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排序方式: 共有407条查询结果,搜索用时 406 毫秒
41.
Ramin Reyhani Barzegar Somaye Akbari Mohammad Haghighat Kish 《Polymer International》2013,62(12):1767-1776
Acrylonitrile/acrylic acid copolymers were synthesized with different mole fractions (1, 2, 5 and 10 mol%) of acrylic acid (AA) in the feed by aqueous suspension polymerization, and bead‐free fibres (295–375 nm in diameter) were made from the copolymers in dimethylformamide solutions by electrospinning. In a heterogeneous system containing electrospun fibre mats, dendritic molecules were grown by reaction between carboxylic acid of AA and –OH groups of citric acid activated by dicyclohexylcarbodiimide. The products were analysed using 1H NMR, 13C NMR and Fourier transform infrared spectroscopies, density determination, scanning electron microscopy, optical microscopy, differential scanning calorimetry and pH response properties. With decreasing AA content, the isotacticity of the copolymers decreases with a more random distribution of the co‐monomers which leads to higher percentage conversions of dendrigraft due to reduced steric hindrance. On the formation of dendrigraft, the percentage conversion of the reactions decreases with an increase of generation number and AA content. A reduction of density for the first generation and then an increase with increasing generation are observed. During oxidation stabilization of fibres with a decrease of AA content and an increase in generation number, the amount of liberated heat increases. Fibres containing more carboxylic groups show significantly greater amounts of swelling/de‐swelling in basic and acidic media, respectively. To be used as nanocarbon fibre precursors, or as active particles for loading with guest molecules, or as pH actuators, the first generation of dendrigrafted fibres are expected to have the greatest potential among the various samples examined. © 2013 Society of Chemical Industry 相似文献
42.
Zinc oxide nanoparticles (ZnO-NPs) were synthesized via the sol-gel method in gelatin media. Long-chain gelatin compounds were utilized to terminate the growth of ZnO-NPs and to stabilize them. The ZnO-NPs were characterized by a number of techniques, such as X-ray diffraction analysis (XRD), Fourier transform infrared spectroscopy (FTIR), and high-magnification transmission electron microscopy (TEM). The ZnO-NPs calcined at different temperatures exhibited a hexagonal (wurtzite) structure with sizes from 30 to 60 nm. The influence of the calcination temperature on the morphology of ZnO-NPs was also investigated. The results showed that gelatin is an interesting material that can be used as a stabilizer in the sol-gel technique for preparing small ZnO-NPs. 相似文献
43.
Zavgorodniy AV Borrero-López O Hoffman M Legeros RZ Rohanizadeh R 《Journal of materials science. Materials in medicine》2011,22(1):1-9
Bioactive hydroxyapatite (HA) coating on titanium (Ti) implant can be used as a drug delivery device. A controlled release
of drug around the implant requires the incorporation of drug into the coating material during the coating process. HA coating
was prepared using a two-step procedure in conditions suitable for simultaneous incorporation of the protein-based drug into
the coating material. Monetite coating was deposited on Ti substrate in acidic condition followed by the transformation of
the monetite coating to HA. X-ray diffraction (XRD) confirmed the formation of the monetite phase at the first step of the
coating preparation, which was transformed into HA at the second step. Fourier transform infrared spectroscopy demonstrated
typical bands of a crystallized carbonated HA with A- and B-type substitution, which was confirmed by the XRD refinement of
the structural parameters. Scanning electron microscope was used to observe the morphology of monetite and HA coatings. Adhesion
of the coatings was measured using a scratch tester. The critical shearing stress was found to be 84.20 ± 1.27 MPa for the
monetite coating, and 44.40 ± 2.39 MPa for the HA coating. 相似文献
44.
