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61.
The investigation and assessment of the oil content of oilseeds are important criteria, especially for the oil milling trade.
Standard methods for the determination of the oil content of oilseeds are very time consuming, with extraction periods of
4 to 8 h. Three different oilseeds—rapeseed, sunflower, and soybean—are extracted by supercritical fluid extraction (SFE),
accelerated solvent extraction, microwave-assisted extraction, solid fluid vortex extraction, and Soxtherm, and the results
are compared with the result of the German Fat Science Society (DGF) standard method B-I 5 (87). Besides, the extracts are
analyzed regarding the content of tocopherols as a parameter for mild extraction conditions and the content of diglycerides
and free fatty acids as parameters for the content of more polar lipids. The results of the determination of the oil content
under optimal conditions are comparable with the results of the DGF standard method B-I 5 (87). There are no significant differences
between the different methods. The content of tocopherols is dependent upon the extraction method and the type of oilseed.
The highest content is obtained by SFE. The content of diglycerides and free fatty acids varied according to the oilseed. 相似文献
62.
The processing of manganese nodules for the production of raw materials has been a subject of research for many decades. The nodules contain many valuable metals like copper, cobalt and nickel. In recent years, the German Federal Institute for Geoscience and Natural Resources developed a process for the processing of manganese nodules based on a combined pyro- and a hydrometallurgical route. Clausthal University of Technology was assigned to develop the hydrometallurgical process for the treatment of a FeNiCuCo alloy. The developed process consists of pressurized sulfuric acid leaching with the suppression of hydrogen gas formation, precipitation and solvent extraction. 相似文献
63.
Dr. Bettina Sommer Dr. Holger von Moeller Martina Haack Dr. Farah Qoura Clemens Langner Dr. Gleb Bourenkov Dr. Daniel Garbe Dr. Bernhard Loll Prof. Dr. Thomas Brück 《Chembiochem : a European journal of chemical biology》2015,16(1):110-118
Isobutanol is deemed to be a next‐generation biofuel and a renewable platform chemical. 1 Non‐natural biosynthetic pathways for isobutanol production have been implemented in cell‐based and in vitro systems with Bacillus subtilis acetolactate synthase (AlsS) as key biocatalyst. 2 – 6 AlsS catalyzes the condensation of two pyruvate molecules to acetolactate with thiamine diphosphate and Mg2+ as cofactors. AlsS also catalyzes the conversion of 2‐ketoisovalerate into isobutyraldehyde, the immediate precursor of isobutanol. Our phylogenetic analysis suggests that the ALS enzyme family forms a distinct subgroup of ThDP‐dependent enzymes. To unravel catalytically relevant structure‐function relationships, we solved the AlsS crystal structure at 2.3 Å in the presence of ThDP, Mg2+ and in a transition state with a 2‐lactyl moiety bound to ThDP. We supplemented our structural data by point mutations in the active site to identify catalytically important residues. 相似文献
64.
Gemini surfactants were synthesized by reaction of long-chain N-alkyl glucamines with epoxy resins. Analogous to the synthesis of gemini surfactns from long-chain N-alkyl glucamines and α, ω-diepoxides (1), the reaction in methanol at 70°C could be used to convert the starting materials
selectively and almost quantitatively. N-Octyl glucamine, N-decyl glucamine, and N-dodecyl glucamine were combined with several epoxy resins, mainly technical glycidyl ethers of diols. Syntheses involving
equimolar amounts of amine resulted in quantitative conversion of the epoxy resins, and epoxide and products could be isolated
quantitatively by removing the solvent. Gemini surfactants having hydrophobic or hydrophilic spacers were preparared according
to their structures and the hydrophilic properties of the epoxy resin. Surface tensions were measured, and foaming propertiers
were examined to characterize surface-active properties of these surfactants. The more hydrophilic products were of particularly
high surface activity. Tensiometric studies showed a reduction of surface tension to 30–34 mN/m and critical micelle concentrations
in the range of 2–35 mg/L. Comparison of gemini surfactants from long-chain N-alkyl glucamines and diepoxides of α,ω-diolefins (chain lengths: C8, C9, C10, and C14) with those based on epoxy resins showed similar or lower surface activities using hydrophobic epoxy resins and much better
surface-active properties using hydrophilic epoxy resins (e.g., based on glycerol). This, together with the easier availability,
makes the epoxy resin-based products interesting surfactants. Products having very good surface-active properties are available,
especially using glycidyl ether of aliphatic diols or glycerol. 相似文献
65.
