Complex‐Shaped Cellulose Composites Made by Wet Densification of 3D Printed Scaffolds

Cellulose is an attractive material resource for the fabrication of sustainable functional products, but its processing into structures with complex architecture and high cellulose content remains challenging. Such limitation has prevented cellulose‐based synthetic materials from reaching the level of structural control and mechanical properties observed in their biological counterparts, such as wood and plant tissues. To address this issue, a simple approach is reported to manufacture complex‐shaped cellulose‐based composites, in which the shaping capabilities of 3D printing technologies are combined with a wet densification process that increases the concentration of cellulose in the final printed material. Densification is achieved by exchanging the liquid of the wet printed material with a poor solvent mixture that induces attractive interactions between cellulose particles. The effect of the solvent mixture on the final cellulose concentration is rationalized using solubility parameters that quantify the attractive interparticle interactions. Using X‐ray diffraction analysis and mechanical tests, 3D printed composites obtained through this process are shown to exhibit highly aligned microstructures and mechanical properties significantly higher than those obtained by earlier additively manufactured cellulose‐based materials. These features enable the fabrication of cellulose‐rich synthetic structures that more closely resemble the exquisite designs found in biological materials grown by plants in nature.     

Concurrent Zero Knowledge, Revisited

We provide a more general and, in our eyes, simpler variant of Prabhakaran, Rosen and Sahai’s (FOCS ’02, pp. 366–375, 2002) analysis of the concurrent zero-knowledge simulation technique of Kilian and Petrank (STOC ’01, pp. 560–569, 2001).     

Interaction of specialized cardiac conduction system with antiarrhythmic drugs: a simulation study

The use of antiarrhythmic drugs is common to treat heart rhythm disorders. Computational modeling and simulation are promising tools that could be used to investigate the effects of specific drugs on cardiac electrophysiology. In this paper, we study the multiscale effects of dofetilide, a drug that blocks IKr, from cellular to organ level paying special attention to its effect on heart structures, in particular the specialized cardiac conduction system (CCS). We include a model of the CCS in a patient-specific anatomical ventricular model and study the drug effects in simulations with and without a CCS. Results confirmed the expected effects of dofetilide at cellular level, increasing the action potential duration, and at organ level, prolonging the QT segment. Notable differences are shown between models with and without the CCS on action potential duration distributions. These techniques show the importance of heart heterogeneity and the global effects of the interaction of drugs with cardiac structures.     

A general architecture in support of interactive, multimedia, location-based mobile applications

The widespread use of cellular telephones and the availability of user-location information are facilitating the development of new personalized, location-based applications. However, as of today, most of these applications are unidirectional and text-based where the user subscribes and the system sends a text message when appropriate. This article describes a modular and general architecture that supports the development of interactive, multimedia, location-based applications, providing an extra level of service to the users. The flexibility of the architecture is demonstrated by presenting the wireless safety security system (Wi-Via) and other potential applications     

CdTe/CdS thin film solar cells grown in substrate configuration

The ability to grow efficient CdTe/CdS solar cells in substrate configuration would not only allow for the use of non‐transparent and flexible substrates but also enable a better control of junction formation. Yet, the problems of barrier formation at the back contact as well as the formation of a p–n junction with reduced recombination losses have to be solved. In this work, CdTe/CdS solar cells in substrate configuration were developed, and the results on different combinations of back contact materials are presented. The Cu content in the electrical back contact was found to be a crucial parameter for the optimal CdCl₂‐treatment procedure. For Cu‐free cells, two activation treatments were applied, whereas Cu‐containing cells were only treated once after the CdTe deposition. A recrystallization behavior of the CdTe layer upon its activation similar to superstrate configuration was found; however, no CdTe–CdS intermixing could be observed when the layers were treated consecutively. Remarkably high V_OC and fill factor of 768 mV and 68.6%, respectively, were achieved using a combination of MoO₃, Te, and Cu as back contact buffer layer resulting in 11.3% conversion efficiency. With a Cu‐free MoO₃/Te buffer material, a V_OC of 733 mV, a fill factor of 62.3%, and an efficiency of 10.0% were obtained. Copyright © 2012 John Wiley & Sons, Ltd.     

