Study on effect of diverse air inlet arrangement on thermal management of cylindrical lithium-ion cells

Lithium-ion cells are preferred in the electrical powertrain due to high-power density, compactness, and modularity. In real driving conditions, the cells undergo discharge rates as high as 4 C resulting in high heat generation affecting the performance. To obtain the maximum performance the pack construction and thermal management of cells are crucial parameters. In our work, air-cooled technique with diverse air inlet and staggered scheme with a two-channel partition approach for thermal management of the cylindrical lithium-ion cells are studied in computational fluid dynamics. The simulation model is validated with experimental results. The obtained results demonstrate that the cells in the dual-directional air inlet arrangement had low maximum temperature difference among and within the cells and required least fan work. This arrangement required least fan work to generate optimal air inlet velocity of 2 m/s for 1, 2, and 3 C and 4 m/s for 4 C discharge rates. There is a reduction of 50% and 33% fan work for 3 and 4 C discharge rates, which are the majority operating points. Also, it shows that the temperature uniformity within the cells has improved. The results of this study can used to optimize parameters for designing an enhanced thermal management system.     

Pebble games for studying storage sharing

Pebble games are played on a directed acyclic graph (dag). Placing a pebble on a vertex may be thought of as entering the value of the subexpression represented by the vertex into accessible storage. In some applications, there are types associated with vertices e.g. some vertices may represent functions, others may represent function values. We are interested in determining if vertices of the same type can share storage. The problem considered is as follows. We are given a labelled dag to be pebbled. A pebble may be placed on a vertex if all sons of the vertex have pebbles—in fact it is legal to move a pebble from a son to a father. Pebbles may be picked up at any time. The objective is to pebble each vertex exactly once. We will be interested in ‘one pebblings of l vertices’ in which there is at most one pebble on vertices with label l, at all times; and ‘stack pebblings of l vertices’ in which the pebbled vertices with label l are along a path, at all times. Results about the existence of such pebblings are presented. The results have applications to testing serializability of database updates, and potential applications to semantics directed compiler generation.     

Effective solar power harnessing using a few novel solar tree designs and their performance assessment

Solar irradiance being considered as one of the most important alternative sources of energy can be harnessed in the form of electrical power using photovoltaic panels erected under the sun. Optimum conversion of power from solar panels can be obtained by using Maximum Power Point Tracking (MPPT), which involves continuously adjusting the angle of panels according to the change in the angle of falling irradiance. These trackers, however, use some amount of power for operation of MPPT equipment. Various techniques for arranging the solar panels in three dimensions have been suggested for optimizing the output power from them. The inspiration behind arranging the panels are often drawn from the natural trees where the branches and the leaves follow a particular pattern called phyllotaxy which is directly analogous to the Fibonacci number and Golden ratio. In this research work, the power output from two solar tree models based on 3/8 and 2/5 phyllotaxy pattern and solar conventional panel compared under similar irradiance conditions. There are so many phyllotaxy patterns like 1/3, 2/5, 3/8, etc. When the solar panels aligned in different phyllotaxies, then the orientation direction of solar panels are distinct. Each solar panel connected in solar trees is in a different direction, so that they received the maximum amount of sunlight throughout the day as compared to conventional panels which is oriented unidirectional.     

A spiral shaped regenerative microfluidic fuel cell with Ni‐C based porous electrodes

Microchannel geometry, electrode surface area, and better fuel utilization are important aspects of the performance of a microfluidic fuel cell (MFC). In this communication, a membraneless spiral‐shaped MFC fabricated with Ni as anode and C as a cathode supported over a porous filter paper substrate is presented. Vanadium oxychloride and dilute sulfuric acid solutions are used as fuel and electrolyte, respectively, in this fuel cell system. The device generates a maximum open‐circuit voltage of ~1.2 V, while the maximum energy density and current density generated from the fuel cell are ~10 mW cm^?2 and ~51 mA cm^?2, respectively. The cumulative energy density generated from the device after five cycles are measured as ~200 mW after regeneration of the fuel by applying external voltage. The spiral design of the fuel cell enables improved fuel utilization, rapid diffusive transport of ions, and in‐situ regeneration of the fuel. The present self‐standing spiral‐shaped MFC will eliminate the challenges associated with two inlet membrane‐less fuel cells and has the potential to scale up for commercial application in portable energy generation.     

