Effect of incorporation of hafnium diboride nanofibers on thermomechanical properties of carbon fiber–phenolic composites

Carbon fiber/phenolic (C/Ph) composites were modified with different weight ratios of hafnium diboride (HfB₂) nanofibers to apperceive thermomechanical properties of C/Ph–Hf nanocomposites. Mechanical properties, thermal stability, and ablation resistance of C/Ph–Hf nanocomposites were found to be optimum when the weight percentage of HfB₂ was equal to one. Maximum flexural strength and modulus were obtained with 118 MPa and 1.9 GPa for C/Ph–1%Hf nanocomposite, respectively. Increasing the proportion of HfB₂, by delaying the temperature of thermal degradation of nanocomposites, enhanced the thermal stability and residual of C/Ph–Hf relative to C/Ph in both nitrogen and air environments. In the oxyacetylene flame test at 2500°C for 160 s, the optimum mass ablation rate of C/Ph–1%Hf nanocomposites was found to be 0.0150 g/s compared to 0.068 g/s for blank C/Ph, along with reducing the back surface temperature by 51%. The ablation mechanism of C/Ph–Hf nanocomposites after the oxyacetylene torch test was concluded from the derivations obtained from X-ray diffraction, energy dispersion spectroscopy, and microstructure analyses. These clarified that the formation of high-temperature species, such as HfO₂, HfC, and B₄C owing to oxidation of HfB₂ and subsequent reaction products with char, resulted in an increased ablation resistance of the nanocomposites.     

Role of hormonal and environmental factors on early incidence of breast cancer in Iran

Although the probability of having breast cancer increases with the age in general, this malignancy affects Iranian women at least one decade younger than their counterparts in other countries. However the underlying risk factors for the discrepancy have not been identified. The aryl hydrocarbon receptor (AhR) mediates the effects of many environmental endocrine disruptors and contributes to the loss of normal ovarian function in polluted environments. This study was aimed to compare the interactions between AhR and other fundamental genes (p53, K-Ras, ER, PgR) in a clinical setting. To conduct the immunohistochemical studies using appropriate monoclonal antibodies, 25 premenopausal invasive ductal carcinoma, 29 postmenopausal invasive ductal carcinoma and 30 breast fibroadenoma were selected retrospectively from 2004 to 2007 in the pathology department of Imam Khomeini hospital complex of Tehran University of Medical Sciences . Higher levels of AhR in epithelial cells of premenopausal patients and breast fibroadenoma emphasized the susceptibility of these cells to environmental-induced tumors. AhR overexpression contributed to ER-/PgR-immunophenotype in young/premenopausal patients but the same pattern was not observed in benign and postmenopausal malignant tumors. It seems that early incidence of breast cancer in Iran is the result of interactions between hormonal and environmental factors.     

Recovery of discarded sulfated lead-acid batteries

The aim of this research is to recover discarded sulfated lead-acid batteries. In this work, the effect of two methods (inverse charge and chemical charge) on the reactivation of sulfated active materials was investigated. At the inverse charge, the battery is deeply discharged and the electrolyte of battery is replaced with a new sulfuric acid solution of 1.28 g cm⁻³. Then, the battery is inversely charged with constant current method (2 A for the battery with the nominal capacity of 40 Ah) for 24 h. At the final stage, the inversely charged battery is directly charged for 48 h. Through these processes, a discarded battery can recover its capacity to more than 80% of a similar fresh and non-sulfated battery.At the chemical charge method, there are some effective parameters that including ammonium persulfate [(NH₄)₂S₂O₈] concentration, recovery temperature and recovery time. The effect of all parameters was optimized by one at a time method. The sulfated battery is deeply discharged and then, its electrolyte was replaced by a 40% ammonium persulfate solution (as oxidant) at temperature of 50 °C. By adding of oxidant solution, the chemical charging of positive and negative plates was performed for optimum time of 1 h. The chemically charged batteries were charged with constant voltage method (2.66 V for the battery with nominal voltage and nominal capacity of 2 V and 10 Ah, respectively) for 24 h. By performing of these processes, a discarded battery can recovers its capacity to more than 84% of the similar fresh and non-sulfated battery. Discharge and cyclelife behaviors of the recovered batteries were investigated and compared with similar healthy battery. The morphology and structure of plates was studied by scanning electron microscopy (SEM) before and after recovery.     

