Enzymatic degradation of thermoresponsive poly(N‐isopropylacrylamide) grafted to carboxymethylcellulose copolymers

The enzymatic degradation of poly(N‐isopropyl acrylamide) (PNIPAM) grafted to carboxymethylcellulose (CMC) copolymers with a cellulasic preparation (Trichoderma viride) was studied. The enzymatic activity of the cellulasic preparation against CMC and the grafted copolymers was determined by the Petterson–Porath method, while their reduced viscosity variation in the presence of the same preparation was also followed. It has been shown that the enzymatic degradation behavior depends on the copolymer composition and the reaction temperature. Reducing sugars analysis showed that the experimental values for the grafted copolymers were higher than the calculated ones. At 50°C, the enzymatic reaction is completed in about 20 min for the copolymers, whereas for CMC it takes more than 40 min. It can be concluded that their enzymatic degradation is facilitated by the presence of the PNIPAM grafts. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 1383–1386, 2003     

低雾化低挥发性汽车用新型聚氨酯泡沫塑料助剂

康普顿公司开发了一系列适用于消除或减少汽车内饰件中胺扩散或雾化的添加剂，其中包括快速、有效的生产用零扩散催化剂和低雾化表面活性剂。该系列添加剂能大大降低泡沫制品中的胺扩散，与异氰酸酯和多元醇原料能组成最佳组合，以保持良好的泡沫物理性能。     

The allelopathic mechanisms of dominance in bracken (Pteridium aquilinum) in Southern California

Bracken,Pteridium aquilinum, exerts a strong dominance over associated plants throughout much of its worldwide range. Associated plants are often severely inhibited or even excluded from dense stands of the fern. This study investigated the various aspects of herb suppression in bracken stands and assessed the contribution of the various forms of interference between plants to the establishment and maintenance of bracken dominance. It was shown that competition for soil moisture, light, and nutrients could not account for the lack of herbs in bracken stands. Further, uniformity of soil pH, texture, water-holding capacity, and organic matter content ruled out variability in physical factors as a cause. Baiting and trapping experiments showed that the higher concentration of animal activity inside the bracken stands contributed significantly to the pattern of herb suppression, but only against select species. The maintenance of this pattern in the animal-free Santa Cruz Island stands indicates the importance of another factor, allelopathy. It was found that phytotoxins leached from the dead, standing bracken fronds with the first few rains of the wet season were largely responsible for herb suppression. These toxins were isolated in raindrip and from soil inside the fern stands. Removal of the fronds from the stand before the rains could leach them resulted in reinvasion by the herbs after several seasons, and, conversely, placing fronds over the herbs in the grassland brought about herb inhibition. A number of known allelopathic chemicals were tentatively identified from bracken leachates. The importance of the interaction of allelopathy with other factors of plant interference is illustrated by bracken.     

Online light scattering measurements: A method to assess morphology development of polymer blends in a twin‐screw extruder

Light scattering has proved itself an efficient technique to determine particle diameters in heterogeneous dilute dispersions in the micrometer range. Extrusion of polymer blends is expected to give rise to very small particles, typically in the range from hundreds of nanometers to tens of micrometers. A light scattering device developed in our laboratory has been used to study the morphology of polymer blends obtained in a twin‐screw extruder. The main advantage of this technique is the immediate response obtained without any surface or interface modification that can occur during the sample preparation by using more conventional techniques like electron microscopy. To show the possible applications of this light scattering device, preliminary tests have been carried out. First, we present a comparison between experimental measurements and theoretical results for dilute systems. Second, we have investigated the effect of shear flow on the droplet deformation. Finally, we have studied the variations of the light scattering pattern for a reactive blend.     

Result Merging Technique for Answering XPath Query over XSLT Transformed Data

Caching stores the results of previously answered queries in order to answer succeeding queries faster by reusing these results. We propose two different approaches for using caches of XSLT transformed XML data in order to answer queries. The first approach checks whether or not a current query Q can be directly answered from the result of a previously answered query Qi stored in the cache. The new query is otherwise submitted to the source over the network, the answer of the query is determined, transmitted back to the client, and stored in the cache. The second approach determines only the intersection Q−Qi and integrates the result of Q−-Qi into the previous results in the cache, which requires applying a numbering scheme for the output of the XSLT stylesheet. We show by experimental results that the second approach can significantly speed up the answering time in comparison to the first approach, but is not significantly slower in few worst cases than the second approach.     