Computation of entropy generation in dissipative transient natural convective viscoelastic flow

Entropy generation is an important aspect of modern thermal polymer processing optimization. Many polymers exhibit strongly non‐Newtonian effects and dissipation effects in thermal processing. Motivated by these aspects in this study, a numerical analysis of the entropy generation with viscous dissipation effect in an unsteady flow of viscoelastic fluid from a vertical cylinder is presented. The Reiner‐Rivlin physical model of grade 2 (second‐grade fluid) is used, which can envisage normal stress variations in polymeric flow‐fields. Viscosity variation is included. The obtained governing equations are resolved using implicit finite difference method of Crank‐Nicolson type with well imposed initial and boundary conditions. Key control parameters are the second‐grade viscoelastic fluid parameter (), viscosity variation parameter (), and viscous dissipation parameter (). Also, group parameter (), Grashof number (Gr), and Prandtl number (Pr) are examined. Numerical solutions are presented for steady‐state flow variables, temperature, time histories of friction, wall heat transfer rate, entropy, and Bejan curves for distinct values of control parameters. The results specify that entropy generation decreases with augmenting values of , , and Gr. The converse trend is noticed with increasing Pr and . Furthermore, the computations reveal that entropy and Bejan lines only occur close to the hot cylinder wall.     

Bi2MoO6 hierarchical microflowers for electrochemical oxygen evolution reaction

Solvothermal Bi₂MoO₆ hierarchical microflowers synthesis has been successfully attempted. Methanol, ethanol and isopropanol have been mediated to synthesize three kinds of Bi₂MoO₆ hierarchical microflowers. Highly oriented (311) plane growth of orthorhombic Bi₂MoO₆ hierarchical microflowers have been confirmed. Interstitial vacancies and its role on electrochemical activity have been extensively discussed. Electrode fabrication was constructively done by using Ni foam substrate. Half cell arrangement of each electrode in alkaline medium has been designed to measure the electrochemical activity towards water oxidation. High current density of 356 mA/cm² was afforded by Bi₂MoO₆ hierarchical microflowers mediated by ethanol solvent during synthesis. Low Tafel slope value of 43 mV/dec has been reported to obtain 10 mA/cm² current density. Higher conductivity long with very good electron transportation has been achieved and is also adapted for 12 h long time stability test and achieved 86% of retention in its performance. Hence, optimally prepared Bi₂MoO₆ hierarchical microflowers could be an efficient electrode for clean energy fabrication.     

Dynamic coupled thermoelastic problems in micropolar theory—I

General solution of the dynamic micropolar coupled thermoelastic equations has been obtained for arbitrary distribution of body forces, body couples and heat sources in an infinite body by the use of Laplace-Fourier transforms. Short time solutions have been obtained for the cases of impulsive body force, body couple and heat source acting at a point. The corresponding classical coupled thermoelastic solutions have been derived by letting the parameter α approach zero. Some numerical results have been illustrated graphically.     

Colour centres and thermally stimulated luminescence of Na2ZnCl4

Thermally stimulated luminescence (TSL) of Na₂ZnCl₄ single crystals showed three glow peaks having their peak maxima at 343, 425 and 475 K. Optical absorption (OA) data of unirradiated samples revealed an absorption band at 272 nm while X-irradiation caused additional bands at 462 and 723 nm. Growth and room temperature annealing studies of TSL and OA supported the idea of attribution of 425 K glow peak and 462 nm absorption band to F-centres. The 272 nm OA band is due to Zn²⁺ centres whereas the 723 nm absorption band and 475 K glow peak have been assigned to Zn⁺ centres.     

Experimental Studies on Damage Growth in Composites under Dynamic Loads

Experimental investigations have been carried out to study the dynamic damage growth in glass/polyester composites. Detonation of two PETN explosive charges on a modified single edge notch (MSEN) specimen provides the dynamic load in the form of a planar tensile wave. High speed photography is used to record the dynamic damage events. The results show that damage grows perpendicular to the loading direction, similar to the static growth; the damage zone splits analogous to the crack branching in unreinforced polyester. The damage propagation velocity in a composite is higher than the crack propagation velocity in polyester resin. The damage area grows at an average rate of 4.3 m²/sec. Static experiments show that about 4 percent of the total energy is spent on the fiber-matrix interface debonding. The damage zone under dynamic loads is much higher than under static loads.     

Properties of solids under high pressure—An electronic band structure approach

The predicting capability of various parameters related to solids by performing their high pressure electronic band structures is discussed in detail. The studies on ground state crystal structure, magnetic structure and magnetic phase transitions under pressures,s-d electron transitions, bulk modulus, Debye temperature, elastic constants, insulator to metal transitions and the phenomenon of pressure induced superconductivity will be discussed with examples. Especially the method of calculating the Debye temperature for a large number of ternary charlcopyrite systems using their recently evaluated band structure will be presented. The limitations of the band theory when used with the local density approximation with respect to the determination of band gaps and magnetic properties will also be discussed.