India’s water management debate: is the ‘civil society’ making it everlasting?

Abstract

This article discusses the bias of the growing constituency of civil society activists in India against conventional water management solutions implemented by the government, and the ‘alternatives’ they champion, which force the government to enter into an endless debate with these groups. The article goes into the fundamental reasons for this bias, and identifies four types of civil society activist: ‘professional’, ‘ideologue’, ‘romantic’ and ‘doomsday prophet’. The article also argues that water bureaucracies in India should adopt evidence-based policy making, subjecting the ‘alternatives’ to the same degree of scrutiny as the conventional ones, to end the policy dilemma, while enhancing the overall quality of design, execution and management of projects for better outcomes.     

Improved energy recovery from dark fermented cane molasses using microbial fuel cells

A major limitation associated with fermentative hydrogen production is the low substrate conversion efficiency. This limitation can be overcome by integrating the process with a microbial fuel cell (MFC) which converts the residual energy of the substrate to electricity. Studies were carried out to check the feasibility of this integration. Biohydrogen was produced from the fermentation of cane molasses in both batch and continuous modes. A maximum yield of about 8.23 mol H₂/kg COD_removed was observed in the batch process compared to 11.6 mol H₂/kg COD_removed in the continuous process. The spent fermentation media was then used as a substrate in an MFC for electricity generation. The MFC parameters such as the initial anolyte pH, the substrate concentration and the effect of pre-treatment were studied and optimized to maximize coulombic efficiency. Reductions in COD and total carbohydrates were about 85% and 88% respectively. A power output of 3.02 W/m³ was obtained with an anolyte pH of 7.5 using alkali pre-treated spent media. The results show that integrating a MFC with dark fermentation is a promising way to utilize the substrate energy.     

Persistent organochlorine pesticide residues in milk and dairy products in India

Monitoring of milk and dairy product samples of various brands from different cities in Maharashtra, India, was carried out to determine if there is any contamination due to organochlorine pesticide residues. The measurements were made using a gas chromatograph-electron capture detector system. Trace levels of DDT and HCH were detected in the samples. Total HCH levels in milk and milk product samples were lower than total DDT levels, which could be attributed to earlier extensive antimalaria sanitary activities. Butter had higher levels of DDT than cheese and milk powder. All levels of organochlorine pesticide residues in milk and milk products were well below the maximum permissible limits given by the FAO/WHO. More importantly, as compared with an earlier report, present levels of the contaminants are substantially lower, which indicate the gradual phase out of these compounds.     

Use of tissue transglutaminase and fibronectin to influence osteoblast responses to tricalcium phosphate scaffolds

To explore the possibility of controlling cell interaction with biomaterials, tricalcium phosphate scaffolds were modified using the enzyme tissue transglutaminase (tTgase) in conjunction with fibronectin. Previous reports in the literature have highlighted a number of favourable responses that this protein-enzyme complex can stimulate, including enhancing both cell adhesion, and mineralisation. Fibronectin and tTgase alone were used as controls, and a series of different concentrations of tTgase and fibronectin in combination were assessed. Cell metabolic activity, alkaline phosphatase production, and collagen content were all measured in cultures up to 28 days. Using tetracycline labelling, calcium containing multilayered regions were imaged and quantified. Addition of 6 microg fibronectin resulted in increased alkaline phosphatase activity in all combinations, while increased transglutaminase resulted in more collagen in the cell lysates. Samples treated with fibronectin produced many small mineralised areas, those with 6 microg fibronectin and transglutaminase produced numerous large mineralised areas. The mixture of fibronectin and transglutaminase may prove to be a useful treatment for producing increased osteoblast differentiation on scaffolds.     

