Dielectric characterization and conduction modelling of a water tree degraded LDPE

Distribution of electric energy by extruded polymer insulated cables continues to be a subject of outstanding relevance in modern industrialized countries all over the world. Dielectric characterization, conduction modelling and finally diagnostics of polymeric insulations are necessary steps towards the development of reliable and less expensive robust technologies of electric power distribution. This paper is devoted to a detailed experimental/theoretical study of the conductive properties of LDPE affected by different levels of degradation by water trees. Water tree layers of different lengths were grown in accelerated conditions and were characterized by water tree kinetics, time-dependent permittivity and polarization current. The polarization current was found to obey a Curie-von Schweidler law whose parameters were used to characterize the effect of ageing time. A new conduction model that takes into account dipole interactions and was obtained from a two-wells Debye model is presented which allows us to give an interpretation of the effect of ageing. This laboratory study was intended to improve the characterization of service power cables aged by water trees     

Secure Sharing of Tuple Spaces in Ad Hoc Settings

Security is emerging as a growing concern throughout the distributed computing community. Typical solutions entail specialized infrastructure support for authentication, encryption and access control. Mobile applications executing over ad hoc wireless networks present designers with a rather distinct set of security requirements. A totally open setting and limited resources call for lightweight and highly decentralized security solutions. In this paper we propose an approach that relies on extending an existing coordination middleware for mobility (Lime). The need to continue to offer a very simple model of coordination that assures rapid software development led to limiting extensions solely to password protected tuple spaces and per tuple access control. Password distribution and security are relegated to the application realm. Host level security is ensured by the middleware design and relies on standard support provided by the Java system. Secure interactions among agents across hosts are accomplished by careful exploitation of the interceptor pattern and the use of standard encryption. The paper explains the design strategy used to add security support in Lime and its implications for the development of mobile applications over ad hoc networks.     

Facile Microwave Assisted Synthesis of Silver Nanostars for Ultrasensitive Detection of Biological Analytes by SERS

We report a very simple, rapid and reproducible method for the fabrication of anisotropic silver nanostars (AgNS) that can be successfully used as highly efficient SERS substrates for different bioanalytes, even in the case of a near-infra-red (NIR) excitation laser. The nanostars have been synthesized using the chemical reduction of Ag⁺ ions by trisodium citrate. This is the first research reporting the synthesis of AgNS using only trisodium citrate as a reducing and stabilizing agent. The key elements of this original synthesis procedure are rapid hydrothermal synthesis of silver nanostars followed by a cooling down procedure by immersion in a water bath. The synthesis was performed in a sealed bottom flask homogenously heated and brought to a boil in a microwave oven. After 60 s, the colloidal solution was cooled down to room temperature by immersion in a water bath at 35 °C. The as-synthesized AgNS were washed by centrifugation and used for SERS analysis of test molecules (methylene blue) as well as biological analytes: pharmaceutical compounds with various Raman cross sections (doxorubicin, atenolol & metoprolol), cell lysates and amino acids (methionine & cysteine). UV-Vis absorption spectroscopy, (Scanning) Transmission Electron Microscopy ((S)TEM) and Atomic Force Microscopy (AFM) have been employed for investigating nanostars’ physical properties.     

The effect of water treeing on the electric field distribution ofXLPE. Consequences for the dielectric strength

This paper describes the influence of water trees on dielectric properties of flat samples cut from a HV crosslinked polyethylene (XLPE) cable insulation. In order to obtain experimental results in a short period of time, we used accelerated aging conditions of voltage and frequency as well as different techniques for producing a multitude of artificial water tree inception points. The average value of the water tree permittivity and a law for the time-dependence of permittivity inside the treed degraded areas were deduced from measurements of capacitance and water tree lengths. On the basis of the experimental knowledge of permittivity and water tree length, we determined with analytical numerical methods, the distribution of the electric field for different shapes of treed regions. Because of the increase in length and permittivity of the water tree, the electric field in front of the degraded area is amplified, which is an important factor of risk leading to the electric breakdown     

Synthesis of probabilistic models for quality-of-service software engineering

An increasingly used method for the engineering of software systems with strict quality-of-service (QoS) requirements involves the synthesis and verification of probabilistic models for many alternative architectures and instantiations of system parameters. Using manual trial-and-error or simple heuristics for this task often produces suboptimal models, while the exhaustive synthesis of all possible models is typically intractable. The EvoChecker search-based software engineering approach presented in our paper addresses these limitations by employing evolutionary algorithms to automate the model synthesis process and to significantly improve its outcome. EvoChecker can be used to synthesise the Pareto-optimal set of probabilistic models associated with the QoS requirements of a system under design, and to support the selection of a suitable system architecture and configuration. EvoChecker can also be used at runtime, to drive the efficient reconfiguration of a self-adaptive software system. We evaluate EvoChecker on several variants of three systems from different application domains, and show its effectiveness and applicability.     

Parameters of TSMG Process for Y1.5Ba2Cu3O x System with CeO2 Addition

The TSMG process of YBCO bulk superconductors with Y_1.5Ba₂Cu₃O _x composition and 1 wt% CeO₂ addition has been studied. It is shown that the window for isothermal growth of single-crystalline sample grown from Sm123 seed is between 988 ^°C and 1003 ^°C. At lower temperatures of this window, Y123 crystals grow with higher growth rate but the quality of crystals is worse due to the formation of steps at the growth front. During an isothermal dwell at the optimized temperature, the growth of Y123 single-crystal stops due to decreasing peritectic temperature with increasing CuO concentration in the melt. Additional slow cooling 1 ^°C/hour from the temperature of isothermal growth leads to epitaxial growth of Y123 crystal over the entire sample. Only very narrow part at the rim of the sample contains CuO phase and blocky Y123 crystals are formed there due to self-nucleation.