Congestion, ramp metering and tolls

The cell transmission model of a freeway is used to compare four congestion-reducing schemes: (R) ramp control only; (T) one lane is tolled and ramps are uncontrolled; (B) bottlenecks are tolled and ramps are uncontrolled; and (RB) ramps are controlled and bottlenecks are tolled. In the base case, ramps are uncontrolled and there are no tolls. It is found that (T) is inefficient and may leave all travellers worse off; (R), (B) and (RB) can achieve efficient freeway use; (B) can eliminate queues, but has adverse spatial and equity side effects; (RB) minimizes these side effects. (RB) is likely to be least costly to implement and maintain.     

Thickness dependent structural, electronic, and optical properties of Ge nanostructures

In the present paper, we have investigated structural, optical as well as electronic properties of electron beam evaporated Ge thin films having layer thicknesses ranging from ultra-thin (5 nm) to thick (200 nm). The Raman spectra show that all peaks are shifted towards lower wave number as compared to their bulk counterparts and are considered as a signature of nanostructure formation and quantum confinement effect. The Raman line exhibits transformation from nanocrystalline to microcrystalline phase with a reduction in blue shift of peak position with increase in Ge film thickness (>5 nm). Similarly, the optical absorption spectra corresponding to these films also show reduction in blue shift effect, although Ge 5 nm film shows the absorption behaviour quite different from higher thickness films. The corresponding band gap values obtained from absorption measurements are much larger than bulk Ge and are mainly attributed to the effect of quantum confinement as expected for small size particles calculated from GIXRD patterns. AFM data in each case are correlated and discussed with structural as well as optical results to support the effect of growth morphology on the above-mentioned observations. The results are further supported by photoelectron spectroscopy (PES), photoluminescence (PL) and resistivity measurements and are interpreted in terms of crystallinity and quantum confinement effect.     

Energy efficient routing with delay guarantee for sensor networks

The paper presents a routing algorithm that maximizes the lifetime of a sensor network in which all data packets are destined for a single collection node. Lifetime is maximized by adjusting the number of packets traversing each node. The adjustment is carried out by transmitting over alternative routes. The first part of the paper assumes that the worst case delay resulting from energy efficient routing is less than the maximum tolerable value. Ignoring the delay constraint of the network, the routes are selected as the solution to a linear programming (LP) problem in which the objective is to maximize the minimum lifetime of each node. The solution is implemented in a centralized algorithm, and then approximated by an iterative algorithm based on least cost path routing, in which each step is implemented efficiently in a distributed manner. The second part of the paper incorporates delay guarantee into energy efficient routing by constraining the length of the routing paths from each sensor node to the collection node. Simulations reveal that the lifetime of the network increases significantly by optimal routing, and including delay constraint in energy efficient routing improves the network performance since the delay of the network keeps increasing as the delay constraint is relaxed beyond the value at which the optimal lifetime is achieved. Research supported by National Science Foundation under Grant CMS-0408627 and California Department of Transportation. Sinem Coleri Ergen received the BS degree in electrical and electronics engineering from Bilkent University, Ankara, Turkey, in 2000, and the M.S. and Ph.D. degrees in electrical engineering and computer sciences from University of California Berkeley (UCB), in 2002 and 2005. Since January 2006, she has been a postdoctoral researcher in electrical engineering at UCB. Her research interests are in wireless communications and networking with a current focus on energy efficient system design for sensor networks. She is a member of the Sensor Networks for Traffic Monitoring project at UCB. She received Regents Fellowship from University of California Berkeley in 2000. Pravin Varaiya is Nortel Networks Distinguished Professor in the Department of Electrical Engineering and Computer Sciences at the University of California, Berkeley. From 1975 to 1992 he was also Professor of Economics at Berkeley. From 1994 to 1997 he was Director of the California PATH program, a multi-university research program dedicated to the solution of Californias transportation problems. His current research is concerned with communication networks, transportation, and hybrid systems. He has taught at MIT and the Federal University of Rio de Janeiro. Varaiya has held a Guggenheim Fellowship and a Miller Research Professorship. He received an Honorary Doctorate from LInstitut National Polytechnique de Toulouse, and the Field Medal of the IEEE Control Systems Society. He is a Fellow of IEEE and a member of the National Academy of Engineering. He is on the editorial board of several journals, including “Discrete Event Dynamical Systems” and “Transportation Research—C”. He has co-authored three books and more than 250 technical papers. The second edition of “High-Performance Communication Networks” (with Jean Walrand) was published by Morgan-Kaufmann in 2000. “Structure and interpretation of signals and systems" (with Edward Lee) was published by Addison-Wesley in 2003. Varaiya is a member of the Board of Directors of Sensys Networks.     