Intermittent water supply systems: causal factors,problems and solution options

Intermittent water supply systems are characterised by schedules that subject water consumers to less than 24 hours a day or less than 7 days of water supply a week. Causes and problems of water supply intermittency and their management options are generally discussed in isolation. This obscures challenges involved in minimising intermittency problems. Through reviewing of the literature relevant to intermittency causal factors, problems and their solution options, this paper finds that the interplay between political, social, economic, natural and technical factors, as they contribute to the development and sustenance of water supply intermittency, calls for interdisciplinary approaches to resolving the problems. These approaches will facilitate understanding of the challenges and development of integrated sustainable interventions. Where water resources are abundant, these interventions should involve conversion from intermittent to continuous supply as the ultimate option to handling supply intermittency problems. For this, development of systematic conversion procedures is recommended.     

Synthesis of Ni(II)-3,5-dichloro-2-hydroxybenzenesulfonyl chloride supported SBA-15 and its application as a nanoreactor catalyst for the synthesis of diaryl sulfides via reaction of aryl halides with thiourea or S<Subscript>8</Subscript>

In the present work, SBA-15 mesoporous grafted with 3-(trimethoxysilyl)-1-propanethiol as a linker and subsequently reacted by 3, 5-dichloro-2-hydroxybenzenesulfonyl chloride. Then to obtain the new catalyst Ni(II) was supported on functionalized SBA-15 by using Ni(NO₃)₂ as Ni(II) source. The Ni/SBA-15 catalyst was characterized with SEM, EDS, ICP, XRD, TGA, FT-IR and N₂ sorption–desorption analysis. The key advantages of this heterogeneous catalyst are inexpensive, short reaction times, excellent yields, recovery and reusability.     

Optimum Design and Management of Pressurized Branched Irrigation Networks

The scarcity of water resources is the driving force behind modernizing irrigation systems in order to guarantee equal rights to all beneficiaries and to save water. Traditional distribution systems have the common shortcoming that water must be distributed through some rotational criteria. This type of distribution is necessary to spread the benefits of scarce resources. Irrigation systems based on on-demand delivery scheduling offer flexibility to farmers and greater potential profit than other types of irrigation schedules. However, in this type of irrigation system, the network design has to be adequate for delivering the demand during the peak period whilst satisfying minimum pressure constraints along with minimum and maximum velocity constraints at the farm delivery points (hydrants) and in the pipes, respectively. In this paper, optimum design and management of pressurized irrigation systems are considered to be based on rotation and on-demand delivery scheduling using a genetic algorithm. Comparison is made between the two scheduling techniques by application to two real irrigation systems. Performance criteria are formulated for the optimum design of a new irrigation system and better management of an existing irrigation system. The design and management problems are highly constrained optimization problems. Special operators are developed for handling the large number of constraints in the representation and fitness evaluation stages of the genetic algorithm. The performance of the developed genetic algorithm is assessed in comparison to traditional optimization techniques. It is shown that the methodology developed performs better than the linear programming method and that solutions generated by the modified genetic algorithm show an improvement in capital cost. The method is also shown to perform better in satisfying the constraints. Comparison between on-demand and rotation delivery scheduling shows that a greater than 50% saving can be achieved in total cost at the cost of reducing flexibility in the irrigation time. Finally, it is shown that minimizing standard deviation of flow in pipes does not result in the best distribution, and therefore minimum cost, neither for systems with uniform flows or those with large variations in discharge at hydrants.     

