Differential scanning calorimetric investigation of curing of resins formed from furfural and various phenols

Curing reactions of adequately characterized phenol-furfural, o-chlorophenol-furfural, P-chlorophenol-furfural and p-tert-butyl phenol-furfural resins with hexamine were studied by differential scanning calorimetry. The data are analyzed by appropriate empirical relations with a view to examining their applicability to the present sets of data and to estimating kinetic parameters of the curing reactions.     

Simultaneous absorption of two gases which react between themselves in a liquid medium: An approximate solution

An approximate solution for the simultaneous absorption and reaction of two gases in a liquid has been presented based on the film theory, assuming a nonlinear (exponential) profile for the concentration of each of the gaseous species in the film. The solution obtained has been compared with the numerical solution of Roper, Hatch and Pigford and found to be in good agreement, thus proving the validity of the approximations.     

Simulation of molecular weight distribution and cyclic oligomer formation in the polymerization of nylon 6

The reversible polymerization of nylon 6 including ring opening, polycondensation, polyaddition, and cyclization reactions as well as the reaction with monofunctional acids was simulated for an isothermal batch reactor at 235°C. The cyclic oligomer concentrations, the molecular weight distributions, and its moments have been computed using a chain length-dependent equilibrium constant for the cyclization reaction. Even though the cyclization step does not influence the monomer conversion considerably, it does effect the molecular weight distribution and its moments.     

Throughput Analysis and Admission Control for IEEE 802.11a

We propose a new Markov model for the distributed coordination function (DCF) of IEEE 802.11. The model incorporates carrier sense, non-saturated traffic and SNR, for both basic and RTS/CTS access mechanisms. Analysis of the model shows that the throughput first increases, and then decreases with the number of active stations, suggesting the need for an admission control mechanism.We introduce such a mechanism, which tries to maximize the throughput while maintaining a fair allocation. The maximum achievable throughput is tracked by the mechanism as the number of active stations increases. An extensive performance analysis shows that the mechanism provides significant improvements.Mustafa Ergen received the B.S. degree in electrical engineering from Middle East Technical University (METU) and was the METU Valedictorian in 2000. He received the M.S. and Ph.D. degrees in electrical engineering in 2002 and 2004, the MOT certificate of HAAS Business School in 2003, and the M.A. degree in International and Area Studies in 2004 from the University of California, Berkeley.Dr. Ergen has been conducting research in wireless communication networks with an emphasis on sensor networks, wireless LAN and OFDM systems and is the author of many works in the field, including the book (with A.R.S. Bahai and B.R. Saltzberg) Multi-Carrier Digital Communications: Theory and Applications of OFDM (New York: Springer, 2004).He is National Semiconductor Post Doctoral Fellow and was awarded eight times Bulent Kerim Altay Award by department of electrical engineering in METU and received Best Student Paper Award in IEEE ISCC 2003 and has an invited paper in IEEE GLOBECOM CAMAD 200.Pravin Varaiya is Nortel Networks Distinguished Professor in the Department of Electrical Engineering and Computer Sciences at the University of California, Berkeley. From 1975 to 1992, he was also Professor of Economics at Berkeley. His research is concerned with communication networks, transportation, and hybrid systems. He has taught at MIT and the Federal University of Rio de Janeiro, Varaiya has held a Guggenheim Fellowship and a Miller Research Professorship. He received an Honorary Doctorate from L’Institut National Polytechnique de Toulouse, and the Field Medal of the IEEE Control Systems Society. He is a Fellow of IEEE and a member of the National Academy of Engineering. He is on the editorial board of several journals, including “Discrete Event Dynamical Systems” and “Transportation Research-C.” He has co-authored three books and more than 250 technical papers. The second edition of “High-Performance Communication Networks” (with Jean Walrand) was published by Morgan-Kaufmann in 2000. “Structure and interpretation of signals and systems” (with Edward Lee) was published in 2002 by Addison-Wesley.     

High Power Factor Operation of a Three-Phase Rectifier for an Adjustable-Speed Drive

This paper presents a novel approach to improve the power factor (PF) and reduce the harmonics generated by an adjustable-speed drive (ASD). A high-frequency (HF) current injection technique is used to improve the PF and harmonic performance. The HF current at the same switching frequency (33 kHz) is injected into the input of a front-end rectifier from the output of an HF inverter. The main feature of the circuit is that it does not require any additional active devices for current injection. The inverter driving the induction motor is operated using a sinusoidal pulsewidth-modulation technique. The circuit simulation and experimental prototype results are presented for 67-hp (50 kW) and 3-hp three-phase induction motors, respectively.     

On the Joint Synchronization of Clock Offset and Skew in RBS-Protocol

Motivated by the necessity of having a good clock synchronization amongst the nodes of wireless ad-hoc sensor networks, the joint maximum likelihood (JML) estimator for clock phase offset and skew under exponential noise model for reference broadcast synchronization (RBS) protocol is formulated and found via a direct algorithm. The Gibbs sampler is also proposed for joint clock phase offset and skew estimation and shown to provide superior performance relative to JML- estimator. Lower and upper bounds for the mean-square errors (MSE) of JML-estimator and Gibbs Sampler are introduced in terms of the MSE of the uniform minimum variance unbiased (UMVU) estimator and the conventional best linear unbiased estimator (BLUE), respectively.     

Allergenic responses of red kidney bean (Phaseolus vulgaris cv chitra) polypeptides in BALB/c mice recognized by bronchial asthma and allergic rhinitis patients

Allergenicity potential of red kidney beans (Phaseolus vulgaris cv chitra) was assessed and attempts were made to identify the responsible proteins by pepsin digestibility assay and IgE immunoblotting. To evaluate allergenic potential, BALB/c mice were sensitized with red kidney bean proteins and levels of specific immunoglobulin, histamine, mast cell protease-1, cytokines and CCL-2 were measured. To confirm our findings in BALB/c, the studies were also extended to human subjects. Human sera collected from control subjects and allergic patients after skin prick test were used for IgE immunoblotting, measuring the levels of total and specific IgE and determining cross reactivity of red kidney bean with other legumes. Red kidney bean allergenic potential was evident by significant increase in specific IgE, IgG1, histamine, mast cell protease-1 and Th2 cytokine levels in comparison to control. Enhanced level of eosinophils in jejunum, prominent anaphylactic symptoms, and eruptive histopathological changes give indication towards red kidney beans allergenicity. IgE immunoblotting detected five protein components with molecular weights of approximately 170, 100, 43, 34 and 20 kDa. Red kidney bean proteins showed cross reactivity with peanut, soybean, chickpea and black gram. Finally, this work demonstrated that red kidney beans may induce allergic response in mice similar to human subjects, with identification of five clinically relevant allergenic protein components.     

Impressed Current Cathodic Protection of Low Carbon Steel in Conjunction with Conducting Polyaniline based Paint Coating

Protection of Metals and Physical Chemistry of Surfaces - Epoxy, Fusion bonded epoxy and conducting polyaniline based paints were applied on low carbon steel sample. Conducting polyaniline and...