Axisymmetric fracture mechanics analysis by the boundary integral equation method

The boundary integral equation (BIE) method of numerical stress analysis is shown to be a powerful technique for solving axisymmetric fracture mechanics problems of the types encountered in practice in pipes, tubes and pressure vessels. Comparisons with established analytical and finite element solutions for problems involving circumferential and penny-shaped cracks in round bars, spheres and hollow cylinders show that accurate values of stress intensity factors at the tips of cracks can be obtained by this method. The main advantage of the technique over the finite element method is the much reduced amount of labour required to prepare the mesh data, since in the BIE approach only the boundary of an axisymmetric component needs to be discretised into simple and relatively coarse line elements.     

The influence of preparation conditions on the electrochemical behaviour of CuO in a Li/CuO cell

A dozen CuO samples prepared under various conditions and from different starting materials were evaluated as cathode materials for a primary Li/CuO cell. The “thin electrode” method was used for rapid evaluation of the samples. Both coulombic efficiency and discharge voltage depend considerably on the method of synthesis. No correlation was found between the specific surface area and the resistivity of the samples on the one hand and the cathode performance on the other. Best results were obtained from CuO prepared by the oxidation of Cu₂O under controlled temperature and time of oxidation.     

Spectrophotometric determination of some antioxidants with potassium permanganate and metol

New spectrophotometric methods for the assay of some antioxidants have been developed using potassium permanganate and metol (p-N-methyl amino phenol). Metol is oxidised at pH 3.0 with potassium permanganate and coupled with antioxidants to give λ_max at 560 nm for propyl gallate and gallic acid and 510nm for butylated hydroxy anisole. The method is simple, sensitive, reproducible and accurate within ±1% and applicable to the assay of antioxidants (gallic acid, propyl gallate and butylated hydroxy anisole) in oils and fats.     

Inhibition by chelating agents of the formation of active extracellular proteinase by Pseudomonas fluorescens 32A

The effect of chelating agents on extracellular proteinase production by Pseudomonas fluorescens 32A was examined. Increasing concentrations of orthophosphate slightly stimulated growth while inhibiting proteinase synthesis. Fifty per cent inhibition was found at 35 and 28 mM-orthophosphate at 5 and 20 degrees C respectively. Extracellular protein concentration was reduced by 30% when cells were grown with 100 mM-orthophosphate. Polyacrylamide gel electrophoresis of the cell-free supernatants suggested that reduced enzyme synthesis had taken place as evidenced by the decrease in staining intensity of the protein band corresponding to the proteinase. Other phosphate compounds could replace orthophosphate as an inhibitor. Extent of inhibition was related to chain length; polyphosphates with 4-6 or 13-18 phosphorus atoms were the most effective inhibitors. EDTA (0.5 mM) completely inhibited proteinase synthesis. This inhibition could be partly reversed by Ca2+ and, to a lesser extent, Mn2+. Proteinase production at 5 degrees C in skim milk was completely inhibited by phosphate glass (P13-P18). Control experiments showed that loss of activity with chelators was not due to inhibition of preformed enzyme. The results suggest a possible role for polyphosphates in controlling proteinase production in stored milk.     

The use of doped polyaniline as an electrode in the galvanic anodic protection of ferrous metals in industrial acid solutions

In order to investigate the galvanic anodic protection (GAP) of ferrous metals (such as 410, 304 and 316 stainless steels) in acid solutions by doped polyaniline (PANi), separate doped PANi powder-pressed electrodes with different surface areas (the area ratio of the PANi electrode to stainless steel is between 1:1 and 1:2) have been prepared. These were coupled with ferrous metal in the following solutions: 5 M sulphuric acid, 5 M phosphoric acid and industrial phosphoric acid (containing 5 M phosphoric acid and 0.05% chloride ion) to construct a galvanic cell, in which PANi is cathode while ferrous metal is anode. The results indicate that a PANi electrode with sufficient area can provide corrosion protection to stainless steel in these acidic solutions. A pilot scale coupling experiment was carried out. The results indicate that PANi is a promising material as an electrode for the anodic protection of ferrous metals in acidic solutions in industrial situations.     

On constructivity of involutive divisions

In the paper, the problem of existence of the minimal involutive monomial basis is considered for different involutive divisions. The existence criterion is obtained in the form of a constructivity property. In the paper, new examples of constructive and nonconstructive (> σ)-divisions are presented.     

Aggregation of Induction Motor Loads for Transient Stability Studies

This study investigates the dynamic representation of a group of induction motors by one or more equivalent motors. The unknown parameters of the equivalent are estimated through a weighted-least-squares procedure. Verification of simulated results with experimental ones suggests that a fifth order dynamic model of the aggregate with a ninth order parameter model is appropriate. The least squares technique was found to provide good convergence characteristics subject to satisfaction of the following conditions good initial estimate of the parameters, proper selection of acceleration factors and homogenity of the motor group.     

Optical performance of a composite parabolic trough

The effects of receiver misplacement and the trough pointing towards the sun on the concentration characteristics of a composite parabolic trough are discussed. Results from some numerical calculations are presented graphically and discussed.     

Effects of free convection and mass transfer on the flow past an impulsively moving infinite vertical circular cylinder

The effects of free convection and mass transfer are taken into account for the Stokes' problem of the flow near an impulsively moving infinite vertical circular cylinder. Expressions of the velocity, temperature, concentration and skin friction of the fluid in closed form are obtained by the Laplace transform technique. The results based on various values of the parameters Gr (Grashof number), Gm (modified Grashof number), Sc (Schmidt number) and Pr (Prandtl number) are given in graphical form. It will be seen that there is a rise in the velocity due to the presence of a foreign mass. But higher Sc yields the lower velocity and skin friction. As the radius of the circular cylinder approaches to infinite, the results presented in this paper agree with those of V.M. Soundalgekar's and C.K. Chen's etc. for the flow past an impulsively moving infinite vertical plate.