Low Temperature Carbothermal Reduction Synthesis of ZrC Nanofibers via Cyclized Electrospun PVP/Zr(OPr)4 Hybrid

The fabrication capability of zirconium carbide (ZrC) nanofibers by a novel polymeric solution was examined using electrospinning method. The electrospinnable solution was prepared from the reaction of zirconium n‐propoxide (Zr(OPr)₄) with acetylacetone and acetic acid followed by the addition of polyvinylpyrrolidone (PVP) solution. By utilizing thermal and microstructural analyses such as differential scanning calorimetry–thermogravimetry (DSC–TG), field emission scanning electron microscopy (FE‐SEM), transmission electron microscopy (TEM), X‐ray diffraction (XRD), and Brunauer–Emmett–Teller (BET), the effect of heat treatment type on the morphology and crystallinity of as‐spun PVP/Zr(OPr)₄ hybrid fibers was examined. The results showed that direct carbonization treatment of as‐spun fibers under argon atmosphere led to spherical ZrC aggregates in lack of fibrillar morphology, whereas carbonization coupled with cyclization could be recognized as the unique template to govern the morphology and crystallinity of ZrC nanofibers. Carbonization of the cyclized fibers at 1550°C in flowing argon atmosphere produced the thick, fragmented rosary‐like fibers with a diameter of 357 nm, while through a 100°C decrease in carbonization temperature to 1450°C, the thin, smooth, long, and uniform ZrC nanofibers with 176 nm diameter and a medium surface area of 23 m²/g were obtained.     

Self-Adaptive Fitness Formulation for Evolutionary Constrained Optimization of Water Systems

In design of water distribution networks, there are several constraints that need to be satisfied; supplying water at an adequate pressure being the main one. In this paper, a self-adaptive fitness formulation is presented for solving constrained optimization of water distribution networks. The method has been formulated to ensure that slightly infeasible solutions with a low objective function value remain fit. This is seen as a benefit in solving highly constrained problems that have solutions on one or more of the constraint bounds. In contrast, solutions well outside the constraint bounds are seen as containing little genetic information that is of use and are therefore penalized. In this method, the dimensionality of the problem is reduced by representing the constraint violations by a single infeasibility measure. The infeasibility measure is used to form a two-stage penalty that is applied to infeasible solutions. The performance of the method has been examined by its application to two water distribution networks from literature. The results have been compared with previously published results. It is shown that the method is able to find optimum solutions with less computational effort. The proposed method is easy to implement, requires no parameter tuning, and can be used as a fitness evaluator with any evolutionary algorithm. The approach is also robust in its handling of both linear and nonlinear equality and inequality constraint functions. Furthermore, the method does not require an initial feasible solution, this being an advantage in real-world applications having many optimization variables.     

The effects of S-doping concentration on the photocatalytic performance of SnSe/S-GO nanocomposites

The effects of S-doped graphene oxide (S-GO) on the photocatalytic performance of SnSe nanostructures have been investigated. Different concentrations of S-doping as 2S-GO, 4S-GO, and 6S-GO (2, 4, and 6% in weight) have been synthesized. Characterization results indicated sulfur not only has successfully placed in the GO structure and a part of the GO sheet has been changed into reduced GO (rGO) by sulfur doping but also the surface morphology of the GO sheets has been changed from a smooth surface to fractured crack surfaces. The results showed that the increase of sulfur content caused the morphology of the SnSe nanostructures was changed from nanoparticles (NPs) into nanorods (NRs). The photocatalytic activity of the samples to degrade dyes under the visible-light irradiation conditions was carried out and it was observed an enhancement photocatalytic performance for the SnSe/2S-rGO nanocomposites in comparison to the other samples. More than 95% of dyes were degraded by the SnSe/2S-rGO nanocomposites for only 60 min. Brunauer–Emmett–Teller (BET) and electrical measurement results indicated the textural properties and conductivity of GO sheets were improved by sulfur doping. In addition, the photogenerated electron lifetime (τ_r) of the SnSe/rGO and SnSe/S-rGO nanocomposites has been measured by the Bode phase plot and it was observed a lifetime of τ_r = 71.1 and 31.7 μs for the SnSe/S-rGO and SnSe/rGO nanocomposites, respectively.