Co‐optimization of SnS absorber and Zn(O,S) buffer materials for improved solar cells

Thin‐film solar cells consisting of earth‐abundant and non‐toxic materials were made from pulsed chemical vapor deposition (pulsed‐CVD) of SnS as the p‐type absorber layer and atomic layer deposition (ALD) of Zn(O,S) as the n‐type buffer layer. The effects of deposition temperature and annealing conditions of the SnS absorber layer were studied for solar cells with a structure of Mo/SnS/Zn(O,S)/ZnO/ITO. Solar cells were further optimized by varying the stoichiometry of Zn(O,S) and the annealing conditions of SnS. Post‐deposition annealing in pure hydrogen sulfide improved crystallinity and increased the carrier mobility by one order of magnitude, and a power conversion efficiency up to 2.9% was achieved. Copyright © 2014 John Wiley & Sons, Ltd.     

完成自动校准的CPLD内部振荡器

Altera公司的MAXII CPLD系列采用内部振荡器,它的功耗低于外接振荡器.内部振荡器的精度只有±25%,因此有时限制了它的使用.     

Making BaZrS3 Chalcogenide Perovskite Thin Films by Molecular Beam Epitaxy

The making of BaZrS₃ thin films by molecular beam epitaxy (MBE) is demonstrated. BaZrS₃ forms in the orthorhombic distorted-perovskite structure with corner-sharing ZrS₆ octahedra. The single-step MBE process results in films smooth on the atomic scale, with near-perfect BaZrS₃ stoichiometry and an atomically sharp interface with the LaAlO₃ substrate. The films grow epitaxially via two competing growth modes: buffered epitaxy, with a self-assembled interface layer that relieves the epitaxial strain, and direct epitaxy, with rotated-cube-on-cube growth that accommodates the large lattice constant mismatch between the oxide and the sulfide perovskites. This work sets the stage for developing chalcogenide perovskites as a family of semiconductor alloys with properties that can be tuned with strain and composition in high-quality epitaxial thin films, as has been long-established for other systems including Si-Ge, III-Vs, and II-VIs. The methods demonstrated here also represent a revival of gas-source chalcogenide MBE.     

Binary monkey algorithm for approximate packing non-congruent circles in a rectangular container

A Packing problem consists in the best arrangement of several objects inside a bounded area named as the container. This arrangement must fulfill with technological constraints, for example, objects should not be overlapping. Some packing models for circular objects are typically formulated as non-convex optimization problems; where the continuous variables are the coordinates of the objects, so they are limited to not finding optimal solutions. Due to the combinatorial nature in the arrangement of such objects, heuristic methods are being used extensively which combine methods of global search and methods of local exhaustive search of local minima or their approximations. In this paper, we will address the packing problem for non-congruent (different size) circles with the binary version of the monkey algorithm which incorporates a cooperation process and a greedy strategy. We use a rectangular grid for covering the container. Every node in the grid represent potential positions for a circle. In this sense, binary monkey algorithm for the knapsack problem, can be used to solve de 0–1 approximate packing problem for non-congruet circles. The binary monkey problem uses two additional processes of the original monkey algorithm, these two processes are a greedy process and a cooperation processes.

     

用LED测光和发光

LED在便携设备中一般用于显示电源状态、电池状态．或蓝牙连接的活动。LED可以是决定电池寿命的主要因素．因为它们的亮度与功耗成正比。采用一种简单的电路．Altera公司的MAX忆CPLD可以测量其所处环境的模拟光照水平．然后以一个成比例的模拟强度水平驱动一只LED发光。一只LED和偏置电阻可以同时完成测光与发光。图1中的电路只需要45只逻辑元件,而CPLD的编程能力使之能够快速调节电路参数．以适应任何LED的特性。