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31.
Long-chain aliphatic α,ω-diols containing up to 32 consecutive methylene groups were synthesized by several methods and characterized. 1,22-Docosanediol HO-(CH2)22-OH and 1,32-dotriacontanediol HO-(CH2)32-OH both exhibited a solid-solid phase transition before melting. The α,ω-diols HO-(CH2)m-OH, where m=12, 22, or 32, were reacted in the melt with much shorter aliphatic α,ω-diisocyanates OCN-(CH2)n-NCO, where n=4, 6, 8, or 12, producing a series of linear, aliphatic, and increasingly polyethylene-like m,n-polyurethanes. Characterization (by DSC, TGA, and SAXS) of the m,n-polyurethane series showed that when the aliphatic segments were increased, and the hydrogen-bonding densities thus decreased, the polymers displayed physical and thermal properties (for example, solubility and melting temperature) typical of polyethylene. 相似文献
32.
Lisa Anthony Quincy Brown Berthel Tate Jaye Nias Robin Brewer Germaine Irwin 《Personal and Ubiquitous Computing》2014,18(6):1471-1483
In next-generation classrooms and educational environments, interactive technologies such as surface computing, natural gesture interfaces, and mobile devices will enable new means of motivating and engaging students in active learning. Our foundational studies provide a corpus of over 10,000 touch interactions and nearly 7,000 gestures collected from nearly 70 adults and children aged 7 years and above, which can help us understand the characteristics of children’s interactions in these modalities and how they differ from adults. Based on these data, we identify key design and implementation challenges of supporting children’s touch and gesture interactions, and we suggest ways to address them. For example, we find children have more trouble successfully acquiring onscreen targets and having their gestures recognized than do adults, especially the youngest age group (7–10 years old). The contributions of this work provide a foundation that will enable touch-based interactive educational apps that increase student success. 相似文献
33.
The telomerization of dimethylaminoethyl methacrylate (DMAEMA) with mercaptoethanol initiated by 2,2′-azobisisobutyronitrile was first investigated at 70 °C and the influence of the type of solvent was studied. The results showed that well-defined telomers of DMAEMA could not be synthetized via telomerization of DMAEMA in water or water/acetonitrile mixture since the telomerization reaction is in competition with the nucleophilic addition of thiol onto the monomer. Transfer constants for mercaptoethanol in benzene and acetonitrile were determined by Mayo's and O'Brien's methods. The transfer constant obtained in acetonitrile (0,6) was higher than that obtained in benzene. This difference can be explained by the fact that the thiol was consumed by two reactions: nucleophilic addition and telomerization. The influence of solvents on the polymerization kinetics was enlightened. These results were applied to the synthesis of macromonomers of DMAEMA with isocyanatoethyl methacrylate (IEM). These macromonomers were copolymerized with styrene. 相似文献
34.
Robin A. Henderson Robert G. Jensen Carol J. Lammi-Keefe Ann M. Ferris Kenneth R. Dardick 《Lipids》1992,27(11):863-869
To examine the effect of fish oil supplementation on the fatty acid (FA) composition of human milk and maternal and infant
erythrocytes, five lactating women were supplemented with 6 g of fish oil daily for 21d. Usual maternal diets contained 1,147
mg of total n−3 FA, with 120 mg from very long-chain (>C18) n−3 FA. Supplementation increased dietary levels to 3,092 mg of total n−3 FA and 2,006 mg of very long-chain n−3 FA. Milk
samples were collected daily, prior to fish oil ingestion, and at 4-h intervals on days 1, 7, 14 and 21. Milk n−3 FA content
increased within 8 h and reached steady state levels within one week. The n−6 fatty acid content decreased. Erythrocyte eicosapentaenoic
acid content increased from 0.24% to 1.4% (P<0.01) in mothers and from 0.11% to 0.70% (P<0.05) in infants. Docosapentaenoic acid increased from 1.4% to 2.2% (P<0.05) in mothers and from 0.30% to 0.78% (P<0.01) in infants. There was no significant change in docosahexaenoic acid or n−6 fatty acid content. Maternal platelet aggregation
responses were variable. No differences in milk or plasma tocopherol levels were noted.
Based on a paper presented at the Symposium on Milk Lipids held at the AOCS Annual Meeting, Baltimore, MD, April 1990. 相似文献
35.
