Constructed wetlands are widely used for a variety of environmental applications, such as wastewater treatment and recharge, and their efficacy is largely determined by the hydrodynamic characteristics of the flow system. An experimental study was carried out to quantify the lateral dispersion of passive substances in shallow zones of a constructed wetland wherein water flows though the interstices of the distributed vegetation. The experimental set up was designed to mimic the Tres Rios constructed wetland located in Phoenix, Arizona. The major emphasis was on the lateral diffusivity K(t) of a shallow zone with randomly distributed vegetation. The results are presented in the context of a simple theoretical model where K(t) is expressed in terms of the diameter of the plant stalk D(v), the characteristic distance between the plants d(v), the flow velocity U and the drag coefficient C(D) as (K(t)/UD(v))(d(v)/D(v))=betaC(D), where beta is a dimensionless constant. Fitting of data to the above model indicate that C(D), in general, is a function of the Reynolds number (Re). The data are also compared with a model proposed by Nepf et al. (Water Res 35 (1999) 479). 相似文献
A recently described family of multicomponent reactions (MCRs) involving isocyanides, aldehydes, dipolarophiles and alkylboranes that yield highly substituted aziridines, oxazolidines and pyrrolidines has been studied in detail. In this work the scope of these processes is significantly increased by preparing the borane input through hydroboration of alkenes or organometallic processes, in tandem with the MCR. The aldehyde range is also expanded, and indole‐3‐carbaldehydes yield reactive imines and bis‐indolyloxazolidines, depending on the electron density of the heterocycle. Finally, the obtained adducts constitute an ideal platform to generate structurally diverse compounds using simple post‐condensation modifications. In this way, indole imines undergo stereoselective hydrocyanation and oxazolidines are reductively opened to give amino alcohols. Additionally, palladium‐, ruthenium‐ and gold‐catalyzed processes lead to a variety of complex heterocycles. The methodology is simple, efficient and highly divergent, leading to an array of interesting scaffolds for medicinal chemistry.
The H2O-catalyzed sintering of MgO in temperature gradients between 1303 and 1233 K is compared to sintering of isothermal samples. Both the changes in sample dimensions in planes normal to the temperature gradients and the increases in density for a fixed sintering time are greater than predicted on the assumption that densification in a temperature gradient is a function only of each local temperature in the gradient. Under the conditions used, neither vapor transport nor transport through a liquid phase is important. The results, therefore, support a recent prediction that temperature gradients supplement surface energy changes in driving sintering and related processes not only by vapor transport, as expected from earlier studies, but also by a surface, grainboundary, or bulk diffusion path. 相似文献
Suspension and centrifugation of crude microsomes of rat liver in low ionic strength solution separated a soluble protein
fraction that is necessary for the full activity of the linoleic acid desaturase. The fraction partially purified through
Sephadex G-150 still retains lipids which are mainly constituted by phosphatidylcholine. Linoleic acid predominates in the
fatty acid composition. By NaCl gradient centrifugation and electrophoresis in gelatinized cellulose acetate, the factor behaves
like a lipoprotein. The factor binds linoleic acid and linolyl-CoA that are desaturated to γ-linolenic acid when incubated
with washed microsomes. Albumin does not replace the factor. 相似文献
Some effects of food, habitat and temperature on the lipid composition of a freshwater mollusk,Diplodom patagonicus, were studied. Animals kept and fasted up to 60 days in an aquarium at 9 C and 20 C showed a decrease of the total lipid
content that corresponded to a decrease of triacylglycerols and diacylglycerol ethers. This decrease evoked an increase of
polar-to-nonpolar lipid ratio. However, no significant change in the total fatty acid composition was shown. Moreover, a decrease
of temperature from 20 C to 9 C decreased the incorporation of labeled linoleic and α-linolenic acid into the lipids, but
did not modify the unsaturated: saturated acid ratio of the mollusk lipids during this period. A change of habitat from lake
to estuary changed very significantly the fatty acid composition of the animal. The ω6 acids, linoleic and arachidonic, typical
ofD. patagonicus living in the lake, were partially replaced by ω3 acids. That this change was due to a change of food composition was indicated
by the fatty acids of corresponding sediments. Therefore, the fatty acid composition ofD. patagonicus is highly sensitive to food composition and varies little with temperature and seasonal changes.
Member of Carrera del Investigador Científico de la Comisión de Investigaciones Científicas de la Provincia de Buenos Aires.
Member of Carrera del Investigador Científico del Consejo Nacional de Investigaciones Ciéntíficas y Técnicas, Argentina. 相似文献
Stillage from cane molasses alcohol for SCP production was used for the growth of strains of Candida and Paecilomyces as SCP sources. The results of small and large scale experiments carried out with a Candida utilis strain with data on chemical composition, amino acid profile, vitamin content and biological value of the cell material are given. 相似文献