Optimization of Fenton-biological treatment scheme for the treatment of aqueous dye solutions

Degradation of dyes especially, azo dyes are difficult due to their complex structure and synthetic nature. The main objective of this study was to evaluate the Fenton-biological (aerobic) treatment train for decolorization and mineralization of azo dyes viz. Reactive Black 5 (RB5), Reactive Blue 13 (RB13) and Acid Orange 7 (AO7). The objective of Fenton treatment was only to decolorize the dyes (breakage of -NN-), as it was considered that after breakage of -NN-, the dyes will become amenable to biodegradation and can be further treated in aerobic biological system. Hence studies were carried out to optimize the lower Fenton's doses for decolorization of dyes. The optimum doses for decolorization (>95%) of all the three dyes were found out to be 15 mgL(-1) of Fe(2+) (0.27 mM) and 50 mgL(-1) (1.47 mM) of H(2)O(2) dose at optimum pH 3. Further it was also investigated that at lower doses, the main problem of Fenton process (sludge generation) can also be minimized. Later the mineralization of the dye (removal of aromatic amines) was achieved in the aerobic biological treatment system. Overall reduction of 64, 89 and 75% in the aromatic amines (at 254 nm), 88, 95 and 78% in naphthalene ring associated compounds (near 310 nm) and 49, 89 and 91% reduction in benzene ring associated compounds (near 226 nm) were observed for RB5, RB13 and AO7, respectively. Thus this treatment system seems to be quite effective and economical option for the treatment of recalcitrant compounds like dyes, as the cost in the chemical treatment is considered mainly due to chemicals thus at lower doses the operational cost is saved. Further, as the sludge generation was almost negligible at lower doses, thus the savings in cost of handling and disposal of hazardous sludge also adds to economy of treatment.     

DC magnetization studies in Nb/Fe superconducting multilayers

The behavior of superconducting transition temperature T_C in superconducting/ferromagnetic (S/F) multilayers as a function of different layer thicknesses and for varying magnetic moment μ_B of the F layer atoms is studied. Multilayer structures consist of five bilayers of constant superconducting Nb layer thickness of 400 Å and Fe of 6 and 24 Å each. The analysis of the magnetization data revealed that for t_Fe=6 Å, the Fe layer is non-magnetic. The interpretation of the observed T_C behavior is attributed to the change of the interaction of the cooper pairs with this layer at the onset of ferromagnetism for t_Fe=6 Å. The hysteresis curve recorded under isothermal conditions at 4.5 K for [Nb (400 Å)/Fe (6 Å)]₅ multilayers shows the usual M–H hysteresis behavior which is typical of a hard type-II superconductor exhibiting an irreversibility field H_irr of 3.5 kOe with substantial pinning at lower field. In addition, [Nb(400 Å)/Fe(6 Å)]₅ multilayer displays anomalous behavior in the form of paramagnetic peak in the superconducting state just below the transition temperature T_C=6.25 K.     

Allergenic responses of red kidney bean (Phaseolus vulgaris cv chitra) polypeptides in BALB/c mice recognized by bronchial asthma and allergic rhinitis patients

Allergenicity potential of red kidney beans (Phaseolus vulgaris cv chitra) was assessed and attempts were made to identify the responsible proteins by pepsin digestibility assay and IgE immunoblotting. To evaluate allergenic potential, BALB/c mice were sensitized with red kidney bean proteins and levels of specific immunoglobulin, histamine, mast cell protease-1, cytokines and CCL-2 were measured. To confirm our findings in BALB/c, the studies were also extended to human subjects. Human sera collected from control subjects and allergic patients after skin prick test were used for IgE immunoblotting, measuring the levels of total and specific IgE and determining cross reactivity of red kidney bean with other legumes. Red kidney bean allergenic potential was evident by significant increase in specific IgE, IgG1, histamine, mast cell protease-1 and Th2 cytokine levels in comparison to control. Enhanced level of eosinophils in jejunum, prominent anaphylactic symptoms, and eruptive histopathological changes give indication towards red kidney beans allergenicity. IgE immunoblotting detected five protein components with molecular weights of approximately 170, 100, 43, 34 and 20 kDa. Red kidney bean proteins showed cross reactivity with peanut, soybean, chickpea and black gram. Finally, this work demonstrated that red kidney beans may induce allergic response in mice similar to human subjects, with identification of five clinically relevant allergenic protein components.     

Heterogenized copper catalysts for the amination of arylhalide: Synthesis,characterization and catalytic applications

This research investigated the synthesis, characterization and catalytic activity of heterogenized copper complexes for the selective amination of aryl halides. Amination reactions using homogeneous copper catalyst systems are not generally selective and it is also difficult to recover the catalyst from the homogeneous system for recycling. To overcome these difficulties, our efforts were directed towards the development of cheaper heterogeneous catalyst systems, which can be easily recovered and recycled. Heterogenized analogs of the homogenous Cu complexes were prepared using two methods: (a) encapsulation of copper complexes in zeolite-Y and (b) tethering of copper complexes on various supports like zeolite-Y, silica, charcoal, or clay. The encapsulated and tethered copper catalysts on zeolite-Y were characterized using EPR, Diffused reflectance UV–vis, XRD, IAS, ICPES, SEM, and TEM. The results confirmed that the copper complexes were truly heterogenized in zeolite-Y support. Encapsulated and tethered copper complexes were tested for amination of aryl iodide. The effects of various reaction parameters were examined using tethered Cu(Phen)(PPh₃)Br-PTA-Y catalyst to determine optimum conditions. A recycle study of encapsulated and tethered Cu catalyst was carried out to test their robustness for possible commercial exploitation.