Kevin P. Nolan Akshat Agarwal Shenghui Lei Robin Shields 《Microfluidics and nanofluidics》2016,20(7):101
Detailed measurements of the flow instability of dilute shear-thinning viscoelastic aqueous solutions, with relatively low zero-shear viscosities, in an obstructed microchannel flow are reported. We examine the flow behaviour resulting from a 100 μm post placed in the channel centreline over a range of Reynolds numbers (\(5<Re<300\)) and Weissenberg numbers (\(20<Wi<10^3\)). Micro-particle image velocimetry measurements show the onset of an upstream instability within a Reynolds number range and at a critical elasticity number corresponding to polymer concentrations above 25 ppm of long-chain polyacrylamide. The instability results in significant local fluctuations in the flow field approaching 30 % of the mean velocity. The magnitude of the local viscosity ratio in the region upstream of the post is proposed as a driving mechanism for the instability which resembles a buckling flow. Additionally, the classical instability owing to separation and vortex formation downstream of the post in Newtonian flow is suppressed and a very long stable wake is observed extending over 10 post-diameters downstream. 相似文献
36.
Faizal Riaz-ud-Din Robin Doss 《International Journal of Parallel, Emergent and Distributed Systems》2016,31(6):543-561
Database query verification schemes provide correctness guarantees for database queries. Typically such guarantees are required and advisable where queries are executed on untrusted servers. This need to verify query results, even though they may have been executed on one’s own database, is something new that has arisen with the advent of cloud services. The traditional model of hosting one’s own databases on one’s own servers did not require such verification because the hardware and software were both entirely within one’s control, and therefore fully trusted. However, with the economical and technological benefits of cloud services beckoning, many are now considering outsourcing both data and execution of database queries to the cloud, despite obvious risks. This survey paper provides an overview into the field of database query verification and explores the current state of the art in terms of query execution and correctness guarantees provided for query results. We also provide indications towards future work in the area. 相似文献
37.
38.
ABSTRACT Incorporating digital gaming into education is an increasingly popular topic in academia. Educators’ views of digital gaming (e.g., computer, video, and online games) have shifted from categorizing these games as an entertaining, yet pedagogically void activity to a promising medium that engages students in the learning process. With over 70% of college students enthusiastically playing digital games, educators are tapping into digital gaming as an effective means to teach millennials problem solving and communication skills. This article investigates gamer characteristics, motivational and engaging aspects of digital games, and the parallels between gaming and the information retrieval process. The authors build on this information to present approaches to incorporate digital gaming techniques into the library classroom since it is not feasible for all libraries to create instructional digital games. 相似文献
39.
Joshua Gorner Jie Zhang Robin Cohen 《Electronic Commerce Research and Applications》2013,12(2):112-123
This paper explores potential improvements to the trust modeling of agents in multi-agent systems when a social network of advisors is employed as part of the trust modeling, and in particular, examines means of optimizing the number of advisors that should be maintained in the social network. We propose three such improvements, two directly relating to the limit of advisor network size by either setting a maximum size for a buyer’s advisor network or setting a minimum trustworthiness threshold for agents to be accepted into that advisor network, and a third which uses an advisor referral system in combination with one of the first two network-limiting techniques. We provide experimental results in defence of our approach for two distinct trust modeling systems, and show how these optimizations can improve, sometimes significantly, the accuracy of different trust models (in the context of electronic marketplaces). We believe that the proposed techniques will be very useful for trust researchers seeking to improve the accuracy of their own trust models by setting the size and composition of advisor networks. 相似文献
40.
In this paper, we describe an implementation of use in demonstrating the effectiveness of architectures for real-time multi-agent
systems. The implementation provides a simulation of a simplified RoboCup Search and Rescue environment, with unexpected events,
and includes a simulator for both a real-time operating system and a CPU. We present experimental evidence to demonstrate
the benefit of the implementation in the context of a particular hybrid architecture for multi-agent systems that allows certain
agents to remain fully autonomous, while others are fully controlled by a coordinating agent. In addition, we discuss the
value of the implementation for testing any models for the construction of real-time multi-agent systems and include a comparison
to related work.
相似文献
Robin CohenEmail: |