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81.
The behavior of two series of concrete slabs exposed to sulfate-bearing soils was investigated by a numerical model called
STADIUM. In addition to the diffusion of ions and moisture, the model also accounts for the effects of dissolution/precipitation
reactions on the transport mechanisms. The simulations yielded by the model were compared to the actual degradation of the
slabs after 8 years of exposure. The microstructural alterations of concrete resulting from the penetration of magnesium,
chloride and sulfate ions were studied by backscatter mode scanning electron microscope observations and energy-dispersive
X-ray analyses. The comparison of both series of data indicates that the model can reliably predict the various features of
the microstructural alterations of concrete.
Editorial Note Laval University (Canada) is a RILEM Titular Member. Prof. J. Marchand was awarded the 2000 Robert L'Hermite Medal. He is Editor in Chief for Concrete Science and Engineering and Associate Editor for Materials and Structures. He participates in RILEM TC 186-ISA ‘Internal Sulfate attack’. 相似文献
Résumé Le comportement de deux séries de dalles sur sol en béton exposées à des sols chimiquement agressifs a été étudié à l'aide d'un code de calcul numérique appelé STADIUM. Ce modèle permet de décrire le transport couplé de l'eau et des ions dans des matériaux poreux non-saturés en prenant en considération l'influence des réactions chimiques. Les résultats des simultations de la dégradation du béton après huit ans d'exposition à des ions chlore, sulfate et magnésium. Les observations ont été réalisées par microscopie électronique à balayage. Des analyses par dispersion des rayons X ont également été effectuées. Les données démontrent clairement que le modèle perment de prédire avec précision le comportement du béton soumis à différents types d'agression chimique.
Editorial Note Laval University (Canada) is a RILEM Titular Member. Prof. J. Marchand was awarded the 2000 Robert L'Hermite Medal. He is Editor in Chief for Concrete Science and Engineering and Associate Editor for Materials and Structures. He participates in RILEM TC 186-ISA ‘Internal Sulfate attack’. 相似文献
82.
A general formalism for the study of nonlinear pulse propagation in optical fibres is presented. It is then applied to study the time evolution of a Gaussian laser pulse in a fibre with cubic and fifth-order nonlinearity in the index of refraction. The results are presented and discussed. 相似文献
83.
84.
85.
U. Rambabu N. R. Munirathnam T. L. Prakash B. Vengalrao S. Buddhudu 《Journal of Materials Science》2007,42(22):9262-9266
High purity gallium oxide nanopowders have been synthesized by using a simple precipitation technique with calcination at
elevated temperature. From the X-ray pattern, the phase purity of the synthesized powders was confirmed as β-Ga2O3. Elemental quantification (stoichiometry) of Ga2O3 was also examined from the X-ray energy dispersive analysis (EDAX). Based on the recorded Fourier Transform Infrared (FTIR)
spectrum of Ga2O3, the IR bands due to Ga–O bond and crystal lattice vibrations have been identified in the wavenumber range 400–4,000 cm−1. From the measured SEM images, it is obvious to notice that the pH value has been playing a dominant role in obtaining morphologically
different gallium oxide nanopowders. Thermogravimetric analysis reveals 8.3% of weight loss when the sample was heated to
the temperature of 1,100 °C from the room temperature, which also shows a crystalline phase transformation. It is very interesting
to report that a broad blue emission at 455 nm has been measured from the synthesized gallium oxide nanopowders. 相似文献
86.
Tanu Sharma Sanjeev Aggarwal Shyam Kumar V. K. Mittal P. C. Kalsi V. K. Manchanda 《Journal of Materials Science》2007,42(4):1127-1130
The UV-Visible absorption spectra of virgin and gamma irradiated (20–800 kGy) CR-39 polymer have been deduced by using Shimadzu
Double beam Double Monochromator UV-Visible Spectrophotometer (UV-2550). The existence of the peaks, their shifting and broadening
as a result of gamma irradiation has been discussed. Finally the indirect and direct band gap in virgin and gamma irradiated
CR-39 has been determined. The values of indirect band gap have been found to be lower than the corresponding values of direct
band gap. 相似文献
87.
88.
Some substituted coumarins have been synthesized by von-Pechmann condensation using SnCl2 · 2H2O (10 mol %) as catalyst in ethanolic medium. The reactions are simple, easy in handling and environmentally benign. 相似文献
89.
90.
Recent advances in isotropic conductive adhesives for electronics packaging applications 总被引:4,自引:0,他引:4
Isotropic conductive adhesives (ICAs) have recently received a lot of focus and attention from the researchers in electronics industry as a potential substitute to lead-bearing solders. Numerous studies have shown that ICAs possess many advantages over conventional soldering such as environmental friendliness, finer pitch printing, lower temperature processing and more flexible and simpler processing. However, complete replacement of soldering by ICAs is yet not possible owing to several limitations of ICAs which are mainly related to reliability aspects like limited impact resistance, unstable contact resistance, low adhesion and conductivity etc. Continued efforts for last 15 years have resulted in development of ICAs with improved properties. This review article is aimed at providing a better understanding of ICAs, their principles, performance and significant research and development work addressing the technological utility of ICAs. 相似文献