Interpretation time of serial chest CT examinations with stacked-metaphor workstation versus film alternator

PURPOSE: Interpretation time of serial staging chest CT cases, which each contained current and previous examinations, with a simple prototype workstation called filmstack was experimentally compared with interpretation time with a film alternator. MATERIALS AND METHODS: The filmstack displayed a "stack" of sections for each examination; user controls allowed rapid selection of preset attenuation windows and both synchronized and unsynchronized scrolling. Eight radiologists were timed as they used the filmstack and the film alternator to interpret four ergonomically complex serial CT cases. RESULTS: All reports dictated on the basis of findings with filmstack and film were of acceptable clinical accuracy. The time to examine a case with filmstack was significantly faster than the time with film, including the time to load and unload the alternator (99% confidence [P = .01]). There was no statistically significant difference in interpretation time between filmstack and prehung film. CONCLUSION: Use of a low-cost stacked CT workstation with a single 1,024 x 1,024 monitor is an effective means of interpreting cases that require comparison of multiple CT examinations.     

Analysis of dynamic magnetic resonance images

Dynamic magnetic resonance (MR) imaging with contrast agents is a very promising technique for studying tissue perfusion in vivo. A temporal series of magnetic resonance images of the same slice are acquired following the injection of a contrast agent into the blood stream. The image intensity depends on the local concentration of the contrast agent, so that tissue perfusion can be studied by the image series. A new method of analyzing such series is described here. Nonparametric linear regression is used for modeling the image intensity along the series on a pixel by pixel basis. After modeling, some relevant quantities describing the time series are obtained and displayed as images. Due to its flexibility, this approach is preferred to parametric modeling when pathology is present since this can induce a wide spread of patterns for the pixel image intensity along time. Results of the application of the method to series of dynamic magnetic resonance images from ischaemic rat brains after the injection of the susceptibility agent Sprodiamide Inj. (Dy-DTPA-BMA) are shown and compared to results from a related known method.     

Using a Trust Inference Model for Flexible and Controlled Information Sharing During Crises

The fluid, urgent nature of crises requires flexible, responsive information sharing. Recent studies show, however, that in business catastrophes and other kinds of crises conventional access control mechanisms favor security over flexibility. Our work addresses these seemingly contradictory needs for security and flexibility and designs a trust inference model based on fuzzy logic, a model that can be used with pervasive computing technologies using sensors and mobile devices. Drawing upon research on trust, we design a trust inference model using attributes of affiliation, task performance, and urgency; apply the model to a known crisis; discuss implementation issues; and explore issues for further research. This article is dedicated to Alan Jarman, a founding influence in the Journal of Contingencies and Crisis Management who died in Canberra 15 July 2010. Alan's quantitative, engineering background and his long standing commitment to improving crisis decision making prompted him to encourage our applying fuzzy logic to crisis information sharing. We are grateful for Alan's encouragement and advice.     

Towards Timbre-Invariant Audio Features for Harmony-Based Music

Chroma-based audio features are a well-established tool for analyzing and comparing harmony-based Western music that is based on the equal-tempered scale. By identifying spectral components that differ by a musical octave, chroma features possess a considerable amount of robustness to changes in timbre and instrumentation. In this paper, we describe a novel procedure that further enhances chroma features by significantly boosting the degree of timbre invariance without degrading the features' discriminative power. Our idea is based on the generally accepted observation that the lower mel-frequency cepstral coefficients (MFCCs) are closely related to timbre. Now, instead of keeping the lower coefficients, we discard them and only keep the upper coefficients. Furthermore, using a pitch scale instead of a mel scale allows us to project the remaining coefficients onto the 12 chroma bins. We present a series of experiments to demonstrate that the resulting chroma features outperform various state-of-the art features in the context of music matching and retrieval applications. As a final contribution, we give a detailed analysis of our enhancement procedure revealing the musical meaning of certain pitch-frequency cepstral coefficients.