Study on the electrical conductivity and morphology of porous polypyrrole layers prepared electrochemically in the presence of pyridinium chlorochromate

The electrical conductivity and morphology of thick (up to 3 mm) porous polypyrrole (PPy) layers produced electrochemically from pyrrole in acetonitrile (ACN) solutions have been studied. The electrical conductivity of pressed porous layers ranges from 1 to 10 Scm^–1, which is about one order of magnitude less than that in films which were prepared under similar conditions but without PnClCr. Analysis of the temperature dependence of conductivity has confirmed the major role of hopping in relation to tunnelling in charge transport inside the PPy layers even at lower temperatures. Scanning electron microscopy (SEM) showed a globular structure, which is different from the usual cauliflower-like structure of PPy films prepared without any oxidizing agent. Globular particles of about 1–3 m diameter have been found under a thin smooth crust on the electrode side of the sample. Globular particles form linked chain-like or larger round formations poorly filling the space. Closely packed fibrils of about 20 nm diameter and over 100 nm in length were found inside the aggregates.     

The δ-Al2O3 (Saffil) fibre degradation during infiltration with MgLi alloy

The chemical and phase transformations of -Al₂O₃ (Saffil) fibres during their infiltration with Mg-8 wt% Li were studied by scanning and transmission electron microscopy, Auger electron spectroscopy, secondary ion mass spectrometry and X-ray diffraction methods. The infiltration experiments were carried out in autoclave under argon pressure at temperatures of 883–908 K and contact times of 4–30 s as well as at 918 K/420 s. During the course of infiltration, lithium penetrates the Saffil fibres and this process is accompanied by the gradual transformation of the tetragonal -Al₂O₃ lattice towards the cubic spinel LiAl₅O₈ compound, where part of the Li⁺ ions is probably substituted by Mg²⁺ No remarkable interfacial zone at the fibre/matrix interface was observed; however, the Saffil fibres became brittle which had been manifested by the occurrence of fragmentation on the metallographically treated fibre cross-sections. The tensile strength (maximum 220 MPa) of the corresponding metal matrix composite clearly decreased with increased infiltration time.     

Comparison of some components of pigs kept in natural (free-range) and large-scale conditions

A new pig genotype of Hungarian Large White (75%) × Mangalica (pig with curly bristles, 25%) was used in the experiments. The experimental group was kept in a farming system under strictly natural circumstances until a body weight of 120 kg was attained. Neither antibiotics nor yield-increasing hormones were given to this group. The control group was kept in the usual large-scale farming conditions until body weight of 120 kg was attained. In most cases, protein, zinc, and copper levels and, in some cases, iron levels were significantly higher in some major cuts (neck-end (Boston-butt), loin, ham) of the 'free-range' pigs (n = 12) in comparison with the control animals kept in large-scale farming conditions. There was, on average, 15% less cholesterol in the muscles and 30% less cholesterol in the liver and less linoleic acid in all tissues of 'free-range' pigs than in the control group. There was less fat, but the amount of thiamin and riboflavin in the liver of the naturally kept pigs was twice that in the controls. In respect of TBA-reactive compounds, there were no significant differences between the two groups, but superoxide dismutase (SOD) showed significantly higher activities in all cuts from pigs kept in a large-scale farming system. This may be the effect of a higher level of linoleic acid in the fat.     

Higher incidence of Gastrospirillum sp. in swine with gastric ulcer of the pars oesophagea

Gastric ulcer in swine is characterized by an area of acid-peptic digestion, occurs usually in the pars oesophagea of the stomach, and has unknown etiopathogenesis. The present work was carried out to investigate the prevalence of the newly described spiral-shaped microorganism Gastrospirillum sp. ("Gastrospirillum suis") in stomachs of abattoir pigs with and without gastric ulcer. Stomachs were removed from 32 consecutive pigs presenting apparently normal mucosa and from 32 additional consecutive pigs presenting frank, chronic gastric ulcer of the pars oesophagea. Fragments of antral, oxyntic, cardiac and pars oesophagea regions were taken from each stomach and processed for histology and for identification of Gastrospirillum sp. in tissue sections. The microorganisms were identified mainly in the mucous layer and in gastric foveolas of the antral and oxyntic mucosa. Forty pigs (62.5%) were positive for Gastrospirillum sp.; among them, 27 (67.5%) had gastric ulcer, and 13 (32.5%) had no ulcer. Twenty-four pigs (37.5%) were negative for Gastrospirillum sp.; among them, five (20.8%) presented with gastric ulcer, and 19 (79.2%) had no ulcer. There was a significant difference between pigs with and without gastric ulcer in regard to the presence of Gastrospirillum sp. (P < 0.01). The spiral-shaped microorganism Gastrospirillum sp. that inhabits the stomach of pigs should be considered a possible factor connected with the etiopathogenesis of swine gastric ulcer.     

