Study of compatibilizers for glass fibre reinforced nylon 6/polypropylene blends

The efficiency of a synthesized interfacial modifier agent, acrylic acid grafted polypropylene (AAgPP) in glass fibre reinforced nylon 6/polypropylene (GFRN6/PP) blends has been studied. Scanning electron microscopy clearly shows that the dispersed phase particle size decreases when AAgPP content increases (12‐fold decrease in diameter) resulting in a more stable morphology. The established emulsification curve for this system emphasizes the efficiency of the synthesised AAgPP as a potential interfacial modifier for GFRN6/PP blends. AAgPP at 7.5 wt% is to be considered as the critical concentration for our blend; such a concentration corresponds to maximum interaction between the matrix and the dispersed phase. Strong interactions between the blend components have been observed. The effect of increasing the compatibility agent content on Izod impact, tensile strength, tensile modulus and elongation at yield has also been investigated, and a bell‐shaped trend observed with a maximum at 7.5 wt% AAgPP content. A 25 % increase in impact strength for the unnotched specimen, a twofold increase in tensile strength and a fourfold increase in tensile modulus are obtained. At 7.5 wt% AAgPP, a tough–brittle fracture transition is observed with a 2.5 µm particle size diameter. © 2000 Society of Chemical Industry.     

Cation exchange membranes by radiation-induced graft copolymerization of styrene onto PFA copolymer films. I. Preparation and characterization of the graft copolymer

PFA-g-polystyrene graft copolymers were prepared by simultaneous radiation-induced graft copolymerization of styrene onto poly(tetrafluoroethylene-co-perfluorovinyl ether) (PFA) films. The effects of grafting conditions such as monomer concentration, dose, and dose rate were investigated. Three solvents, i.e., methanol, benzene, and dichloromethane, were used as diluents in this grafting system. Of the three solvents employed, dichloromethane was found to greatly enhance the grafting process, and the degree of grafting increased with the increase of monomer concentration until it reached its highest value at a styrene concentration of 60 (vol %). The dependence of the initial rate of grafting on the monomer concentration was found to be of the order of 1.2. The degree of grafting was found to increase with the increase in irradiation dose, while it considerably decreased with the increase in dose rate. The formation of graft copolymers was confirmed by FTIR analysis. The structural investigation by X-ray diffraction (XRD) shows that the degree of crystallinity content of such graft copolymers decreases with the increase in grafting, and consequently, the mechanical properties of the graft copolymers were influenced to some extent. Both tensile strength and elongation percent decreased with the increase in the degree of grafting. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 73: 2095–2102, 1999     

Developments of high performance vibration absorber from poly(vinyl chloride)/chlorinated polyethylene/epoxidized natural rubber blend

A high performance vibration absorber requires a high loss factor behavior over a wide temperature and frequency range. An investigation was carried out to prepare such materials based on poly(vinyl chloride), chlorinated polyethylene, and epoxidized natural rubber ternary blends. The loss factor and damping behavior of several compositions were measured using a viscoelastic spectrometer and a polymer‐laminated steel cantilever‐beam damping device. Suitable compositions were found to give good mechanical properties and high loss factor over a wide temperature and frequency range. It was also observed that flake‐type fillers improve the damping behavior. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 71: 855–863, 1999     

Properties of some citrus seeds. Part 1. Physico-chemical characteristics of proteins

The protein solubility of some citrus seeds flours as well as physico-chemical characteristics were determined by gel filtration, polyacrylamide gel electrophoresis (PAGE), polyacrylamide gel electrophoresis in the presence of sodium dodecylsulphate (SDS-PAGE), and UV-spectrum. The highest solubility was in 0.1 M NaOH followed by both 0.1 M KCl and NaCl, respectively. The lowest solubility was in water. The protein solubility showed a minium with shift towards the acidic side in presence of 0.1 M and 0.5 M NaCl. The PAGE pattern showed two major protein fractions for citron, orange and mandarin seeds. SDS-PAGE proved presence of 3 major polypeptide chains in all seeds proteins. The apparent molecular weight was 37 304, 23 516 and 16 740 daltons, respectively. Also, the major protein fraction in all samples was globulin. The polypeptide chains were 4 for both albumins and globulins, 3 and 2 for prolamins and glutelins, respectively. Gel filtration revealed four peaks in all samples. The major peaks were eluted at 79 and 160 ml. All peaks were principally free from nucleic acids except peak No. 4.     

Thermal Behavior of Selected Starches in Presence of Other Food Ingredients Studied by Differential Scanning Calorimetery (DSC)–Review

ABSTRACT: This review article highlights the thermal behaviors of selected starches that were studied using differential scanning calorimetery (DSC) with data shown in various research publications. The starches of sago, potato, sweet potato, cassava, yam, and corn are included in this overview. Our examinations indicate that thermal properties are highly affected by the type of starch, its amylose/amylopectin content, and the presence of other food ingredients such as sugar, sodium chloride, water, milk, hydrocolloids, and meat. When the heating temperatures of the starches were increased, the DSC measurements also showed an increase in the temperatures of the gelatinization (onset [T_o], peak [T_p], and conclusion [T_c]). This may be attributed to the differences in the degree of crystallinity of the starch, which provides structural stability and makes the granule more resistant to gelatinization.     