Ramin Nabizadeh Alireza Mesdaghinia 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2006,81(7):1209-1217
Biofilm systems have been extensively used for treating different types of wastewater. Difficulty in determination of microbial mass in fixed‐film reactors has been always the greatest problem in evaluating effects of loading rates on the microbial population in such reactors. For this reason, the effect of operating parameters such as organic loadings on the available microbial mass in the system and solids retention time (SRT) have not been discussed in detail. In this study an innovative methodology was developed to simulate the quantity of microbial mass in an aerated submerged fixed‐film reactor (ASFFR) reactor. After determination of kinetic parameters, a dynamic model was developed using STELLA, popular dynamic modeling software, to simulate the microbial mass in the reactor at run time. The pilot plant study was performed with two different surface media and at different loading rates from 2.37 to 19.56 g m?2 d?1. Furthermore, the effect of different organic loadings on the accumulation of microbial mass and SRT have been studied and the relevant mathematical relationships were presented. This method makes the evaluation of biofilm system simple and practical without taking samples to quantify microbial mass in reactors. Copyright © 2006 Society of Chemical Industry 相似文献
45.
Mohammad Reza Karafi Ramin Narimani Yousef Hojjat Mojtaba Gheybi 《The International Journal of Advanced Manufacturing Technology》2010,50(9-12):953-960
This paper presents a method for automatic control of arc length in tungsten inert gas (TIG) welding process using the arc voltage. By using this method, the role of operator in arc length control is played by an automatic control system based on a predefined arc voltage value for any special welding operation. A dynamic model for feed-rate mechanism and the relation between variations of arc length and voltage are described in details. Using a proportional-integral controller, variations of arc length in welding path is compensated with an automatic feed-rate mechanism in a normal direction to the welding path. By keeping the voltage constant during the process, a stable weld with higher quality and better appearance is obtained specially in welding of uneven surfaces. Theoretical and practical investigations show that the suggested method is able to control the TIG welding process successfully. Test results show that an accurate weld is obtained without the interference of the operator, and by comparing the predefined values of arc voltage with what is practically obtained, the welding gap is automatically adjusted. 相似文献
46.
There is a great variety of two‐phase models in numerical simulations. The performance of each model complicates the numerical simulation of boiling. The challenge of the right choice of heat and mass transfer models makes this type of problem more complicated. In this research work, the volume of the fluid two‐phase model has been used to simulate the film boiling of saturated liquid. The geo‐reconstruction method also reconstructs the interface of two phases. The models of the sharp interface, Lee and Tanasawa have been employed among the available models for calculating the phase change rate and the source terms of the equations. The Numerical solver of the phase‐change is verified through the Stefan one‐dimensional vaporizing problem. Correct empirical coefficients used in both Lee and Tanasawa models are presented. Bubble detachment time, flow pattern, the periodic Nusselt number, and the bubble form have been investigated in all three phase change models. Two Berenson and Klimenko experimental correlations have been used for verification of Nusselt number derived from simulations. The Nusselt number shows a proper fit with the Klimenko's Nusselt number. Obtained Nusselt number demonstrates the Lee model is more precise than other phase change models in simulating of film boiling on the flat plate. 相似文献
47.
48.
NiMo nanocatalysts supported on activated red mud with different zeolite beta contents were successfully prepared by impregnation technique. Their hydrocracking and hydrodesulfurization activities were evaluated with two different kinds of diesel feed (iso diesel and heavy diesel) in a fixed bed reactor at ambient pressure and 500 °C. Physico-chemical properties of synthesized samples were characterized using the methods of XRF, XRD, FESEM, BET, FTIR and NH3-TPD. The results indicated that zeolite incorporation resulted in a significant increase in specific surface area (BET result) and acidic strength (TPD result) of nanocatalysts. FESEM analysis confirmed that the particles size of zeolite-containing NiMo/ARM was less than 100 nm and the average size of particles was about 30 nm. Hydrocracking results illustrated that incorporation of zeolite beta improved cracking activity considerably. In addition, NiMo nanocatalyst containing 37.5 wt% of zeolite had the highest yields of desirable products (naphtha, kerosene and diesel) and the highest conversion. Moreover, the flash point and viscosity of the liquid product decreased notably the nanocatalysts with 37.5 wt% and 12.5 wt% of zeolite were able to remove approximately 96% and 72% of the sulfur content of iso diesel and heavy diesel, respectively. 相似文献
49.
Wireless Personal Communications - Target tracking in wireless sensor networks is one of the well-known applications of such networks. The use of sensor-based electronic devices is becoming... 相似文献
50.
The Journal of Supercomputing - Depression is the most prevalent mental disorder that can lead to suicide. Due to the tendency of people to share their thoughts on social platforms, social data... 相似文献