Reaching the Fundamental Limitation in CO2 Reduction to CO with Single Atom Catalysts

The electrochemical CO₂ reduction reaction (CO₂RR) to value-added chemicals with renewable electricity is a promising method to decarbonize parts of the chemical industry. Recently, single metal atoms in nitrogen-doped carbon (MNC) have emerged as potential electrocatalysts for CO₂RR to CO with high activity and faradaic efficiency, although the reaction limitation for CO₂RR to CO is unclear. To understand the comparison of intrinsic activity of different MNCs, two catalysts are synthesized through a decoupled two-step synthesis approach of high temperature pyrolysis and low temperature metalation (Fe or Ni). The highly meso-porous structure results in the highest reported electrochemical active site utilization based on in situ nitrite stripping; up to 59±6% for NiNC. Ex situ X-ray absorption spectroscopy (XAS) confirms the penta-coordinated nature of the active sites. The catalysts are amongst the most active in the literature for CO₂ reduction to CO. The density functional theory calculations (DFT) show that their binding to the reaction intermediates approximates to that of Au surfaces. However, it is found that the turnover frequencies (TOFs) of the most active catalysts for CO evolution converge, suggesting a fundamental ceiling to the catalytic rates.     

Pseudo-T2 mapping for normalization of T2-weighted prostate MRI

Magnetic Resonance Materials in Physics, Biology and Medicine - Signal intensity normalization is necessary to reduce heterogeneity in T2-weighted (T2W) magnetic resonance imaging (MRI) for...     

Electronic simulation and microcontroller real implementation of an autonomous chaotic and hyperchaotic system made of a Colpitts-Josephson junction like circuit

Most of the simple Josephson junction (JJ) based circuits with chaotic behavior found in the literature are nonautonomous. Hyperchaotic JJ-based circuits are often either driven by an external force or result from coupling chaotic circuits. An autonomous simple circuit based on Josephson junction active element (JJ), with exactly three physical energy storage tanks, is proposed and analyzed in this paper. This Colpitts-like CLC circuit, though operating at low frequencies, can generate hyperchaotic signals when its nonlinear element is a resistive–capacitive–inductance shunted junction (LRCLSJ) model. Two equilibrium points are found, and their stability analysis is investigated. The proposed circuit displays Hopf bifurcation, periodic oscillations, chaotic and hyperchaotic attractors. The electronic implementation of the proposed circuit using OrCAD-PSpice software is presented to confront the numerical simulations results. A good qualitative agreement is revealed by comparing the analog and numerical simulations results. At last, the microcontroller real implementation is presented using Arduino UNO board. The results obtained are in good agreement with the numerical simulation results.

     

Workload assignment for global real-time scheduling on unrelated clustered platforms

Real-Time Systems - Heterogeneous MPSoCs are being used more and more, from cellphones to critical embedded systems. Most of those systems offer heterogeneous sets of identical cores. In this...     

Hierarchical classification of data streams: a systematic literature review

The classification task usually works with flat and batch learners, assuming problems as stationary and without relations between class labels. Nevertheless, several real-world problems do not assume these premises, i.e., data have labels organized hierarchically and are made available in streaming fashion, meaning that their behavior can drift over time. Existing studies on hierarchical classification do not consider data streams as input of their process, and thus, data is assumed as stationary and handled through batch learners. The same can be said about works on streaming data, as the hierarchical classification is overlooked. Studies concerning each area individually are promising, yet, do not tackle their intersection. This study analyzes the main characteristics of the state-of-the-art works on hierarchical classification for streaming data concerning five aspects: (i) problems tackled, (ii) datasets, (iii) algorithms, (iv) evaluation metrics, and (v) research gaps in the area. We performed a systematic literature review of primary studies and retrieved 3,722 papers, of which 42 were identified as relevant and used to answer the aforementioned research questions. We found that the problems handled by hierarchical classification of data streams include mainly classification of images, human activities, texts, and audio; the datasets are mostly created or synthetic data; the algorithms and evaluation metrics are well-known techniques or based on those; and research gaps are related to dynamic context, data complexity, and computational resources constraints. We also provide implications for future research and experiments to consider common characteristics shared amongst hierarchical classification and data stream classification.