新试剂2－（6－甲基－2－苯并噻唑偶氮）－5－二乙氨基酚分光光度法测定微量镍

本文报道用新试剂２－（６－甲基－２－苯并噻唑偶氮）－５－二乙氨基酚（ＭＢＴＡＥ）分光光度法测定微量镍。Ｎｉ：ＭＢＴＡＥ＝１：２，ε＝８．１×１０４Ｌ／ｍｏｌ·ｃｍ，Ｎｉ２＋浓度在０～２２μｇ／２５ｍＬ范围内服从比尔定律。用于金属有机化合物中微量镍的测定，结果与理论值相符。     

塑料管材用于干式地板供热、供冷的可行性研究

据塑料管材的力学性能，针对其应用于地板供热、供冷时应注意的问题，从塑料管材使用条件、管材的选择、管壁厚度的确定、地板结构、介质作用温度及供热、供冷运行方式等方面对塑料管材应用于供热、供冷的可行性进行了探讨，提出了一些相应措施和技术方案，并给出了实例。     

Program verification and testing technologies

Program verification and testing techniques are crucial in fruitfully analyzing and validating complex software systems. This is an active research area and has produced various promising techniques in the last decade. However, many challenges lie ahead. We review the research area and summarize six papers selected from the Sixth International Symposium on Theoretical Aspects of Software Engineering (TASE 2012).     

Echo state networks based predictive model of vinyl chloride monomer convention velocity optimized by artificial fish swarm algorithm

Conversion rate in the Polyvinylchloride (PVC) polymerizing process has a certain influence on the molecular weight of PVC, porosity, absorption rate of plasticizer, vinyl chloride monomer (VCM) residue and thermal stability. Therefore, a predictive model based on echo state networks (ESN) method optimized by the artificial fish swarm algorithm (AFSA) is proposed to predict the conversion velocity. Firstly, the hot balancing mechanisms of polymerizer and the influenced factors of convention rate of VCM are analyzed in details. Then the auxiliary variables of the predictive model kernel are selected by using the kernel principal component analysis method for reducing the model dimensionality. Thirdly, the structure parameters of the ESN are optimized by the AFSA to realize the nonlinear mapping between input and output variables of the discussed soft-sensor model. The artificial fish swarm behaviors, such as foraging, swarming, chasing, random, are introduced in details. Finally, simulation results show that the proposed model can significantly enhance the predictive accuracy and robustness of the technical index and satisfy the real-time control requirements of PVC polymerizing production process.     

Terrain‐inclination‐based Three‐dimensional Localization for Mobile Robots in Outdoor Environments

A new terrain‐inclination‐based localization technique is proposed in this paper to enable a robot to identify its three‐dimensional location relative to measurable terrain inclinations. Given a topographical map and a planned path, a robot‐terrain‐inclination model (RTI model) is extracted along the path on the terrain upon which the robot is operating. A particle filter is then used to fuse the measurement data with the robot motion based on the extracted RTI model for either a three‐wheeled or a four‐wheeled mobile robot. Experiments were carried out in four outdoor scenarios: one short path with different initial conditions and map resolution, another short path with different surface roughness and sensor accuracy, and two long paths with different types of rigid terrains and multiple loops. Experimental results show that the proposed method could achieve good localization performance on inclined outdoor terrains.     

超高交联树脂吸附处理2,4-D含酚废水的研究

采取超高交联树脂NDA-150吸附处理2,4-二氯苯氧乙酸含酚生产废水,取得了良好的效果。通过静态吸附比较和动态吸附-脱附研究,确定了最佳工艺参数。原废水呈深红褐色,总酚质量浓度>16000mg/L,树脂吸附后出水无色透明,总酚质量浓度<0.5mg/L,达到国家排放标准。原废水酸化和高浓脱附液酸化处理,能回收大量的2,4-二氯酚和2,4-二氯苯氧乙酸。该工艺简单,操作方便,是一项具有环境效益和经济效益,值得推广的技术。     

Novel Method To Optimize the Structure of Reticulated Porous Ceramics

A novel method has been developed for the fabrication of silicon nitride reticulated porous ceramics (RPCs) with regulated structure, using polyurethane sponge as the template. This technique includes two centrifuging steps. In the first stage, the polyurethane sponges are coated with thin slurry through high-speed centrifuging. After the slurry on sponges dried, a high-strength green body without filled cells is obtained. In the second stage, because of improved adhesion between the body and the slurry after the first coating, the body with uniformly thick strut is produced by recoating the as-prepared green body with thixotropic slurry and centrifuging again. The loading content of slurry and the pore diameter of the RPCs body greatly depend on the slurry viscosity in the process of recoating. The strut diameter and pore diameter of the RPCs are effectively optimized by modulating the slurry viscosity.     

岩盐溶解速率的研究

在岩盐溶解速率及其影响因素的实验研究基础上,建立了岩盐溶解速率的计算公式。研究的结果可为岩盐开采和其他水溶法矿物开采提供参考。     

Synthesis of water-soluble single-walled carbon nanotubes by RAFT polymerization

Water-soluble single-walled carbon nanotubes (SWNTs) were synthesized by grafting poly(acrylamide) (PAM) from the surface of SWNT via reversible addition-fragmentation chain transfer (RAFT) polymerization. The RAFT agents were covalently attached to the SWNTs by functionalizing SWNTs with in situ generated diazonium compounds. The product was characterized by means of FT-IR, Raman, ¹H NMR, TGA and TEM. The results showed that PAM chains had successfully grafted from SWNT by RAFT polymerization. The amount of PAM grown from SWNT increased with the polymerization time. The acrylamide conversion increased linearly with the polymerization time, indicating the “living” characteristics of the RAFT polymerization. TEM was utilized to image PAM-g-SWNT, showing relatively uniform polymer coatings present on the surface of individual, debundled nanotubes.     

再结晶法制备高纯超细Al2O3粉的研究

本文介绍了用一种再结晶技术制造高炖、超细Al_2O_3粉体的新方法。 将硫酸铝铵溶液(AA)滴入碳酸氢铵溶液(AHC),经过反应合成一种新的含铝化合物,碳酸氢铝铵(AACH),然后在高温下煅烧,生成超细Al_2O_3粉体。另外还采用了X射线,红外光谱,DTA,以及TEM等手段,研究了反应温度、浓度、PH值和老化条件等对生成物AACH和Al_2O_3的影响。