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61.
Adriel Bortolin Fauze A. Aouada Márcia R. de Moura Caue Ribeiro Elson Longo Luiz H. C. Mattoso 《应用聚合物科学杂志》2012,123(4):2291-2298
This article studied the applicability of poly(acrylamide) and methylcellulose (PAAm‐MC) hydrogels as potential delivery vehicle for the controlled‐extended release of ammonium sulfate (NH4)2SO4 and potassium phosphate (KH2PO4) fertilizers. PAAm‐MC hydrogels with different acrylamide (AAm) and MC concentrations were prepared by a free radical polymerization method. The adsorption and desorption kinetics of fertilizers were determined using conductivity measurements based on previously built analytical curve. The addition of MC in the PAAm chains increased the quantities of (NH4)2SO4 and KH2PO4 loaded and extended the time and quantities of fertilizers released. Coherently, both loading and releasing processes were strongly influenced by hydrophilic properties of hydrogels (AAm/MC mass proportion). The best sorption (124.0 mg KH2PO4/g hydrogel and 58.0 mg (NH4)2SO4/g hydrogel) and desorption (54.9 mg KH2PO4/g hydrogel and 49.5 mg (NH4)2SO4/g hydrogel) properties were observed for 6.0% AAm–1.0% MC hydrogels (AAm/MC mass proportion equal 6), indicating that these hydrogels are potentially viable to be used in controlled‐extended release of fertilizers systems. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
62.
Rafael Mattos Deus Rosane Aparecida Gomes Battistelle Gustavo Henrique Ribeiro Silva 《Clean Technologies and Environmental Policy》2017,19(1):205-214
As achieving Brazil’s National Policy on Solid Waste-based goals effectively is not simple, there are alternatives such as intermunicipal cooperation by consortium or privatization. Therefore, this study aimed to evaluate the Greenhouse Gas emissions and energy use of six scenarios in two landfills contexts (private and consortium) for small municipalities (less than 100,000 inhabitants as per Brazilian standards) located in São Paulo, Brazil. Through the technique of scenario building and method of Waste Reduction Model was possible to obtain the total energy, the amount of carbon dioxide equivalent (CO2E) and carbon equivalent (CE) emissions. The best scenario integrates composting and recycling, reducing 72 % for CO2E and CE emissions, and saving about 410 % in energy. The landfill consortium will only take advantage, if the location is the most ideal as far as possible. Small municipalities that do not dispose their waste in landfills compatible with regulatory standards may seek for intermunicipal cooperation and adopt integrated waste-management programmes to reduce their environmental impacts. 相似文献
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Alexandre Antunes Ribeiro Rodrigo Fernando Costa Marques Antônio Carlos Guastaldi João Sinézio de Carvalho Campos 《Journal of Materials Science》2009,44(15):4056-4061
Many techniques have been used to coat metallic substrate with bioceramics. The aim of this study was to study the physical-chemical
characteristics of polyvinylidene fluoride (α-PVDF)/hydroxyapatite (HA) composite coating, obtained by casting method, on
commercially pure titanium (α-CP Ti) substrate surface modified by laser beam irradiation. The preparation of coating was
done for mixing α-PVDF pellets shape dissolved in dimethylacetamide (DMA) with HA/DMA emulsion. The mixture was poured onto
the α-CP Ti sample and left to dry in an oven. CP Ti plates were coated with α-PVDF/HA composite film, in proportions of 100/00
and 60/40 in weight, and characterized by particle size analysis, scanning electron microscopy, energy dispersive spectroscopy
(EDS), X-ray diffractometry, thickness measurement and contact angle. Uniform coating with a small thickness variation along
the coated surface was successfully obtained. 相似文献
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Maurilio Toscano de Lucena Mário Ribeiro de Melo Júnior Mariana Montenegro de Melo Lira Célia Maria Machado Barbosa de Castro Leonardo Aguiar Cavalcanti Mariana Arruda de Menezes Flávia Cristina Morone Pinto José Lamartine de Andrade Aguiar 《Journal of materials science. Materials in medicine》2015,26(2):82
The development of a skin substitute suitable for immediately performing the function of the lost dermis and epidermis could result in a positive impact on the treatment of patients with extensive skin lesions. A biopolymer film was applied to skin wounds to investigate the biocompatibility and cutaneous reaction and to test its activity as a mechanical barrier and conductor in the healing process. Forty Wistar rats of both sexes were used in the present study. Two excisions were performed in the dorsal part of the skin flaps. The polysaccharide film was applied over one of the incisions and other incision was washed with saline. The time spent for complete healing of both lesions was virtually the same in both groups, during 21 days of observation. The film remained attached to the bed of the exposed wound for an average period of 6 days. There were no statistically significant differences with regard to lesion measurement area at assessment times of 2nd, 7th and 14th postoperative days. At day 21, the scar area showed a significant difference (0.0229). After 40 days, all wounds were completely healed. No statistically significant differences were found between the histological parameters assessed in the experimental and control groups. The cellulosic polysaccharide film integrated well with the tissue showing high biocompatibility and low skin reactivity. 相似文献
68.
Soraya Mendes de Souza Lineu Jose Pedroso Paulo Marcelo Vieira Ribeiro 《土木工程与建筑:英文版》2013,(9):1111-1117
Problems of fluid structure interactions are governed by a set of fundamental parameters. This work aims at showing through simple examples the changes in natural vibration frequencies and mode shapes for wall-cavity systems when the structural rigidity is modified. Numerical results are constructed using ANSYS software with triangular finite elements for both the fluid (2D acoustic elements) and the solid (plane stress) domains. These former results are compared to proposed analytical expressions, showing an alternative benchmark tool for the analyst. Very rigid wall structures imply in frequencies and mode shapes almost identical to those achieved for an acoustic cavity with Neumann boundary condition at the interface. In this case, the wall behaves as rigid and fluid-structure system mode shapes are similar to those achieved for the uncoupled reservoir case. 相似文献
69.
This paper introduces the innovative system used in the reconstruction of Lisbon after the 1755 earthquake. Its findings are based on original documents that offer a detailed picture of the principles and methods established to convert the land and properties of the old city into the new and standardized gridded Plan. Implemented in the mid‐eighteenth century, the methodical system outlined was, undoubtedly, an important point of reference for the large‐scale urban improvement and redevelopment operations that would follow in nineteenth‐century Europe. 相似文献
70.
João P. F. Mota Viviane G. P. Ribeiro Fernando L. F. da Silva Antônio E. C. Junior Davi R. Oliveira Lloyd R. V. Kotzebue 《分离科学与技术》2016,51(14):2473-2483
The present work made a comparative study between two purification methods, column chromatography and recrystallization, for compounds derived from cardanol, a by-product of the cashew industry (Anacardium occidentale L.). The compounds were successfully synthesized and characterized, focusing our attention to results obtained in terms of yield, purity, generation of solid waste and amount of solvent used in each purification process. For all the synthesized compounds, the amount of solvent used was greatly reduced in the recrystallization process, with purities above 80%, when compared to chromatographic column, which still demands high amounts of eluent. 相似文献