One-, two-, and three-photon pumped lasing in a novel liquid dye salt system

We report the observation of one-, two-, and three-photon pumped lasing in the same medium, a novel liquid dye salt system when excited by pulsed 0.532-, 1.06-, and /spl sim/1.49-/spl mu/m coherent radiation pulses, respectively. Since the gain medium is a liquid and not a solution, it contains a significantly higher effective dye concentration and, therefore, is highly suitable for multiphoton pumped lasing and optical power limiting applications. The lasing spectra, temporal waveforms, near- and far-field intensity distributions, and output/input efficiency were measured under the conditions of one-, two-, and three-photon pump configurations.     

Outage Theorems for MIMO Block-Fading Channels

The connection between the average codeword or frame error probability (FEP) of space-time codes and the outage probability over general block-fading multiple-input multiple-output (MIMO) channels is established. Three archetypal problems are considered under general fading distributions in a single framework wherein the receiver has channel state information whereas the transmitter knows a) the fading distribution but not the channel realization b) the channel realization but must follow a short term (per codeword) average power constraint, and c) the channel realization but is constrained only by a long-term average power constraint. Three telescoping sets of space-time codes are defined for a given rate and it is shown that average FEPs arbitrarily close to the respective outage probabilities for each of the three cases a)-c) can be achieved by codes in each set for sufficiently large frame lengths. For the smallest set among the three which contains codes with a spectral norm constraint that is stricter than the average or maximum energy constraints commonly assumed, firm sphere-packing lower bounds on the FEP are obtained, and, consequently, strong converse theorems are proved which assert that the respective outage probabilities also represent the best achievable FEP in the large frame-length limit. Moreover, the set of spectral norm constrained codes are also shown to be large enough to contain universal codes that can communicate reliably over any channel realization for which the mutual information exceeds the information rate of the code     

A Class of Algorithms for Collision Resolution with Multiplicity Estimation

The wireless connectivity in pervasive computing has ephemeral character and can be used for creating ad hoc networks, sensor networks, connection with RFID (Radio Frequency Identification) tags etc. The communication tasks in such wireless networks often involve an inquiry over a shared channel, which can be invoked for: discovery of neighboring devices in ad hoc networks, counting the number of RFID tags that have a certain property, estimating the mean value contained in a group of sensors etc. Such an inquiry solicits replies from possibly large number of terminals n. This necessitates the usage of algorithms for resolving batch collisions (conflicts) with unknown conflict multiplicity n. In this paper we present a novel approach to the problem of collision resolution for batch conflicts. We show how the conventional tree algorithms for collision resolution can be used to obtain progressively accurate estimation of the multiplicity. We use the estimation to propose a more efficient binary tree algorithm, termed Estimating Binary Tree (EBT) algorithm. The EBT algorithm is suited for implementation when the conflicting nodes are passive, such as e.g. RFID tags. We extend the approach to design the Interval Estimation Conflict Resolution (IECR) algorithm. For n→∞ we prove that the efficiency achieved by IECR for batch arrivals is identical with the efficiency that Gallager’s FCFS algorithm achieves for Poisson packet arrivals. For finite n, the simulation results show that IECR is, to the best of our knowledge, the most efficient batch resolution algorithm reported to date.     

Modelling and experimental investigation of devolatilizing wood in a fluidized bed combustor

A two-dimensional model is developed for the determination of devolatilization time and char yield of cylindrical wood particles in a bubbling fluidized bed combustor. By using the concept of shape factor, the model is extended to particles of cuboid shape. The model prediction of the devolatilization time agrees with the measured data (present and those reported in the literature) for cylindrical and cuboidal shaped particles within ±20% while the char yield is predicted within ±17%. Influence of some important parameters namely, thermal diffusivity, external heat transfer coefficient and shrinkage, on the devolatilization time and char yield are studied. Thermal diffusivity shows noticeable influence on devolatilization time. The external heat transfer coefficient shows little influence beyond a value of 300 W/(m² K). However particle shrinkage shows negligible effect on the devolatilization time but has a significant influence on the char yield.     

Noninvasive assessment of regional ventilation in the human lung using oxygen-enhanced magnetic resonance imaging

The imaging of regional ventilation in the lungs is essential for the evaluation of a variety of pathological conditions, such as emphysema, pneumonia and pulmonary embolism. We propose a novel approach for ventilation scanning, using magnetic resonance imaging (MRI) and inhaled molecular oxygen as a contrast agent, that directly depicts transfer of oxygen across the alveolus into the pulmonary vasculature. Molecular oxygen is only weakly paramagnetic but produces substantial signal changes in the lungs because of their large surface area. Ventilation defects were shown in a patient with bullous emphysema, and ventilation-perfusion mismatches were shown in two patients with pulmonary embolism.     

Probing acid sites in MAPO-36 by solid state NMR

An ordering of magnesium is observed in the as-synthesized MAPO-36 molecular sieve. Upon calcination, part of the magnesium is removed from the sample and part occupies extraframework positions thus rendering a random distribution of magnesium in the lattice. The shoulder observed in the³¹P spectrum of the calcined sample is assigned to P(3Al, 1Mg) sites in conflict with the earlier assignment to P-OH groups. The bridging hydroxyl groups located at these sites are detected in the¹H MAS spectrum at 3.6 ppm. Further, MAPO-36 catalyzed acetone conversion to mesityloxide that cracked at elevated temperature to yield acetic acid and aliphatics.     

Intermodulation analysis of the collector-up InGaAs/InAlAs/InP HBTusing Volterra series

The intermodulation (IM) distortion of the collector-up InGaAs/InAlAs/InP heterojunction bipolar transistor (HBT) is analyzed using Volterra-series theory. A T-equivalent circuit is used for this analysis. The contribution and interaction of four nonlinear elements: base-emitter resistance, base-emitter capacitance, base-collector capacitance, and common base-current gain are analyzed. For the particular device under investigation, it is found that the cancellation effect is not significant and the base-emitter resistance nonlinearity dominates the third-order IM     

Dry sliding wear response of some bearing alloys as influenced by the nature of microconstituents and sliding conditions

An attempt has been made in this study to examine the dry sliding wear response of a leaded-tin bronze, an aluminum bronze, and a conventional zinc-based alloy under varying applied pressure and speed conditions. Different characteristics of the microconstituents of the alloys have been correlated with that of their wear behavior. The study clearly indicates that the influence of the microstructural features greatly changes with the sliding conditions. It also has been observed that in order to attain good wear characteristics, a material should comprise an optimum level of lubricating, load bearing and ductile microconstituents, and, above all, thermal stability. Room temperature properties in fact play rather a secondary role in this context.