Implicit and explicit alcohol-related cognitions in heavy and light drinkers.

Implicit and explicit alcohol-related cognitions were measured in 2 dimensions: positive-negative (valence) and arousal-sedation, with 2 versions of the Implicit Association Test (IAT; A. G. Greenwald, D. E. McGhee, & J. L. Schwartz) and related explicit measures. Heavy drinkers (n = 24) strongly associated alcohol with arousal on the arousal IAT (especially men) and scored higher on explicit arousal expectancies than light drinkers (n = 24). On the valence IAT, both light and heavy drinkers showed strong negative implicit associations with alcohol that contrasted with their positive explicit judgments (heavy drinkers were more positive). Implicit and explicit cognitions uniquely contributed to the prediction of 1-month prospective drinking. Heavy drinkers' implicit arousal associations could reflect the sensitized psychomotor-activating response to drug cues, a motivational mechanism hypothesized to underlie the etiology of addictive behaviors. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Does Social Capital Affect Residents' Propensity to Move from Restructured Neighbourhoods?

Many Dutch post-war neighbourhoods are subject to intensive urban restructuring. Demolition and new housing construction combined with social and economic programmes should improve the housing stock, liveability and social capital. Currently, it is unknown whether social capital contributes to residential stability and reduces residents' propensity to move. In this paper, social capital levels of stayers, movers and newcomers are studied in two recently restructured neighbourhoods in Rotterdam, The Netherlands. Using survey data, social capital is operationalised as benefits of everyday cursory interactions, trust, shared norms and collective action. Logistic regression analysis shows that age, length of residency, employment, income, dwelling satisfaction, dwelling type and perceived neighbourhood quality significantly predict residents' propensity to move. Newcomers are more inclined to move again than stayers and other movers. Social capital is of less importance than suggested by previous research; housing features, satisfaction and neighbourhood perception affect residents' propensity to move much more strongly. The paper concludes with policy implications and suggestions for future research.     

Same wording, distinct concepts? Testing differences between expectancies and motives in a mediation model of alcohol outcomes.

Per definition, alcohol expectancies (after alcohol I expect X), and drinking motives (I drink to achieve X) are conceptually distinct constructs. Theorists have argued that motives mediate the association between expectancies and drinking outcomes. Yet, given the use of different instruments, do these constructs remain distinct when assessment items are matched? The present study tested to what extent motives mediated the link between expectancies and alcohol outcomes when identical items were used, first as expectancies and then as motives. A linear structural equation model was estimated based on a national representative sample of 5,779 alcohol-using students in Switzerland (mean age = 15.2 years). The results showed that expectancies explained up to 38% of the variance in motives. Together with motives, they explained up to 48% of the variance in alcohol outcomes (volume, 5+ drinking, and problems). In 10 of 12 outcomes, there was a significant mediated effect that was often higher than the direct expectancy effect. For coping, the expectancy effect was close to zero, indicating the strongest form of mediation. In only one case (conformity and 5+ drinking), there was a direct expectancy effect but no mediation. To conclude, the study demonstrates that motives are distinct from expectancies even when identical items are used. Motives are more proximally related to different alcohol outcomes, often mediating the effects of expectancies. Consequently, the effectiveness of interventions, particularly those aimed at coping drinkers, should be improved through a shift in focus from expectancies to drinking motives. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The influence of surface-active agents on the mass transfer from gas bubbles in a liquid—I

The influence of surface-active agents on the mass transfer coefficient can be classed under three dimensionless parameters: Re, Ca, and De. From this classification, which is represented in a table, it follows whether the interface of the bubble is rigid, free, or of an intermediate nature. The mass transfer coefficient can be calculated with the aid of known equations. The whole is checked against data from the literature.     

A quantitative determination of tocotrienols and tocopherols in palm oil by TLC-GLC

A reliable analytical method is required for determining tocopherols and tocotrienols in palm oil and palm oil fractions. This paper describes a TLC/GLC method which distinguishes between these compounds and is based on their separations from palm oils by saponification and TLC, followed by direct GLC analysis. Dedicated to professor E. Havina on the occasion of his retirement from the State University of Leyden, The Netherlands     

Late re-interventions following arterial switch operations in transposition of the great arteries. Incidence and surgical treatment of postoperative pulmonary stenosis

Seventy-six patients were studied after arterial switch operation (ASO) between May 1977 and February 1992. Pulmonary artery reconstruction was initially performed by: conduit interposition in 5 patients, direct main pulmonary artery anastomosis and button patches in 60 patients, and pantaloon-like patch repair in 11 patients. Pulmonary stenosis developed in 17 patients (22%), requiring a total of 26 late re-interventions. Re-intervention was required in four out of five patients operated with pulmonary artery conduits, 11 out of 60 with a button patch repair and 2 out of 11 following pantaloon-type repair. In this series pulmonary artery stenosis (PS) involving the pulmonary valve occurred in 9/17 patients. Involvement of the pulmonary valve was related to the technique of pulmonary artery reconstruction. In these patients surgery is necessary. Balloon angioplasty can be a valuable tool when the stenosis is more distal. The incidence of PS was not influenced by the type of reconstruction or the use of Lecompte's maneuver.     

Current and future trends of additive manufacturing for chemistry applications: a review

Three-dimensional (3-D) printing, also known as additive manufacturing, refers to a method used to generate a physical object by joining materials in a layer-by-layer process from a three-dimensional virtual model. 3-D printing technology has been traditionally employed in rapid prototyping, engineering, and industrial design. More recently, new applications continue to emerge; this is because of its exceptional advantage and flexibility over the traditional manufacturing process. Unlike other conventional manufacturing methods, which are fundamentally subtractive, 3-D printing is additive and, therefore, produces less waste. This review comprehensively summarises the application of additive manufacturing technologies in chemistry, chemical synthesis, and catalysis with particular attention to the production of general laboratory hardware, analytical facilities, reaction devices, and catalytically active substances. It also focuses on new and upcoming applications such as digital chemical synthesis, automation, and robotics in a synthetic environment. While discussing the contribution of this research area in the last decade, the current, future, and economic opportunities of additive manufacturing in chemical research and material development were fully covered.

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LCA of second generation bioethanol: A review and some issues to be resolved for good LCA practice

This paper aims at reviewing the life cycle assessment (LCA) literature on second generation bioethanol based on lignocellulosic biomass and at identifying issues to be resolved for good LCA practice. Reviews are carried out on respective LCA studies published over the last six years. We use the classification of lignocellulosic biomass to define system boundaries, so that the comparison among LCA results can be thoroughly assessed based on identified system components. A basis for attributing environmental burden for different biomass feedstocks is also suggested. Despite the non-homogeneous systems, we conclude that second generation bioethanol performs better than fossil fuel at least for the two most studied impact categories, net energy output and global warming. For the latter category, carbon sequestration at the biomass generation stage can even consistently offset the GHG emissions from all parts of the life cycle chains at high ethanol percentage (≥85%). The aspect of biogenic carbon and agrochemical input for energy crops and biomass residues, and the effect of removal of the latter from soil have not been treated consistently. In contrast, the exclusion of upstream chain of biomass waste feedstocks is observed in practice. The bioethanol conversion process is mostly based on simultaneous saccharification and co-fermentation, characterized by high yield and low energy input. In this regard, the LCA results tend to under estimate the real impacts of the current technology. The choice of allocation methods strongly influences the final results, particularly when economic value is used as a reference. Substitution of avoided burden seems to be the most popular allocation method in practice, followed by partition based on mass, energy, and economic values.