Synthesis, structure and properties of a novel hybrid bimodal network elastomer with inorganic cross-links: The case of silicone–nanocrystalline titania

We describe an innovative concept of synthesizing a novel hybrid bimodal network elastomer with high strength–high ductility combination involving utilization of functionalized nanocrystalline titania as short-chain cross-links between neighboring elastomer chains. This subject is germane both fundamentally and from an application viewpoint. Silicone rubber is selected as the model elastomer. The short-chain cross-links are acrylic acid functionalized nanocrystalline titania that are an integral component of bimodal network structure of the elastomer. To delineate and separate the effects of functionalization from nanoparticle effects, a relative comparison is made between silicone rubber–titania nanocomposite (i.e. containing dispersion of titania as a reinforcement filler) and silicone rubber–titania hybrid network elastomer (i.e. titania as short chain cross-links). An important finding is that the effect of functionalized titania present as short chain cross-links is far more significant than non-functionalized titania present as reinforcement filler, on mechanical behavior. This is presently ascribed to the double bonds introduced to nanocrystalline titania via functionalization with acrylic acid that provide active sites for the cross-linking reaction resulting in inorganic bridging chains. The basic physical mechanisms that govern elastic recovery in hybrid bimodal network elastomer with short chain cross-links of functionalized nanocrystalline inorganic particles are discussed. The hypothesis of the study described here is that the hybrid bimodal network elastomer with short chain cross-links of functionalized nanocrystalline inorganic particles modifies the unimodal long chain network elastomer with consequent increase in modulus and high strength–ductility combination.     

An analysis on decentralized adaptive MAC protocols for cognitive radio networks

The scarcity of bandwidth in the radio spectrum has become more vital since the demand for more and more wireless applications has increased. Most of the spectrum bands have been allocated although many studies have shown that these bands are significantly underutilized most of the time. The problem of unavailability of spectrum and inefficiency in its utilization has been smartly addressed by the cognitive radio (CR) technology which is an opportunistic network that senses the environment, observes the network changes, and then uses knowledge gained from the prior interaction with the network to make intelligent decisions by dynamically adapting their transmission characteristics. In this paper, some of the decentralized adaptive medium access control (MAC) protocols for CR networks have been critically analyzed, and a novel adaptive MAC protocol for CR networks, decentralized non-global MAC (DNG-MAC), has been proposed. The results show the DNG-MAC outperforms other CR-MAC protocols in terms of time and energy efficiency.     

From template to image: reconstructing fingerprints from minutiae points

Most fingerprint-based biometric systems store the minutiae template of a user in the database. It has been traditionally assumed that the minutiae template of a user does not reveal any information about the original fingerprint. In this paper, we challenge this notion and show that three levels of information about the parent fingerprint can be elicited from the minutiae template alone, viz., 1) the orientation field information, 2) the class or type information, and 3) the friction ridge structure. The orientation estimation algorithm determines the direction of local ridges using the evidence of minutiae triplets. The estimated orientation field, along with the given minutiae distribution, is then used to predict the class of the fingerprint. Finally, the ridge structure of the parent fingerprint is generated using streamlines that are based on the estimated orientation field. Line integral convolution is used to impart texture to the ensuing ridges, resulting in a ridge map resembling the parent fingerprint. The salient feature of this noniterative method to generate ridges is its ability to preserve the minutiae at specified locations in the reconstructed ridge map. Experiments using a commercial fingerprint matcher suggest that the reconstructed ridge structure bears close resemblance to the parent fingerprint     

Novel Systemic Treatment Modalities Including Immunotherapy and Molecular Targeted Therapy for Recurrent and Metastatic Head and Neck Squamous Cell Carcinoma