Destruction of formic acid using high frequency cup horn reactor

Degradation of formic acid has been studied in a high frequency cup horn type reactor with an aim of understanding the effect of operating parameters on the destruction efficiency. The methodology used in the work serves as a useful guideline for the optimization exercise for the sonochemical reactors to establish a set of operating parameters at large scale operation for achieving maximum efficiency. Firstly energy efficiency of the reactor has been established as a function of the operating volume with an aim of optimization of the capacity of the reactor for maximum extent of degradation. It has been observed that maximum transfer of supplied power is obtained at 300 ml capacity and hence the actual degradation studies have been performed with this operational capacity. The effect of time of irradiation, initial concentration of the pollutant, stirrer speed, presence of sodium sulfite (to scavenge the initial dissolved oxygen) on the extent of degradation has been investigated. Maximum extent of degradation has been observed under the conditions of 500 mg/l initial concentration, 200 rpm stirrer speed and presence of initial dissolved oxygen (no sodium sulfite in the system). Process intensification studies have been carried out using sodium chloride over a range of initial concentration and it has been observed that maximum extent of degradation of formic acid is obtained at 4% NaCl concentration. Comparison has been also made with different sonochemical configurations operating at lower frequency of irradiation (typically in the range of 20-50 kHz) with an aim of comparing the efficacies of the reactor at equivalent power consumption.     

Residual aluminium in water defluoridated using activated alumina adsorption - Modeling and simulation studies

The removal of fluoride from drinking water by the method of adsorption on activated alumina is found superior than other defluoridation techniques mostly due to the strong affinity between aluminium and fluoride. Dissolution of aluminium from the alumina surfaces into its free and hydroxide ions in the aqueous medium is reported to be very low, but the presence of high fluoride concentrations may increase its solubility due to the formation of monomeric aluminium fluoride and aluminium hydroxyl fluoride complexes. An Activated Alumina Defluoridation Model Simulator (AAD) has been developed to represent fluoride adsorption on the basis of the surface complexation theory incorporating aspects of aluminium solubility in presence of high fluoride concentrations and pH variations. Model validations were carried out for residual aluminium concentrations in alumina treated water, by conducting a series of batch fluoride adsorption experiments using activated alumina (grade FB101) treating fluoride concentrations of 1-10 mg/L, at varying pH conditions. The total residual aluminium in the defluoridated water is due to presence of both dissolved and precipitated Al-F complexed forms. The Freundlich adsorption isotherm was found fit for fluoride adsorption capacity versus residual fluoride concentrations for pH = 7.5, and the relationship is given by the linearised equation log (x/m) = log k + (1/n) log C_e with values of k = 0.15 mg/g and 1/n = 0.45 indicating favorable adsorption. The relationship is linear in the region of low fluoride concentrations, but as concentrations of fluoride increased, the formation of the dissolved AlF₃⁰ complexes was favored than adsorption on alumina, and hence makes the isotherm nonlinear. The AAD simulations can predict for operating fluoride uptake capacity in order to keep the residual aluminium within permissible limits in the alumina treated water.     

Uplift capacity of horizontal anchor plate in geocell reinforced sand

The paper investigates the uplift performance of horizontal anchor plate in geocell reinforced sand through a series of model tests. It is noted that the unreinforced anchor plate undergoes a clear failure at a displacement of about 3% of its width, whereas with the provision of geocell and a layer of geotextile right below the geocell mattress significantly increases the uplift capacity by about 4.5 times higher than that of unreinforced sand and could sustain anchor displacement of more than 60%. Results indicates that the geocell mattress by virtue of its rigidity distributes the uplift load in the lateral directions to a larger area, thereby reducing the stress in the overlying soil mass and hence increases the performance of anchor plate system. The provision of the additional geotextile layer right below the geocell mattress is found to be very effective in increasing the stiffness as well as load carrying capacity of anchor plate system. The optimum size (i.e., width and length) of geocell mattress giving adequate load carrying capacity of anchor plate is found to be 5.4 times of anchor width (5.4B). The comparison of model tests results with 3D numerical analysis shows good agreement, indicating that the proposed model is able to capture the uplift load-displacement behaviour of geocell reinforced anchor plate system.     

Two-criteria optimization of H-section bars–beams under bending and compression

The two-criteria optimum design problem for thin-walled members with two axes of symmetry (of H-type) subjected to compression and bending is solved. Components of the objective function vector are the compressive force and the bending moment in the web plane. Pareto-optima and “compromise” optimal projects have been obtained and compared with standard profiles.