Use of colloidal ruthenium particles in the electrochemical reduction of benzene by solvated electrons

Ruthenium colloidal particles prepared by the decomposition of a ruthenium acid sulfite complex increased the electrochemical reduction of benzene from 45% to 60% at room temperature and 10 psig of hydrogen. The reduction was carried out in a 21 mole % ethanol - 79 mole % hexamethylphosporamide. The significant increase in the percent of benzene reduced was accompanied by an apparent current efficiency of 98%. Comparison with analogous experiments employing colloidal platinum particles indicates that the above increase in benzene reduction can be attributed to direct catalytic hydrogenation by the ruthenium.     

Relationship between structure parameters and chemical properties in some MPS3 layered phases

Cationic thermal motions in the MPS₃ have been related to substitution abilities in this layer family. They have also been correlated to the crystal field stabilization energy. These considerations explain why some MPS₃ materials may or may not undergo a low temperature substitution intercalation reaction. From interatomic distances comparisons, the bond between (PS₃) groups in the anionic (P₂S₆)^4? octahedra, is found to be easily stretched upon cation substitution. Cationic radii follows the expected variation according to their high spin configuration in octahedral sulfur environment.     

Olfactory discrimination of individual littermates in rats (Rattus norvegicus).

Tested the ability of 4 adult male Sprague-Dawley rats to use odors in discrimination among littermates living as a group. Ss were trained in a Y-maze to discriminate the presence of a littermate from its absence. Results from transfer of training in 3 subsequent testing periods indicated that the animals were capable of distinguishing among individuals when relatedness and familiarity were held constant, that this ability was not due to training, and that performance was based solely on odor cues. Results suggest that laboratory rats exhibit odor sensitivities conmensurate with very complex social processes. (17 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Quantitative determination of aflatoxin B1 in chick liver

A method for the rapid and quantitative determination of aflatoxin B1 from small quantities of liver, around 1-2 g, is described. The extraction procedure involves acidification to pH 2 of the aqueous liver homogenates, extraction with chloroform: acetone and HPLC-fluorimetric detection after derivatization with trifluoroacetic acid. Quantitative recovery of aflatoxin B1 from chick liver was achieved and detection at levels of 0.2-1 ppb was proved feasible. The aflatoxin B1 concentration in chick liver after oral administration is also shown.     

Continuous-wave lasing of single-mode metamorphic quantum dot lasers for the 1.5-μm spectral region

Lasers based on InAs/InGaAs quantum dots grown on metamorphic (In,Ga,Al)As layers deposited by MBE on GaAs substrates exhibited emission near 1.5 μm with a differential quantum efficiency of about 50%. The narrow-stripe lasers operate in a single transverse mode and withstand continuous current density above 20 kA cm^?2 without significant degradation. A maximum continuous-wave output power of 220 mW is obtained. Neither current nor beam filamentation was observed up to the highest pumping levels.     

Processes of the Collision Interaction between Ceramic Particles Being Crushed in a Circulation Pneumatic Crusher

A new circulation pneumatic crusher capable of producing submicron powders of refractory materials is presented. A mathematical model is constructed for the dynamic breaking of ceramic macroparticles. This model allows the basic laws of shock-wave crushing in the circulation pneumatic apparatus to be analyzed.__________Translated from Teoreticheskie Osnovy Khimicheskoi Tekhnologii, Vol. 39, No. 3, 2005, pp. 327–333.Original Russian Text Copyright © 2005 by Belov, Biryukov, Roslyak, Yugov, Afanas’ev.     

The focusing magnetic resonance system with a new type of supersonic atomic beam source

A focusing magnetic resonance system (MRS) with a new type of supersonic atomic - and molecular - beam source is suggested. The beam sources used in the MRS are discussed and the main operation principles of the suggested supersonic beam source as well as the advantages of this type of source over the rest are shown. An optimization procedure for the magnetic resonance system with the effect of the finite source size taken into account is considered. Numerical results are given and analyzed. The MRS with the new type of beam source possesses higher transmission with low background and is simpler and cheeper in construction as compared to the conventional systems.     

A new method for the electro-optical measuring of fast high voltage pulses

This report describes a new method for measuring fast high voltage electric pulses based on one particular application of the Kerr effect. This work was carried out in order to further the development of optical particle detectors. At the present time with our method, the minimum risetime of the measured pulse reaches the nanosecond domain while the maximum voltage is limited only by the physical dimension of the electro-optical transducer.The measuring principle chosen requires a new calibration method in order to reconstruct the observed signal.The use of nitrobenzol as the active liquid allows the continuous modification of the cell sensitivity over a ratio of 1 to 3 without changing the geometry of the cell.     

Crystallization of amorphous Ni60 Nb40−x Cr x alloys

Crystallization behaviour of amorphous Ni₆₀ Nb_40-x Cr _x (x = 0, 5, 10 and 13 at%) alloys was studied by differential Scanning calorimetry and X-ray diffraction measurements. It is shown that the addition of chromium reduces the crystallization temperature, stages of crystallization and activation energies associated with the crystallization sages of the Ni₆₀Nb₄₀ glass. Crystallization of the Ni₆₀Nb₄₀ glass occurred in three stages; in the initial stage a metastable M-phase formed in the amorphous matrix as reported earlier [1] . However, contrary to earlier observation [1], M -phase was not very stable and transformed together with some amorphous phase to the equilibrium Ni₃Nb phase in the second stage of crystallization. In the third stage, the remaining amorphous matrix transformed to the equilibrium NiNb phase. On addition of chromium the formation/stability of the M-phase was found to be suppressed and equilibrium NbCr₂ phase precipitated preferentially in the first stage. The second stage, corresponding to the formation of Ni₃Nb phase, remained almost unaltered. The third stage corresponding to the crystallization of NiNb phase disappeared completely at 13 at% Cr. In the fully crystallized samples the proportion of the NiNb phase decreased and that of NbCr₂ phase increased continuously with chromium concentration.     

Transparent monolithic zirconia gels: effects of acetylacetone content on gelation

Transparent yttria-stabilized zirconia monolithic gels were synthesized under controlled conditions for hydrolysis and chemical polymerization. The influence of acetylacetone on the previous chemical reactions was explored, and a plausible explanation was proposed concerning the outstanding role of this additive during the gelation process. Small-angle X-ray scattering was used to estimate the size of the polymeric species and to investigate the influence of acetylacetone on the structure of the gels prepared.