Electrical properties of La0.6Sr0.4Co1-yFeyO3 cathode material

The electrical properties of La0.6Sr0.4Co1-yFeyO3 （LSCF, y=0-1.0） cathode materials were measured by DC four probes, X-ray photo-electron spectrum （XPS） was also introduced to determine the chemical state of Co, F.e ions in LSCF. It is found that the electrical conductivity of each sample has a maximum value with increasing temperature. XPS analysis shows that Co ion has three different chemical states, corresponding to two with Fe ion. The analyses indicates that the small-polaron hopping mechanism dominates the electron conduction at low temperature, while at high temperature, the three factors such as the thermally activated disproportionation of Co^3＋ ions into Co^2＋ and Co^4＋ pairs, the ionic compensation of oxygen vacancies formed at high temperatures, and Fe^4＋ ions charge compensation preferential to Co^4＋, all contribute to electrical conduction.     

Relationship between yield ratio and the material constants of the Swift equation

The relationship between the yield ratio and the material constants,b andN, of the Swift equation for hotrolled low carbon steels has been established. The yield ratio calculated by using the Swift equation agrees well with an experimentally obtained yield ratio. It was found that the yield ratio decreases with an increasing value ofN or with a decreasing value ofb. It was also found, however, that high yield strength is associated with small values of bothb andN. Therefore, to obtain both high yield strength and low yield ratio, a detailed microstructural control is needed to determine the optimum values ofb andN.     

定、转子冲片级进模维护要领及常见故障的排除

通过对电机定、转子片级进冲模结构形式的分类、凸模、凹模常见的固定方式的介绍，阐述了电机定、转子片级进冲模模具在日常使用中的维护和保养要领。重点介绍了凸模、凹模的更换程序，卸料板的安装程序，以及模具在使用中常见故障原因的分析和排除方法。     

水口结瘤对板坯连铸结晶器钢水行为影响的数值模拟

以230 mm×1 600 mm板坯连铸机结晶器为研究对象,采用CFD数值模拟的计算方法,建立了VOF模型,研究了连铸水口结瘤对钢渣界面波动与钢液流动行为的影响。研究结果表明,当水口无结瘤时,结晶器内流场为典型的双环流形貌。当水口有结瘤时,结晶器内水口两侧会出现严重的非对称流,结瘤侧流股范围小,非结瘤侧流股范围大。水口不结瘤一侧动能增大导致结晶器下涡心位置下降,会使钢液冲击深度增大;水口结瘤一侧水口因涡心位置较高,加剧了弯月面处的波动和钢渣表面的波动紊乱。结瘤情况下的钢液波动较大,最大波动差为4.03 mm;不结瘤情况下钢液波动较平稳,最大波动差为1.4 mm。     

超声及电磁场对铝合金熔体影响的数值模拟及试验研究

针对铝合金熔体的超声及电磁搅拌处理过程,创建了超声场、电磁场、流场和温度场的数学模型,并采用COMSOL Multiphysics软件求解模型,得到了超声场、电磁场和超声/电磁复合场对铝合金熔体内流场和温度场的分布规律,并通过试验对模拟结果进行了验证。结果表明,增加超声功率使得声压幅值和流场的流动速率均随之增加,同时会使熔体的温度梯度逐渐减小;施加电磁场后产生的电磁搅拌改变了熔体的流动方向且使熔体的流动速率显著增大,这对熔体的温度分布产生了较大影响;在超声和电磁复合场下,电磁场比超声场对熔体流场和温度场的影响更大,且占主导地位。数值模拟结果和试验结果符合较好。     

复合加载方式作用下熔合线上含裂纹焊接接头的裂端场与断裂参量

针对复合载荷作用下熔合线含裂纹的焊接接头,应用弹塑性有限元方法分析了其裂端应力场的分布规律.并对不同组配焊接接头的COD断裂参量及其复合角进行了数值计算,讨论了加载角度和接头强度组配对焊接接头断裂行为及断裂参量的影响机制.研究结果表明,对于复合载荷作用下的熔合线含裂纹焊接接头,其裂端应力场同时受到加载角度以及材料非均匀性的影响.当加载角度较小时,复合载荷对接头性能的影响相对于接头组配的影响更为显著.而当加载角度达到并超过30°时,情况与之相反.     

Superplasticity of fine-grained 7475 Al alloy and a proposed new deformation mechanism

A study has been made to investigate the superplastic deformation mechanisms of 7475 Al alloy in relation to the variation of grain size ranging between 5.5 μm and 13 μm. The strain-rate sensitivity (m) was increased with decreasing grain size in the superplastic deformation regime. Microstructural investigation after tension tests revealed that the dispersoid free zones were produced mostly at the grain boundaries normal to the tensile direction. A new model for describing the deformation behavior of the 7475 Al alloy has been proposed based on the assumption that the grain boundary sliding was accommodated by both diffusional flow and slip. This new model well predicts many aspects of experimental results.     

The form error prediction in side wall machining considering tool deflection

In this research, an effective method for the form error prediction in side wall machining with a flat end mill is suggested. The form error is predicted directly from the tool deflection without surface generation by cutting edge locus with time simulation. The developed model can predict the surface form error accurately about 300 times faster than the previous method. Cutting forces and tool deflection are calculated considering tool geometry, tool setting error and machine tool stiffness. The characteristics and the difference of generated surface shape in up milling and down milling are discussed. The usefulness of the presented method is verified from a set of experiments under various cutting conditions generally used in die and mold manufacturing. This study contributes to real time surface shape estimation and cutting process planning for the improvement of form accuracy.     

中厚板在线30通道超声波探伤方法及应用

介绍了柳钢公司在生产锅炉板、压力容器板过程中，曾试用了６种探伤方法；而研制的３０通道在线超声波探伤法不仅可满足国家标准要求，而且能适应生产节奏，并具有快速、准确、简便的特点。