Head and neck squamous cell carcinomas (HNSCCs) are the sixth most common cancers worldwide. More than half of patients with HNSCC eventually experience disease recurrence and/or metastasis, which can threaten their long-term survival. HNSCCs located in the oral cavity and larynx are usually associated with tobacco and/or alcohol use, whereas human papillomavirus (HPV) infection, particularly HPV16 infection, is increasingly recognized as a cause of oropharyngeal HNSCC. Despite clinical, histologic, and molecular differences between HPV-positive and HPV-negative HNSCCs, current treatment approaches are the same. For recurrent disease, these strategies include chemotherapy, immunotherapy with PD-1-inhibitors, or a monoclonal antibody, cetuximab, that targets epidermal growth factor; these therapies can be administered either as single agents or in combination. However, these treatment strategies carry a high risk of toxic side effects; therefore, more effective and less toxic treatments are needed. The landscape of HNSCC therapy is changing significantly; numerous clinical trials are underway to test novel therapeutic options like adaptive cellular therapy, antibody-drug conjugates, new targeted therapy agents, novel immunotherapy combinations, and therapeutic vaccines. This review helps in understanding the various developments in HNSCC therapy and sheds light on the path ahead in terms of further research in this field.     

Characterizing cerebral oxygen metabolism employing oxygen-17 MRI/MRS at high fields

This article provides a comprehensive overview of oxygen (¹⁷O) magnetic resonance spectroscopy and imaging, including the advantages and challenges offered by the different methods developed thus far. The physiological role and relevance of oxygen, and its participation in aerobic metabolism, are addressed to emphasize the importance of the investigations and the efforts related to these developments. Furthermore, a number of methods employed in the determination of the cerebral metabolic rate of oxygen in neural cells will be presented, focusing primarily on methodologies enabling absolute quantification.     

On Structural,Optical, and Electrical Properties of Chromium Oxide Cr2O3 Thin Film for Applications

Protection of Metals and Physical Chemistry of Surfaces - Chromium oxide thin films were grown on Al2O3 substrates by ablating a pure Cr2O3 target using a KrF excimer laser. The energy density on...     

Highly luminescent film functionalized with CdTe quantum dots by layer‐by‐layer assembly

Robust and facile strategies are required to fabricate film with high luminescence for application in the fields of biomaterials. In this study, the luminescent electrospinning cellulose fibrous mats were decorated with CdTe quantum dots (QDs) and poly(diallyl dimethyl ammonium chloride) (PDDA) using layer by layer (LBL). The characterizations of the LBL films coated mats were executed by X‐ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscopy, fluorescent spectroscopy, X‐ray diffraction, thermal gravimetric analysis, and differential scanning calorimetry. The luminescent intensities were linearly increased with adding the amount of deposited bilayers. The green fabricated (QDs/PDDA)_n coated mat through physical interactions is a promising luminescent material. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41893.     

Aspects of varying crosslinker and catalyst concentrations on tear strength of silicone polymer networks: Comparison of tear strengths using samples of different geometries

Crosslinker and catalyst concentrations have been varied to prepare different hydroxyfunctional poly(dimethylsiloxane) (HOPDMS) polymer network compositions. The tear strengths of these silicone polymer networks have been measured using different geometries, as trouser, crescent, and Graves (angled) specimens. It has been observed that the results of tear strength of Graves and crescent‐shaped specimens do not show a constant ratio with the concentration of crosslinker used for curing of HOPDMS networks. Instead, it has been observed and reported for the first time that the tear strengths of Graves and crescent‐shaped samples show a crossover at about 1.2% crosslinker. The observation of this crossover pattern for different compositions of silicone networks show that it is difficult to compare the results of the tear test of the same polymer performed on samples of different geometries with one another. The crossover pattern of the tear energy results for the test specimens of two different geometries has been explained in the light of essential work facture theory based on the geometry of the testing sample, crosslinking, and testing that alters the distribution of force over the width of the specimen. It was shown that the change in composition of the HOPDMS networks changes the order of ranking of Graves and crescent tear tests. With varying catalyst concentration in the silicone network composition, the tear property differences between the Graves and crescent‐shaped specimens are not significant. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43115.