Compact two-dimensional coarse-positioner for scanning probe microscopes

We report on the design and fabrication of a compact two-dimensional xy-positioner for scanning probe microscopes. This positioner uses three piezoelectric bimorphs in flexing or length-change mode by appropriate selection of electrodes and voltage polarities. One end of these bimorphs is fixed to a rectangular metal frame while on each of the free ends two sapphire disks are fixed which can slide against the polished plates of a platform movable in the xy-plane. For moving the platform by one step, the bimorphs are deformed sequentially in one mode and they are brought back to their undeformed state simultaneously. The motion of the positioner has been tested with an optical microscope and a homemade scanning tunneling microscope.     

Synthesis and characterization of polysiloxanes for controlled release of 2-pyridine aldoxime–chloride

A number of polysiloxanes and their copolymers were synthesized by hydrolytic polycondensation of dialkyl (ary) dichlorosilane or their mixtures in a saturated solution of NaCl in water at low temperature (0–5°C). These polysiloxanes were characterized by intrinsic viscosity, infrared and nuclear magnetic resonance spectroscopy. 2-Pyridine aldoxime–chloride (PAM–Cl) was incorporated into these polysiloxanes, followed by crosslinking with tetraethoxysilane using dibutyltindilaurate as catalyst. The effect of pH on in vitro release rate of PAM–Cl from polysiloxane matrices was investigated in phosphate buffer of pH 3.0, 7.4, and 10.0 at 37°C using an ultraviolet spectrophotometer. Transport parameters like the order of release and diffusion coefficients for these systems (polysiloxane—PAM–Cl) were also calculated. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 70: 1837–1846, 1998     

Guest–host interaction in ferroelectric liquid crystal–nanoparticle composite system

The present paper deals with the characterization of a ferroelectric liquid crystal–nanoparticle (FLC–NP) composite system. The dielectric, electrical and polarization property of the FLC–NP composite system have been studied as a function of temperature and frequency. Ferroelectric Cu-doped ZnO (Cu–ZnO) nanoparticles have been added to the pure ferroelectric liquid crystal (FLC) Felix 17/100. The nanoparticles are bigger in size as compared to FLC molecules; therefore, they distort the existing geometry of FLC matrix and set up an antiparallel correlation with the dipole moments of the host FLC molecules. This antiparallel correlation of guest–host geometry reduces the net ferroelectricity of the composite system and modifies all the physical properties of the pure FLC. The change in properties has been analysed and explained in the light of guest–host interaction.     

Computational Markets to Regulate Mobile-Agent Systems

Mobile-agent systems allow applications to distribute their resource consumption across the network. By prioritizing applications and publishing the cost of actions, it is possible for applications to achieve faster performance than in an environment where resources are evenly shared. We enforce the costs of actions through markets, where user applications bid for computation from host machines.We represent applications as collections of mobile agents and introduce a distributed mechanism for allocating general computational priority to mobile agents. We derive a bidding strategy for an agent that plans expenditures given a budget, and a series of tasks to complete. We also show that a unique Nash equilibrium exists between the agents under our allocation policy. We present simulation results to show that the use of our resource-allocation mechanism and expenditure-planning algorithm results in shorter mean job completion times compared to traditional mobile-agent resource allocation. We also observe that our resource-allocation policy adapts favorably to allocate overloaded resources to higher priority agents, and that agents are able to effectively plan expenditures, even when faced with network delay and job-size estimation error.     

Deformation mechanics in single-point and accumulative double-sided incremental forming

Single-point incremental forming (SPIF) uses one small hemispherically ended tool moving along a predefined toolpath to locally deform a completely peripherally clamped sheet of metal such that the sum total of the local deformations yields the final desired shape of the sheet. While SPIF is characterized by greater formability than conventional forming processes, it suffers from significant geometric inaccuracy. Accumulative double-sided incremental forming (ADSIF) is a substantial improvement over SPIF in which one hemispherically ended tool is used on each side of the sheet metal. The supporting tool moves synchronously with the forming tool, therefore acting as a local but mobile die. ADSIF results in considerably enhanced geometric accuracy and increased formability of the formed part as compared to SPIF. In light of the aforementioned advantages of ADSIF as compared with SPIF, an investigation of the mechanics associated with the ADSIF process, which has yet to be presented in the literature, is warranted. The present study sheds light on the differences in deformation mechanisms between SPIF and ADSIF. Finite element analyses are performed to simulate deformation in the two processes, and a detailed analysis of the deformation history is presented. It is shown that the presence of the supporting tool in ADSIF elicits substantial differences in the plastic strain, hydrostatic pressure, and shear strains as compared to SPIF. The implications of these trends on the prevalent modes of deformation in ADSIF along with possible explanations for increased formability observed in the process arediscussed.     

Polymer‐induced improvements in ferroelectric liquid crystal

The chevron geometry in the SmC* phase of ferroelectric liquid crystals (FLC) has been a major obstacle in the use of FLC in displays as it results in poor electro‐optical performance. The present paper reports a novel method to overcome this problem, by doping a small amount of polymer in the FLC matrix. In addition to the improvement in smectic ordering, polymer doping is also found to be useful in improving the vital electro‐optical properties. The various electro‐optical parameters like switching time, tilt angle, contrast ratio etc. show improvement in polymer mixed guest host mixture of FLC samples. POLYM. COMPOS., 31:1776–1781, 2010. © 2010 Society of Plastics Engineers.     

Dark fermentative hydrogen production by defined mixed microbial cultures immobilized on ligno-cellulosic waste materials

Mixed microbial cultures (MMCs) based on 11 isolates belonging to Bacillus spp. (Firmicutes), Bordetella avium, Enterobacter aerogenes and Proteus mirabilis (Proteobacteria) were employed to produce hydrogen (H₂) under dark fermentative conditions. Under daily fed culture conditions (hydraulic retention time of 2 days), MMC6 and MMC4, immobilized on ligno-cellulosic wastes – banana leaves and coconut coir evolved 300–330 mL H₂/day. Here, H₂ constituted 58–62% of the total biogas evolved. It amounted to a H₂ yield of 1.54–1.65 mol/mol glucose utilized over a period of 60 days of fermentation. The involvement of various Bacillus spp. – Bacillus sp., Bacillus cereus, Bacillus megaterium, Bacillus pumilus and Bacillus thuringiensis as components of the defined MMCs for H₂ production has been reported here for the first time.