalytic hydrolysis rate which indicates the connection of process kinetics with the structure of solutions. These data should be considered when carrying out homo- and copolymerization of the previously mentioned monomers in aqueous solutions. 相似文献
39.
Zoltan Zyman Matthias Epple Anton Goncharenko Dmytro Rokhmistrov Oleg Prymak Kateryna Loza 《Journal of materials science. Materials in medicine》2017,28(3):52
Thermal evolution of amorphous calcium phosphate (ACP) powder from a fast nitrate synthesis with a Ca/P ratio of 1:1 were studied in the range of 20–980?°C. The powder consisted of amorphous dicalcium phosphate anhydrate (CaHPO4) after heating to 200?°C. CaHPO4 gradually condensed to amorphous calcium pyrophosphate Ca2P2O7 (CPP) between 200 to 620?°C. Amorphous CPP crystallized at 620–740?°C to a metastable polymorph α′-CPP of the high-temperature phase α-CPP and β-CPP. The α′-CPP/ β-CPP phase ratio reached a maximum at 800?°C (60?wt% α′-CPP/40?wt% β-CPP), and α′-CPP gradually transformed to β-CPP at a higher temperature. Some β-TCP occurred at 900?°C, so that a three-phasic mixture was obtained in the powder heated to 980?°C. The occurrence of metastable α′-CPP is attributed to Ostwald’s step rule, and a mechanism for β-TCP formation is proposed. The advantages of prospective biomaterials from these powders are discussed. 相似文献
40.
Carlo S. Iorio Olga Goncharova Oleg A. Kabov 《Microgravity science and technology》2009,21(Z1):313-319
When a layer of volatile liquid is exposed to a shear flow of inert gas, thermal patterns, in the form of interfacial ripples
and bulk plumes, are created by the combined action of evaporative, shear-driven and surface-tension-driven instabilities.
The topology of the interfacial thermal patterns is mainly influenced by the geometry of the evaporating surface, the thickness
of the evaporating layer, the intensity of the shear flow and by the physic-chemical properties of the working fluid. In this
paper, by means of numerical simulations, we focused our attention on the dynamics of the interfacial thermal patterns for
different working fluids and thicknesses of the volatile liquid layer. This study has been performed in the frame of the ESA
sponsored Space Program on heat and mass transfer CIMEX-1. The choice of the fluids—ethyl alcohol and FC72 (n-perfluorohexane)—the
reference values for the inert gas flow rate, the thickness of the liquid layer as well as the geometrical features of the
computational domain correspond exactly to the ones foreseen for the CIMEX-1 experiment. However, the main conclusions can
be considered of more general validity. 相似文献