Determination of biogenic amines in selected Malaysian food

The biogenic amines tryptamine (TRP), putrescine (PUT), histamine (HIS), tyramine (TYR) and spermidine (SPD) were determined in 62 selected food items commonly consumed in Malaysia. This include the local appetisers “budu” and “cincalok”, canned fish, salt-cured fish, meat products, fruit juice, canned vegetables/fruits and soy bean products. After the aqueous extraction, the samples were derivatised with dansyl chloride before analysing using reversed phase HPLC with UV detection. Mean levels of TRP, PUT, HIS, TYR and SPD in eight budu samples were 82.7, 38.1, 187.7, 174.7 and 5.1 mg kg⁻¹, respectively. The main biogenic amines found in cincalok were PUT, HIS and TYR where the mean values were 330.7, 126.1 and 448.8 mg kg⁻¹, respectively. With the exception of “pekasam” and “belacan”, significantly lower levels of biogenic amines were found in canned fish and salt-cured fish samples. Non detectable or low levels of biogenic amines were found in meat, fruit juice and canned vegetables/fruit samples.     

Tailoring (1)H Spin Dynamics in Small Molecules via Supercooled Water: A Promising Approach for Metabolite Identification and Validation

Metabolic mixtures are often analyzed via NMR spectroscopy as it provides a metabolic profile without sample alteration in a noninvasive manner. These mixtures however tend to be very complex and demonstrate considerable spectral overlap resulting in assignments that are sometimes ambiguous given the range of current NMR methods available. De novo molecular identification in these mixtures is generally accomplished using chemical shift information and J-coupling based experiments to determine spin connectivity information, but these techniques fall short when a molecule of interest contains nonrelaying centers. A method is presented here that enhances intramolecular spatial interactions via supercooled water and uses the resulting spatial correlations to edit mixtures. This is accomplished by utilizing nuclear Overhauser effect spectroscopy (NOESY) at subzero temperatures in capillaries to enhance NOE and provide more complete spin systems. This technique is applied to a standard mixture of three known molecules in D(2)O with overlapping resonances and is further demonstrated to assign molecules in a worm tissue extract. The current method proves to be a powerful complement to existing methods such as total correlation spectroscopy (TOCSY) to expand the range of molecules that can be assigned in situ without physical separation of mixtures.     

Effect of rotating cylinder on heat transfer in a square enclosure filled with nanofluids

Convective heat transfer in a differentially heated square enclosure with an inner rotating cylinder is studied theoretically. The free space between the cylinder and the enclosure walls is filled with water–Ag, water–Cu, water–Al₂O₃ or water–TiO₂ nanofluids. The governing equations are formulated for velocity, pressure and temperature formulation and are modeled in COMSOL, a partial differential equation (PDE) solver based on the Galerkin finite element method (GFEM). The governing parameters considered are the solid volume fraction, 0.0 ? ? ? 0.05, the cylinder radius, 0 ? R ? 0.3 and the angular rotational velocity, ?1000 ? Ω ? 1000. The results are presented to show the effect of these parameters on the heat transfer and fluid flow characteristics. It is found that the strength of the flow circulation is much stronger for a higher nanoparticle concentration, a better thermal conductivity value and a smaller cylinder with a faster, negative rotation. The maximum heat transfer are obtained at a high nanoparticle concentration with a good conductivity value, a slow positive rotation and a moderate cylinder size located in the center of the enclosure.     

Lie group analysis for the effects of temperature-dependent fluid viscosity and chemical reaction on MHD free convective heat and mass transfer with variable stream conditions

This paper concerns with a steady two-dimensional flow of an electrically conducting incompressible fluid over a vertical stretching surface. The flow is permeated by a uniform transverse magnetic field. The fluid viscosity is assumed to vary as a linear function of temperature. A scaling group of transformations is applied to the governing equations. The system remains invariant due to some relations among the parameters of the transformations. After finding three absolute invariants a third-order ordinary differential equation corresponding to the momentum equation and two second-order ordinary differential equation corresponding to energy and diffusion equations are derived. The equations along with the boundary conditions are solved numerically. It is found that the decrease in the temperature-dependent fluid viscosity makes the velocity to decrease with the increasing distance of the stretching sheet. At a particular point of the sheet the fluid velocity decreases with the decreasing viscosity but the temperature increases in this case. It is found that with the increase of magnetic field intensity the fluid velocity decreases but the temperature increases at a particular point of the heated stretching surface. Impact of chemical reaction in the presence of thermal radiation plays an important role on the concentration boundary layer. The results thus obtained are presented graphically and discussed.     

Mechanisation of large‐scale agricultural fields in developing countries – a review

Mechanisation of large‐scale agricultural fields often requires the application of modern technologies such as mechanical power, automation, control and robotics. These technologies are generally associated with relatively well developed economies. The application of these technologies in some developing countries in Africa and Asia is limited by factors such as technology compatibility with the environment, availability of resources to facilitate the technology adoption, cost of technology purchase, government policies, adequacy of technology and appropriateness in addressing the needs of the population. As a result, many of the available resources have been used inadequately by farmers, who continue to rely mostly on conventional means of agricultural production, using traditional tools and equipment in most cases. This has led to low productivity and high cost of production among others. Therefore this paper attempts to evaluate the application of present day technology and its limitations to the advancement of large‐scale mechanisation in developing countries of Africa and Asia. Particular emphasis is given to a general understanding of the various levels of mechanisation, present day technology, its management and application to large‐scale agricultural fields. This review also focuses on/gives emphasis to future outlook that will enable a gradual, evolutionary and sustainable technological change. The study concludes that large‐scale‐agricultural farm mechanisation for sustainable food production in Africa and Asia must be anchored on a coherent strategy based on the actual needs and priorities of the large‐scale farmers. © 2016 Society of Chemical Industry