Fredrik Berthold Kristina Gustafsson Rickard Berggren Elisabeth Sjholm Mikael Lindstrm 《应用聚合物科学杂志》2004,94(2):424-431
A method for the characterization of the molar mass distributions (MMDs) of softwood kraft pulps dissolved in 0.5% lithium chloride (LiCl)/N,N‐dimethylacetamide (DMAc) by size exclusion chromatography is presented. The method is based on derivatization with ethyl isocyanate and the dissolution of samples in 8% LiCl/DMAc. In this study, the derivatization of hardwood kraft pulps did not influence the MMD. In the case of softwood pulps, however, the derivatization decreased the proportion of the high‐molecular‐mass material and increased the proportion of the low‐molecular‐mass material, which resulted in a distribution similar to the MMD of a hardwood kraft pulp. The results suggest that associations between hemicellulose and cellulose in the softwood kraft pulp were ruptured during derivatization. This led to a more correct estimation of the MMD of derivatized softwood kraft pulps than obtained by the dissolution of nonderivatized samples. This new method offers several advantages over derivatization with phenyl isocyanate: a precipitation step is not necessary, it is possible to follow the lignin distribution in the samples, and the method allows very high levels of dissolution of softwood kraft pulps up to a κ number of around 50. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 424–431, 2004 相似文献
66.
Anna Schüller Daniel Matzner Dr. Christina E. Lünse Prof. Dr. Valentin Wittmann Dr. Catherine Schumacher Sandra Unsleber Prof. Dr. Heike Brötz‐Oesterhelt Prof. Dr. Christoph Mayer Prof. Dr. Gabriele Bierbaum Prof. Dr. Günter Mayer 《Chembiochem : a European journal of chemical biology》2017,18(5):435-440
The ever‐growing number of pathogenic bacteria resistant to treatment with antibiotics call for the development of novel compounds with as‐yet unexplored modes of action. Here, we demonstrate the in vivo antibacterial activity of carba‐α‐d ‐glucosamine (CGlcN). In this mode of action study, we provide evidence that CGlcN‐mediated growth inhibition is due to glmS ribozyme activation, and we demonstrate that CGlcN hijacks an endogenous activation pathway, hence utilizing a prodrug mechanism. This is the first report describing antibacterial activity mediated by activating the self‐cleaving properties of a ribozyme. Our results open the path towards a compound class with an entirely novel and distinct molecular mechanism. 相似文献
67.
68.
Flange forming is a process which is wide spread in macro range for blanks with thicknesses from less than 1?mm up to several millimeters. Flange formed geometries are used as preforms for threads but also as device to give guidance and contact face to bolts and axles in sheet metal. A great advantage of flange forming compared to other machining processes is low process cycle time combined with high material utilization. Thus, a reasonable repertoire of knowledge has been gained for flange forming in macro range. Due to ongoing miniaturization of today??s products, flange forming is an interesting process applicable in micro range as well whereas size effects do not generally allow transfer of process limits from macro to micro range. Therefore the maximum flaring ratio for flange forming in micro range for sheet metal foil of 10?C25???m for a stainless steel 1.4301 and Copper E-Cu58 is investigated and compared with results in macro range. It is shown that the maximum flaring ratio decreases with decreasing sheet metal thickness. The resulting flange heights of experiments are compared with theoretical estimations which show a good accordance. 相似文献
69.
Gerold M. Rangger Oliver T. Hofmann Benjamin Bröker Egbert Zojer 《Synthetic Metals》2010,160(13-14):1456-1462
A better understanding of metal-organic interfaces combined with means to control their properties is crucial for the further improvement of organic (opto)electronic devices. In this context, the use of organic acceptors is an efficient tool to modify metal work functions and hole-injection barriers, which has the potential to considerably improve the performance of organic devices. Here, we use density functional theory based calculations to discuss a particularly potent acceptor suitable for that purpose, 3,5-difluoro-2,5,7,7,8,8-hexacyanoquinodimethane (F2HCNQ), which clearly outperforms the frequently applied and in the meantime prototypical system 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4TCNQ). Comparative calculations for a single monolayer of the two molecules adsorbed on an Ag(1 1 1) surface reveal that (i) the work-function increase induced by F2HCNQ is more than 20% higher than for F4TCNQ and that (ii) at the same time the adsorption energy basically is unaffected, while (iii) the electronic structure is slightly modified. In the end of the day, F2HCNQ is a highly promising candidate for applications in organic devices. 相似文献
70.
D.G. Cram X.Y. Fang H.S. Zurob Y.J.M. Bréchet C.R. Hutchinson 《Acta Materialia》2012,60(18):6390-6404
A series of Cu–Sn alloys (pure Cu, Cu–0.2Sn, Cu–2Sn and Cu–5Sn) has been prepared to experimentally test the effect of solute on discontinuous dynamic recrystallization (DDRX) as a function of both temperature and strain rate. Hot compression tests were performed and the microstructure was characterized using optical and scanning electron microscopy. Solute additions tend to broaden the peak in the flow stress curve and increase the peak stress, peak strain and steady-state stress. A reduction in the DRX grain size and a retardation of the kinetics of recrystallization are observed with solute additions, although the effect saturates at 2Sn. A recently published, physically based model for DDRX of pure Cu has been extended to include the effect of solute. The effect on the plastic response of the material and the mobility of high-angle grain boundaries was incorporated and, through comparisons between experiment and simulated DRX phenomena, it is concluded that solute must also significantly affect the nucleation stage of DDRX. A model is developed for the effect of solute on the nucleation of DDRX in Cu–Sn alloys and comparisons with experiment indicate that the principal effects are well captured. Important areas for future work are discussed. 相似文献