Solidification behavior of Al-Si-Fe alloys and phase transformation of metastable intermetallic compound by heat treatment

Solidification behavior of Al-20 wt% Si-8 wt% Fe and Al-30 wt% Si-5 wt% Fe alloys during cooling with a cooling rate of 10 K/min has been studied using optical microscopy, X-ray diffractometry, differential thermal analysis, scanning electron microscopy and energy dispersive X-ray spectroscopy. In Al-20Si-8Fe alloy, metastable -Al₄FeSi₂ phase with tetragonal structure formed first from melt, followed by primary Si precipitation and then remaining liquid solidified finally into ternary eutectic of -Al, Si and phases. However, in Al-30Si-5Fe alloy, primary Si formed first, followed by the phase precipitation and then eutectic solidification. During isothermal heat treatment of as-solidified alloys, phase transformation from the phase to equilibrium phase began at the interface between phase and -Al matrix and progressed toward the inside of phase with co-precipitation of Si particles due to the difference in composition between -Al₄FeSi₂ and -Al₅FeSi phases.     

Slurry sampling in serum blood for mercury determination by CV-AFS

The heavy metal mercury (Hg) is a neurotoxin known to have a serious health impact even at relatively low concentrations. A slurry method was developed for the sensitive and precise determination of mercury in human serum blood samples by cold vapor generation coupled to atomic fluorescence spectrometry (CV-AFS). All variables related to the slurry formation were studied. The optimal hydrochloric concentration and tin(II) chloride concentration for CV generation were evaluated. Calibration within the range 0.1-10 microg L(-1) Hg was performed with the standard addition method, and compared with an external calibration. Additionally, the reliability of the results obtained was evaluated by analyzing mercury in the same samples, but submitted to microwave-assisted digestion method. The limit of detection was calculated as 25 ng L(-1) and the relative standard deviation was 3.9% at levels around of 0.4 microg L(-1)Hg.     

Solid biofuels in Mexico: a sustainable alternative to satisfy the increasing demand for heat and power

Bioenergy is the largest renewable energy source in Mexico with an estimated 4–9% of total current energy demand. There are large uncertainties and contrasting estimates regarding its current extent and end-uses, particularly with traditional uses. However, a large potential exists to improve the efficiency of existing uses and, at the same time, to diversify the use of SBF in the industrial and power sectors. This paper aims at: providing the first updated and comprehensive estimate of current SBF demand in Mexico including traditional and modern uses; providing a consistent estimate of actual SBF supply potential; estimating the total potential substitution of fossil fuels that could be achieved by SBF considering an integrated “modernization scenario”; and finally describing the main barriers limiting SBF to fully triggering its potential. Results show that current SBF consumption reached 481 PJ/yr in 2015; SBF supply potential reaches 3622 PJ/yr, out of which 883 PJ/yr could be used to substitute up to 29% of current demand of FF, mitigating 66 MtCO_2e/yr of greenhouse gas (GHG) emissions, or near 88 MtCO_2e/yr if mitigation from traditional uses is added.     

Small size, low power consumption, low phase noise MMIC VCO usingoff-chip packaging resonator for mobile communication

An MMIC VCO with a new type of frequency tunable multilayer ceramic resonator for mobile communication is designed and fabricated for the 2 GHz band. The VCO presents a dramatic size reduction and a C/N performance of -100 dBc/Hz at 100 kHz. Its RF output power is about -3 dBm, the frequency tuning range is 110 MHz, and current consumption is 7mA of DC     

Nanostructured copper/porous silicon hybrid systems as efficient sound-emitting devices

In the present work, the photo-acoustic emission from nanostructured copper/porous silicon hybrid systems was studied. Copper nanoparticles were grown by photo-assisted electroless deposition on crystalline silicon and nanostructured porous silicon (nanoPS). Both the optical and photo-acoustic responses from these systems were determined. The experimental results show a remarkable increase in the photo-acoustic intensity when copper nanoparticles are incorporated to the porous structure. The results thus suggest that the Cu/nanoPS hybrid systems are suitable candidates for several applications in the field of thermoplasmonics, including the development of sound-emitting devices of great efficiency.     

Modeling Lightning Impact Thermo-Mechanical Damage on Composite Materials

Carbon fiber-reinforced polymers, used in primary structures for aircraft due to an excellent strength-to-weight ratio when compared with conventional aluminium alloy counterparts, may nowadays be considered as mature structural materials. Their use has been extended in recent decades, with several aircraft manufacturers delivering fuselages entirely manufactured with carbon composites and using advanced processing technologies. However, one of the main drawbacks of using such composites entails their poor electrical conductivity when compared with aluminium alloy competitors that leads to lightning strikes being considered a significant threat during the service life of the aircraft. Traditionally, this problem was overcome with the use of a protective copper/bronze mesh that added additional weight and reduced the effectiveness of use of the material. Moreover, this traditional sizing method is based on vast experimental campaigns carried out by subjecting composite panels to simulated lightning strike events. While this method has proven its validity, and is necessary for certification of the structure, it may be optimized with the aid provided by physically based numerical models. This paper presents a model based on the finite element method that includes the sources of damage observed in a lightning strike, such as thermal damage caused by Joule overheating and electromagnetic/acoustic pressures induced by the arc around the attachment points. The results of the model are compared with lightning strike experiments carried out in a carbon woven composite.     

A comparative assessment of biofiltration and activated sludge diffusion for odour abatement

The deodorization performance of a biofilter and an activated sludge diffusion (AS) system was comparatively evaluated in terms of removal efficiency (RE) and process stability at empty bed residence times (EBRT) ranging from 94 to 32s. Both bioreactors were fed with a synthetic odorous emission containing H(2)S, butanone and toluene at 23.6-43.3, 4.3-6.3 and 0.4-0.6 mg m(-3), respectively. While the outlet H(2)S concentration was always lower than 1.4 mg m(-3), the REs for butanone and toluene remained higher than 95% in both bioreactors regardless of the EBRT. The continuous supply of wastewater in the AS unit did not affect removal and appeared to be a requirement for efficient pollutant abatement. Despite the narrow carbon source spectrum treated, the AS system maintained a large bacterial diversity over time. Therefore, the results obtained confirmed the potential of AS systems as a robust and efficient biotechnology for odour treatment in WWTPs.     

Recovery of struvite from animal wastewater and its nutrient leaching loss in soil

Contaminants in swine wastewater were recovered in the form of struvite, a crystal of magnesium ammonium phosphate (MAP), using a newly designed process, and the leaching loss of MAP in soil was examined. The continuous flow process was operated under optimal conditions: 1.0 molar ratio of magnesium (Mg) addition with respect to orthophosphate (OP) and an aeration rate of 0.73 L/L min. Five treatments were performed with three replications for soil pH and nutrient leaching loss tests. It was found that 93% of the OP in the swine wastewater was crystallized, and the MAP crystal formation was verified by X-ray diffraction (XRD) and scanning electron microscope (SEM) analyses. The analyses revealed that the pattern of pH change and N leaching losses for MAP-treated soil were remarkably different from those for fused super phosphate (FSP)-urea-treated soils. The pH levels for the control and FSP-urea-treated soils after a five-week experiment were unchanged or slightly decreased, whereas an increase in pH was observed in the MAP-treated soils. Leaching loss of N was higher in FSP-urea treatments, with MAP treatments showing N losses of only 1.93 and 2.05%, respectively, while FSP-urea treatments showed N losses of 7.82 and 6.47%, respectively, during the same period. Phosphate (P) leaching was very slow in both MAP- and FSP-treated groups.